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Mol/L. This method is applied to determination of aristolochic acid in crude chinese medicine aristolochia debilis Sieb.

SCE。还原电流与马兜铃酸的浓度在1.60×10〓~1.38×10〓moL·L〓〓(R=0.9992)范围成线性相关,检出限为7.58×10〓moL/L。

The spectroscopic and electrochemical studies suggest the energy structure of this class complex can be easily controlled by modification. With the introduction of electron-donating arylamino groups, the obtained complexes show intense and continuous absorption bands in the region of 250-550nm with strong metal-to-ligand charge transfer dπ(Pt →π* transitions (ε~ 2×104 dm3 · mol-1 · cm-1). Complexes involving the construction of D-π-A type systems also display continuous absorption bands in the region of 400-750nm, rising from the overlapping effect of MLCT and LL'CT bands.

其中,芳胺及其二聚体类修饰基团的引入,使其配合物MLCT吸收谱带的摩尔吸光系数增加,并在250~550nm范围内形成了强的连续吸收;具有D-π-A结构的配合物,由于MLCT吸收谱带和LL'CT吸收谱带的协同效应,导致在400~750nm范围内形成连续吸收;得到了从绿光到深红光的磷光发射系列配合物,并采用真空蒸镀的方法获到了外量子效率分别为5.7%和5.0%的橙光和橙红光多层电致发光器件。

For example, there is only local cooperative organization between polymer segments of atactic poly in the middle-sized solvent poly with molecular weight 200g/mol (PEG200). But for the stereo-regular isotactic polystyrene, pronounced content of 3〓 helix can be found in its middle-sized solvents.

例如,无规聚甲基丙烯酸甲酯在聚乙二醇(分子量为400)中分子溶剂中表现为链段的局部协同组织,而等规聚苯乙烯在邻苯二甲酸二辛酯、氯代十四烷等中分子溶剂中则出现相当含量的3〓螺旋构象。

Under certain experimental conditions,the Terbiumbasic Calbonate can be dissolved in aqueous solution of nicotinic acid to yield an Orange Tb Complex, which has a broad characteristic absorption band between, 370—410 nm The autoreduction of the Tb—Complex was studied by means of spectrophotometric method, It was determined by experiments that the reaction order is equal to two and the apparent activation energy of the auto—reduction is equal to 68.4±0,8KJ/mol.

在一定条件下,Tb的碱式碳酸盐可以溶解在烟酸的水溶液中形成橙黄色的络合物,该络合物在390nm波长附近有一宽带特征吸收峰。消光值在0。~1.0范围內与Tb的浓度具有直线关系。分光光度法对Tb自还原反应研究确定:于15℃及烟酸浓度为0.35M时,当pH值小于6.0条件下,随pH值的增加,其自还原速度常数减小,该自还原反应级数为二,反应活化能为68.4±0.8KJ/mo1。

The simplified peseudo-first-order kinetic model for hydrolyzation of benzal chloride was proposed according to the character of hydrolyzation reaction and the apparent reaction rate constant and activity energy was obtained. The activity energy is 17.73KJ/mol in the temperature range from 900C to 1100C and the model values and experimental values tally well.

根据水解反应的特点,提出了简化的苄叉二氯水解反应拟一级动力学模型,经参数估计,得出了水解反应的宏观反应速率常数和活化能,在900C~1100C温度范围内,反应活化能为E1=17.73kJ/mol,模型计算值与实验值吻合较好。

The resin with I_1 as photoinitiator possessed much higher sensitivity with a threshold energy 2.02 mW at the concentration of 0.05 mol% compared to that of 12.72 mW for benzil.

含有0.18 mol% II_1的树脂在1000μm/s扫描速度下,仅用2.53 mW的激光能量即可聚合成连续的线。

Under the steady state assumption, equilibrium concentration of benzo pyrene in air is very low (1. 3×10〓mol/m〓) with almost all of the chemical absorbed on particles.

稳态条件下,气相中苯并芘的平衡浓度相当低,仅1.3×10〓mol/m〓,且在气相中几乎所有的物质都吸附在颗粒物上,以气态形式存在的量微不足道。

Results showed that the best separation factor of sulfides amounted to 1.7 by ZSM-5 membranes loaded with 0.2 mol/L Ag+ solution. The separation performance of the membranes was the best when activated 450℃. Benzothiophene showed a strong competitive adsorption effect to thiophene.

实验表明:当银离子浓度为0.2 mol/L时硫化物的分离因子最高达到1.7;当活化温度为450 ℃时ZSM-5分子筛膜的分离性能最好;苯并噻吩对噻吩有较强的竞争吸附影响。

Mol〓 by examining the acid number of the system during polymerization. The monomer emulsion of St and CTUP was formed by adjusting pH to 8, and the self-emulsified emulsion polymerization was initiated by using KPS and sodium bisulphite.

以CTUP和St为单体,通过调节体系至弱碱性(pH=8)制成单体/水的乳化液,并在过硫酸钾-亚硫酸氢钠氧化还原体系的引发作用下进行自乳化乳液聚合。

It is characterized by that firstly, preparing silver bromiodide flake microcrstalline emulsion, then utilizing silver halide solution to corrode core of silver bromide to prepare the invented hollow silver bromiodide flake microcrystal whose form is triangle or hexagon and whose surface possesses small holes and pits, and the core of the microcrystal is silver bromide and its external layer is silve bromidiode, its iodine content is 1-10 mol%, and the light sensitivity of the emulsion is greatly raised.

首先制备溴碘化银薄片微晶乳剂,再利用卤化银溶剂使溴化银内核腐蚀,制备成的中空溴碘化银薄片微晶呈三角形或六边形,表面上有小孔和凹坑,微晶的内核为溴化银,外层为溴碘化银,其碘含量为1―10mol%;无论从色盲乳剂,还是经光谱增感乳剂的感光度都有大幅度的提高。

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