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After the basis set superposition error correction and the zero point vibration energy correction, the interaction energies for three types of NMA-acetic acid complexes and one type of NMA-water complex were -44.3,-35.5,-32.4 and -16.0 kJ·mol-1 respectively, which showed that NMA had a great affinity for acetic acid than water.

NMA与水\醋酸之间都有氢键形成,经计算得到NMA-醋酸复合物的稳定化能在-32.4~-44.3kJ/mol之间,且平面构型的NMA-醋酸复合物稳定能较高,而NMA与单分子水的稳定化能仅为-16.0kJ/mol。

Under the optimum conditions, the linear range of the method was 0-80 μg/L. The detection limit was 4.58×10^(-7) g /L.The catalytic reaction was the zeroth order one. The apparent activation energy and the reaction rate constant was found to be 96.04 kJ/mol and 3.61×10^(-3)/s, respectively. The sensitivity was increased by 3 times in the presence of surfactant.

在最佳实验条件下,方法线性范围为0~80μg/L,检出限为4.58×10^(-7)g/L;催化反应为动力学零级反应,表观活化能为96.04kJ/mol,反应速率常数为3.61×10^(-3)/s;反应在表面活性剂存在下,灵敏度提高3倍。

When the reaction temperatures were 303.15, 308.15, 313.15, 318.15, 323.15 and 328.15 K, respectively, the apparent reaction rate constants of abietic acid were 0.0036, 0.0041, 0.0062, 0.0087, 0.011 and 0.0157 min^(-1), respectively. Its reaction activation energy was 50.29 kJ/mol.

枞酸的氧化反应温度为30,35,40,45,50和55℃时,表观速率常数分别为0.0036,0.0041,0.0062,0.0087,0.011和0.0157min^(-1),表观反应活化能E为50.29kJ/mol。

It includes the following steps: extract trivalent iron ion and divalent iron ion in water phase through organic extractant, get predecessor of; absterge it with secondary distilled water for2-3 times and get pure load metal predecessor of organic phase; mix organic phase of Mg2 and Fe3 with mol rate of 1:2 and introduce them into autoclave, add distilled water according to the rate of 3:1 or 4:1 of organic phase and water phase and airproof it, and then mix it fiercely, stripping with hydrothermal method at temperature between 200 degree C and 300 degree C and make them react for 2.5 hours; cool it to the room temperature under natural condition, separate liquid and centrifugalize it, absterge it with absolute alcohol for 2-3 times and dry it at temperature of 50 degree C for 30-180 minutes, then get product of magnesium ferrite.

包括如下步骤:通过有机萃取剂来萃取水相中的三价铁离子和二价镁离子,制得有机相前驱物;用二次蒸馏水洗涤2-3次,获得纯净的负载金属有机相前驱物;按照Mg 2 和Fe 3 摩尔比1∶2将有机相混合均匀后引入高压釜中,按照有机相与水相的比例为3∶1或4∶1加入蒸馏水,密封后,对溶液进行强力搅拌,水热反萃的温度在200-300℃之间反应2.5小时;自然冷却至室温,分液,离心分离,用无水乙醇洗涤2-3次,在50℃下干燥30-180分钟,得铁酸镁产品。

The non-isothermal kinetic data were analyzed with the Achar equation, Coats-Redfern equation, Kissinger equation, Flynn-Wall-Ozawa equation and Starink equation.The mechanism function and kinetic parameters of the thermal decomposition in the third step were obtained.The chemical reaction mechanism (F3) controlled the third thermal decomposition process.The apparent activation energy and the pre-exponential factor were 351 kJ·mol-1 and 2.57×10 30s-1 respectively.

采用Achar方程、Coats-Redfern方程、Kissinger方程、Flynn-Wall-Ozawa方程和Starink方程对非等温动力学数据进行了分析,得到了第3步热分解反应的机理函数、动力学参数和热分解反应动力学方程,其热分解反应过程受F3机理控制,表观活化能为351 kJ·mol-1,指前因子为2.57×

Seeds were germinated at eleven salinities (0,20,40,60,80,100,120,140,160,180,200 m mol/L NaCl) and germination percentage, rate of germination, as well as seedling growth were measured to detect the differences amang three cultivarscline.

在0,20,40,60,80,100,120,140,160,180,200m mol/L浓度NaCl胁迫条件下,研究了发芽率、发芽指数,并比较分析了胚根、胚轴生长状况。

All transition states in the assisted aminolysis are 35—70 kJ/mol lower than those for the non-assisted reaction.

研究结果还表明:水分子的参与有利于N-甲基b-磺内酰胺的氨解反应,它能够大大的降低反应能垒,降低值约为35—70 kJ/mol。

When phosphine≥〓mol is added to a solution ofL1M in 〓, a strong fluorescence species L1ML is formed and a new off-onprocess is completed.The reaction of L2 with 〓 gives macrocyclic luminescencecomplexes L2M by the π-π interaction of the anthryl groups in the two L2ligands.

对其光物理性能进行研究表明由L1到L1MCu(Ⅰ、Ag、Au荧光被完全猝灭呈现荧光on-off开关现象,金属络合物作为新的荧光分子开关体系以金属离子为受体中心在溶液中对三价磷中性客体呈现off-on开关现象。

AIM:To study the protective effects and mechanism of Ligustrazine against damage and apoptosis in human umbilical vascular endothelial cells induced by 160 μ mol/L arachidonic acid.

目的:研究川芎嗪对花生四烯酸(160 μ mol/L)诱导的血管内皮细胞损伤和凋亡的保护作用及其机制。

Among the four species of ground cover, the light saturation point and light compensated point of Ardisia japonica was the highest, and the value was 645 and 202 u mol/m2s, respectively, while the light compensated poin of Belamcanda chinense was the lowest.

四种地被植物中,紫金牛的光饱和点与补偿点最高,分别为645与202μmol/m~2s,金叶过路黄、多花筋骨草与射干依次减小,光补偿点以射干为最低。

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