反应时间

The optimum reaction conditions are as follows: diphenylmethanethiol : methyl chloroacetate is 1:1.5, and the reaction carried out at 100℃ for 4 h, 2- acetamide can be carried out in the room temperature for 20 h, the yield of 2- acetamide was 76%, hydrogen dioxide: 2- acetamide is 1:1, and the reaction carried out at 60℃ for 3 h, the yield of modafinil was 79%, the total yield of reaction can be reached 48%.

研究表明，采用氯乙酸甲酯作为醚化试剂，反应时间4h，反应温度100℃，二苯甲硫醇：氯乙酸甲酯=1：1.5，室温下氨解反应20h，二苯甲硫乙酰胺收率76%；采用过氧化氢作为氧化试剂，反应时间3h，反应温度60℃，过氧化氢：二苯甲硫乙酰胺=1：l，莫达非尼收率79%，反应总收率可达48%。

The preparation process includes the following steps: dissolving activator and RE oxide in the molar ratio of 0.01-0.02 in concentrated nitric acid and heating to dry, dissolving the obtain RE nitrate in deionized water to obtain solution of RE nitrate; dissolving soluble tungstate and surfactant in deionized water to obtain tungstate solution; mixing the RE nitrate solution and the tungstate solution through stirring to reaction for 25-60 min to obtain white precipitate; hydrothermal reaction of the precipitate in a reaction kettle at 100-260 deg.c for 24-72 hr; centrifugally separating, washing and drying to obtain the product.

浓硝酸的加入量保证稀土氧化物溶解就可以，过量的硝酸可以加热除去；将可溶性钨酸盐和表面活性剂溶解于去离子水中，得到钨酸盐溶液，表面活剂性的加入量为反应原料重量的0-30wt％；将稀土硝酸盐溶液加入到钨酸盐溶液中搅拌，发生沉淀反应，磁力搅拌时间为25-60分钟，得到白色沉淀；将含有沉淀物的溶液作为前驱物加入到反应釜中，发生水热反应，反应温度为100-260℃，反应时间为24～72小时；离心分离，洗涤，干燥，即得所需产物。

The optimum reaction conditions are obtained by orthogonal exptl. design; ring-opening reaction:n:n = 1:1.3, Hexamethylenetetramine catalyst 0.7%,reaction temp. is 80℃, reaction time is 7 h, and concentration of inhibitor is 0.3%. ring-closing reaction : n:n=1:0.9, reaction temp. is 40℃, reaction time is 5 h.

通过正交设计确定了最佳工艺条件为：开环反应：六次甲基四胺用量0.7%(占反应物总量的质量百分比)，阻聚剂用量0.3%(占反应物总量的质量百分比)，ECH：MAA的摩尔比为1.3：1，温度80℃，反应时间7h ；闭环反应：氯醇酯： NaOH的摩尔比为1：0.9，反应温度40℃，反应时间5h。

Results show that 4-oxo-β-ionone is the major product with yield of 53.5% under the conditions as follows: reaction temperature 45℃, reaction time 24 h, the molar ratio of n: n(NaClO3): n 20: 100: 3, and pH value of solution in 1-3; on the other hand, 5,6-epoxy-β-ionone is major product with yield of 25.4% when reaction temperature is 40℃, reaction time is 24 h, the molar ratio of n: n(NaClO3): n is 20: 120: 5, and pH values of solution is 3. The excessive β-ionone can be recovered by vacuum distillation for reusing again. 4-oxo-β-ionone and 5,6-epoxy-3-ionone were purified by recrystallization and silica gel column chromatograph respectively with the purity over 98%.

研究结果表明：氯酸钠氧化β-紫罗兰酮的反应主要生成4-氧代－β-紫罗兰酮和5，6-环氧－β-紫罗兰酮，经重结晶和硅胶柱层析分离，纯度高于98%；4-氧代－β-紫罗兰酮的有利合成条件是反应温度为45℃，反应时间为24h，溶液的pH值为1~3，反应物配比n：n(NaClO3)：n为20：100：3，最佳收率为53.5%；5，6-环氧－β-紫罗兰酮有利的合成条件是反应温度为40℃，反应时间为24h，溶液的pH值为3，反应物配比n：n(NaClO3)：n为20：120：5，其收率为25.4%；未反应的β-紫罗兰酮经减压蒸馏回收后可重复使用。

In this research, the activities of CWDE were measured by saccharifying according to the theory that red-brown amino compounds were produced when 3, 5-dinitro salicylic acid and aldehyde were heated together. And the testing conditions were made clear. The activity of Cx should be tested with optimal temperature of 50℃, optimal pH of 4.8, incubation time of 30 min, and optimal substrate of 0.6% CMC-Na. Due to the heat-libality, Cx should be sterilized more than 10 min. The testing conditions of the activity ofβ-G were almost the same with Cx except the substrate of 0.5% salicin and the sterilization time of more than 15 min.

主要取得了一下成果：(1)明确了条锈菌细胞壁降解酶活性测定的条件：羧甲基纤维素酶活性的测定条件为50℃，pH4.8，反应时间30min，底物浓度为0.6%羧甲基纤维素钠，以DNS法测定，且失活酶液的灭活时间应大于10min；β-葡萄糖苷酶活性的测定条件为：50℃，pH4.8，反应时间30min，底物浓度为0.5%水杨苷，以DNS法测定，且失活酶液的灭活时间应大于15min；果胶酶活性的测定条件为：50℃，pH4.8，反应时间1h，底物浓度为0.25%果胶，以DNS法测定，且失活酶液的灭活时间应大于10min。

The thermolysis electrocyclic reaction was affected significantly by the structuresof substrates, reaction temperature and time as well as Lewis acids and organic acids.

通过对反应物的结构、反应温度、反应时间、Lewis酸和质子酸的催化效果等诸多因素对该反应的影响进行探讨发现，在反应中使用1.1当量的三氟乙酸时，不仅反应时间可以缩短8-21小时，产率也可以提高20-30％。

The results showed high class PbSt2 could be synthesized by this new saponifying process.Compared with metathetical process,the reaction time shortened,liquid-solid ratio and moisture content of filter cake decreased.Powder product could be prepared by one-step process,and particle product by two-step process.For the optimum processing conditions,the reaction temperature and time for one-step process were 65℃ and 10min,the amount of alkali added in the first step was 50%;reaction temperture and time were 65℃ and 10min for the two-step process.

结果表明，用皂化法工艺可得到优等品PbSt2，较复分解工艺，反应时间缩短、液-固比降低、滤饼湿含量比减小，一步式工艺得到粉状产品，二步式工艺得到颗粒状产品；最佳工艺条件为：一步式工艺反应温度65℃，反应时间10min；二步式工艺第一步的加碱量比50%，反应温度65℃，反应时间10min。

Study result suggest: The change of stock in RFCCU directly affect gasoline content. Gasoline content can be reduced through increasing the equilibrium activity of catalyst, controlling reaction level, increasing recirculating rate of gasoline and stability of gasoline level. Conclusions drawn from experiment is that optimization of operating condition has great effect on lowering olefine content of gasoline which can be reduced from 60% to 50%.Reducing reaction temperature is useful for lowering olefine content of gasoline, when the reaction temperature is raised, thermal cracking rate is higher than catalytic cracking rate, so that olefine content is increased. Raising catalyst-to-oil ratio is good for lowering olefine content. With conversion rate increased, the yield of LPG and coke is raised, the yield of gasoline is increased firstly and then decreased slightly, hydrogen transfer index is increased, so the olefine content is decreased.

研究结果表明：催化裂化装置的原料的变化直接影响到催化汽油的烯烃含量；可以通过优化催化装置的操作条件来降低催化汽油中的烯烃含量，其中通过提高催化剂平衡活性、控制反应深度、增加汽油回炼量、汽油深度稳定可以降低催化汽油烯烃含量，优化工艺条件对降低催化汽油烯烃含量有较大作用，汽油烯烃含量由60％降至50％左右；降低反应温度有利于降低催化汽油的烯烃含量，当反应温度的提高，热裂化反应速度提高的幅度大于催化裂化反应速度提高的幅度，汽油烯烃含量增加；剂油比的提高有利于降低催化汽油的烯烃含量，转化率提高，液化气产率提高，汽油收率先增加后略有下降，焦炭产率增加，氢转移反应指数提高，汽油烯烃含量下降；反应时间对产品分布及汽油烯烃含量有影响，增加提升管反应时间，液化汽、汽油产率提高，干气和焦炭产率增加。

The results showed that the yield of the esterification stage was 95.0% and the yield of the addition stage was 90.0% when the mole ratio of trimethylolalkane,triethyl phosphate and dimeth...

结果表明：亚磷酸三乙酯：三羟甲基丙烷：甲基磷酸二甲酯的摩尔比为1.05：1：1.2，自制复合有机酸为酯交换反应催化剂，质量分数为0.1%，反应温度85℃，反应时间3 h，自制复合有机碱为加成反应的催化剂，质量分数为1.0%，反应温度200℃，反应时间8 h，酯交换反应收率95.0%，加成反应收率90.0%。

To the product yield is mainly studied in the brominating process, and the best synthesizing process conditions is obtained; the effect of the selection, quantity of the solvent, the reaction temperature, reaction time, and the catalyzer to the product yield is researched in the process of ketalization and the relative preferable process conditions has been got.

在脱溴反应中，主要研究了溶剂的用量、溶剂配比、物料配比、反应时间和反应温度等对目标产物得率的影响；在选择性溴化反应中，主要研究了溶剂和溴化剂的选择、物料配比、溶剂的用量等参数对产物质量和得率的影响，最终得到了合成的最佳工艺条件；在缩酮化反应中，主要研究了溶剂的选择、溶剂的用量、反应温度、反应时间和催化剂的选择等参数对产物得率的影响，并得到合成的较佳工艺条件。

Since historical times,England ,where the early inhabitants were Celts, has been conquered three times .

从有历史以来，英国，在此地早期居住的是凯尔特人，已经被征服了三次。

Bluetooth OBEX File Transfer Enables the sending and receiving of files on your phone via Bluetooth.

蓝牙OBEX文件移动允许经过蓝牙传送和接受文件。。。。