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At the normal state, porphyrin molecules do not have EPR signal. However, light excitation may cause a transition of porphyrin molecules from singlet to triplet. At the same time, the change from diamagnetism to paramagnetism occurred to porphyrin molecules. In this case, the two un-paired electrons are nearby each other and cause a strong interaction, giving EPR signal with sharp peak at g =2.000. The g value increased with an increase in electron cloud density.

常态下卟啉分子没有EPR信号,在光的激发下,卟啉分子由原来的逆磁性分子变成顺磁性的激发三重态分子,这种激发三重态分子在分子轨道上具有两个未成对电子,这两个电子相距很近,彼此之间发生很强的相互作用而产生电子,它的 g 值随卟啉共轭体系平均电子云密度增大而变大。

Density Functional Theory in connection with accurate LCAO basis sets and norm-conserving pseudopotentials were used to study two issues which are (1) The Selective Functionalization of Single-Walled Carbon Nanotubes with Diazonium Radical and (2) The Molecular Dynamic Simulated IR Spectrum of Adsorbed C3H3 and I on the Ag(111) Surface.For the first, we investigated (1) NO2C6H4 direct addition (2) NO2C6H4N2 dissociative addition reaction on semiconductor (8,0), metallic (9,0)and(5,5) carbon nanotubes.

第一部分模拟的结果显示,在半导体性质(8,0)和金属性质(9,0)、(5,5)奈米碳管上,硝基苯自由基(NO2C6H4)的直接加成反应於不同导电性质的奈米碳管间不具有选择性,而硝基苯重氮化合物自由基(NO2C6H4N2)的解离吸附反应会选择性的与金属性质奈米碳管发生反应,因为在金属性质的系统中,奈米碳管於过渡态时会藉由电荷的转移来稳定过渡态的结构,进而帮助反应更快的进行。

IGMs are a kind of experimentally new-identified optical mode, standing with apparent potential in design and application. However, the mathematical expression of IGMs under Elliptic Cylindrical coordinates, preventing us from understanding IGMs instinctively, stands a formidable challenge in application. The pure mathematical expressions of IGMs are composed by a great deal of calculation, which also bids us no help in common use. I am, therefore, prompted to build an easier mathematical approach in this study.

Ince- Gaussian modes为在实验中可见的一种崭新型态的光学模态,对於我们在应用和设计上的实现,拥有许多潜力;然而,由於IGMs是在椭圆圆柱座标系下的数学来表示,造成了我们无法直觉的去了解,也成了我们在使用上的一大考验; IGMs的不易亲近,也让我们无从进一步去了解其物理特性,若纯粹以数学出发,又包含了庞大的运算,无法达到普遍的运用,是故我希望能在这篇论文使用简单的数学描述来达成对IGMs较平易近人的理解。

By means of the expansion theorem, the displacement is expressed as the summation of the first several exact modal vectors.

考虑前若干阶线性振动模态,使用展开定理,将索的位移表示成共轭的模态函数的级数和。

A new pricing approach to real option is thus proposed to transform the forecast intervals evaluated by experts into some normal fuzzy numbers with the lattice closeness degree introduced to construct weighted vectors. In this way the rationality of estimating the present value of expected cash flow payoff by using a normal fuzzy number is verified.

提出了将预期现金流收益现值的专家评估区间转化成正态模糊数并利用格贴近度构造权向量的一种新的实物期权定价方法,验证了利用正态模糊数估计现金流收益现值的合理性。

In city , because the occupied area of the urban sewage pumping station is usually limited , the length of the forebay is inclined to be short and the diffusion angle in flow direction is big accordingly , which causes bad flow pattern, such as backflows ,vortices, etc.

城市排污泵站由于条件的限制,前池一般面积较小,扩散角较大,扩散段较短,因此水流进入前池后突然扩散,流态紊乱,易行成回流、漩涡等不良水流流态,从而影响水泵的工作性能。

The analysis gets the result: the two methods both make out the heteromorphism InSb nanocrystals, which have different crystal lattices. There are few In and Sb elementary substance grains mixed in the samples and the ratio of two kinds of chemical elements nears to 1:1. The crystal structure of the particle which is gained in vacuum evaporation method is affected by the crystal structure of substrate surface and anneal, the size of grain is direct proportion to evaporation time.

分析得到结果表明:两种方法均制备出了多晶态的InSb纳米微粒,但晶格结构不同,样品中都混有少量的In和Sb单质颗粒,且两种元素的比均接近1:1;真空蒸镀法得到的微粒的晶态受基片表面晶格和退火的影响,颗粒的尺寸与蒸镀时间成正比;而惰性气体中蒸发法得到的微粒结晶过程与基片无关,颗粒的尺寸与惰性气体的种类和压强有关。

This method calculates the next status functions of each trigger in a sequenced circuit and shows all the functions within one Karnaugh map, and then converts into status chart.

该方法首先求出时序电路中各触发器的次态表达式,然后把各次态表达式表示在同一张卡诺图上,最后再把它转换成状态图。

A monostable-bistable transition logic element, employing two NDR devices connected in series, is a functional logic gate.

在本论文中我们亦介绍了以单稳态-双稳态传输逻辑闸架构而成的多逻辑闸电路。

The author concluded that the content of general nitrogen and amino nitrogen of normal beers were higher than others, and the super drought beer were lowest; The spirit degree was match with the malt liquor.

普通型啤酒的总氮及氨态氮含量都最高,超干型啤酒总氮及氨态氮含量最低。酒精度与原麦汁浓度成正比。

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He and Nina moved to California and lived at 2005 Ivar Street, Apt.

他和Nina搬到加州,并在2005年伊瓦尔街,公寓生活。

Droperidol ( potently inhibits transfected HERGchannels and this is the probable mechanism for QT prolongation.

氟哌利多有效地抑制了转染的 HERG 钾通道,可能是 QT 间期延长的机制。

The Nazi's cruel treatment of the Jews during the Second World War is beneath contempt .

二战期间纳粹对犹太人的暴行极其可鄙。