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The experimental results show that hydrophobic association increases obviously with increasing polymer concentration, hydrophobe content, hydrophobic side chain length and temperature. The Critical aggregate concentration of P(AM/NaAA/C_8AM) with different hydrophobic content is 1.5-3g/L. Strong ass...

结果表明,随聚合物浓度、疏水单体摩尔分数、疏水侧链长和温度的增加,疏水缔合作用增强;不同疏水单体含量的P(AM/NaAA/C8AM)的临界缔合浓度为1.5~3.0 g/L;表面活性剂十二烷基硫酸钠与P(AM/NaAA/C8AM)发生了强烈的疏水相互作用,形成混合胶束,得到SDS的临界胶束浓度为8×10-3 mol/L;由于聚合物链上羧基的存在,使其具有良好的 pH敏感性,随 pH值的增大,P(AM/NaAA/C8AM)的疏水缔合作用呈现先减弱后恒定再增强的变化。

The experimental results show that hydrophobic association increases obviously with increasing polymer concentration, hydrophobe content, hydrophobic side chain length and temperature. The Critical aggregate concentration of P (AM/NaAA/C8AM) with different hydrophobic content is 1.5~3g/L. Strong association between surfactant sodium dodecyl sulfate and P (AM/NaAA/C8AM) occurs through the formation of mixed micelles. The CMC of SDS is 8×10^(-3)mol/L. Moreover, because of the presence of-COOH group, the terpolymers have pH-responsive characterization. The hydrophobical association changes greatly with increasing pH.

结果表明,随聚合物浓度、疏水单体摩尔分数、疏水侧链长和温度的增加,疏水缔合作用增强;不同疏水单体含量的P(AM/NaAA/C8AM)的临界缔合浓度为1.5~3.0g/L;表面活性剂十二烷基硫酸钠与P(AM/NaAA/C8AM)发生了强烈的疏水相互作用,形成混合胶束,得到SDS的临界胶束浓度为8×l0^(-3)mol/L;由于聚合物链上羟基的存在,使其具有良好的pH敏感性,随pH值的增大,P(AM/NaAA/C8AM)的疏水缔合作用呈现先减弱后恒定再增强的变化。

The joint toxicity was evaluated by different methods, including toxicity unit,additive index, similarity parameter and mixtures toxicity index. The results show that the binary joint effects of phenol and toluol mixed with SDS are synergistic, while the binary joint effect of SDS and nitrobenzene is antagonistic. The environment risk of some compounds will be enhanced because of the joint of SDS.

研究结果表明: 4种不同的评价方法对SDS与取代芳烃苯酚、甲苯和硝基苯的联合效应评价结果具有较好的一致性,即SDS与苯酚、甲苯的二元混合体系的毒性表现为不同程度的协同作用,而与硝基苯则表现为弱拮抗作用;对环境存在风险性的阴离子表面活性剂SDS,当与一些有毒有害物质共存时会增加该类物质的环境风险性。

The effect of the latter was that the resulting codeposit will contain only a few PTFE particles at lower surfactant concentration, and that it will contain a lot of bubblles at higher surfactant concentration, and that a flat composite codeposit formed with densely arranged micro-cells at suitable surfactant concentration.

后者的影响是:在表面活性剂浓度过低时所沉积的镀层中只含很少量的PTFE粒子,在其浓度过高时所沉积的镀层中会夹杂许多气泡,只有在其浓度合适时才能得到平整的、由致密排布的微胞组成的复合镀层。

The Schiff base transitional metal complexes of various structures and their metallomicelles as peroxidase models for the phenol and phenolic derivant oxidation have been investigated. Some results are obtained from the studies:(1) the Schiff base transitional metal complexes have high catalytic activity for the phenol and phenolic derivant oxidation, and the structure of the complexes has a great effect on its catalytic activity;(2)a novel kinetic mathematical model for the complexes and their metallomicelles catalyzing the phenolic derivant oxidation has been established;(3) the feasibility and mechanism for the phenolic derivant oxidation catalyzed by the metallomicelle(as the mimetic model of peroxidase)have been discussed.

研究了冠醚Schiff碱金属配合物作为过氧化物酶的模拟模型对酚类物质氧化反应的催化作用,取得如下结果:(1)几种冠醚Schiff碱金属配合物对催化酚类物质氧化具有良好的催化活性,其中配体结构对其催化活性有较大的影响;(2)建立了金属配合物与表面活性剂形成的金属胶束催化酚类物质氧化反应的动力学数学模型;(3)探讨了金属胶束模拟过氧化物酶催化酚类氧化反应的可行性及其机理。

It has a high activated alkali degree,strong PH buffering effect,and strong resediment effect.It cooperates with suface activated agent well. Its aid-washing effect and detersive power in scour is almost the same with that of STPP,so it can replace STPP.It is an excellent new silicate non-phosphor washing assistants.It can be used to produce washing power in both front and back compound product line.It is also an imporant washing assistant for paste and liquid washing as well as basic raw material for industrial scour.It has wider foreground in market.

层状结晶硅酸钠具有较强的软化水和去污能力,很好的活性碱度,PH缓冲能力和抗再沉积能力强,与表面活性剂有较好的协同作用,用在洗涤剂中的助洗效果和去污能力与三聚磷酸钠相近,是优秀的新型硅酸盐助剂,可用于前后配料生产洗衣粉,也是膏状、液体洗涤剂的重要助洗剂及工业清洗剂的基础原料,产品市场前景广阔。

Different additives acted differently in the course of fermentation. Dodecane as oxygen vector and cosolvent, Tween-85 as surfactants and structure analog of carbon source, were the most important for the lipase production.

不同的添加剂在发酵的过程中所起的作用不同,正十二烷作为氧载体和溶剂的作用,Tween-85作为表面活性剂和碳源结构类似物的诱导作用,在发酵过程中对脂肪酶能够大量的产生都是至关重要的。

The effects of the surfactants, trioctyl phosphine oxide, sodium dodecyl sulfonate and hexadecyl trimethyl ammonium bromide, on the extraction rate of Co^2^+ were investigated. The acceleration in the kinetics in contributed to the associated molecule~2 TOPO taking part in the extraction process directly. The decrement effects of SDS or CTMAB on the rate of extraction kinetics of Co^2^+ with HDEHP were also observed, which caused by the adsorption of molecules of SDS or CTMAB on the interface and decreased the interfacial adsorption amount of HDEHP. In addition, the extraction rate was reduced by a bigger margin in HDEHP-SDS system. This can be explained in terms of the formation of an electric field at the interface.

研究体系中加入不同表面活性剂所引起萃取速率的不同改变:三辛基氧化膦因与HDEHP形成可萃取的Co^2^+活性分子缔合物,降低了萃取过程活化能而使反应加速;十二烷基磺酸钠和十六烷基三甲基溴化铵因占据发生萃取反应的界面区,减小了HDEHP与Co^2^+反应的机会而使反应减速; SDS还因其在界面形成较强的负电场,造成Co^2^+的附加势能而使萃取速率有更大幅度的降低。

Synchronous fluorescence showed that the addition of POM could enhance the fluorescence intensity of CV, which was explained in terms of the hindrance of the formation of the nonfluorescent twisted intramolecular charge transfer states of CV by the assembled POM-CV system, and the surfactant CTAB could enhance the luminescence by coordinated assembly.

具有同样Keggin结构的4种稀土杂多阴离子与结晶紫的作用总体一致,稀土元素不同体系的光活性会表现出一定的差异。实验证实,阳离子表面活性剂CTAB的存在会进一步增强体系的发光活性。三者协同作用,形成了更稳定的杂多阴离子-CV-CTAB三元超分子体系,而β-CD的存在对稀土杂多酸盐与结晶紫的超分子体系稳定不利。

Recently, Shelnutt and co-workers obtained discrete porphyrin nanosheets reprecipitated from their solutions;[3] Sathish and co-workers constructed hexagonal C60 nanosheets using a liquid–liquid interfacial precipitation method;[4] the groups of Yao[5] and Hu[6] prepared singlecrystalline nanosheets of polycyclic aromatics using a surfactant- assisted reprecipitation and a physical vapor transporting method, respectively; and Zhang and co-workers suggested that molecules with intramolecular charge-transfer dipole moments could be grown into quasi-2D nanostructures.

近年来,Shelnutt及其同事由他们的溶液再沉淀获得了离散的卟啉纳米片[3]; Sathish和他的同事用液-液界面沉淀法构建了六边形的C60纳米片[4]; Yao[5]和Hu[6]分别用表面活性剂辅助的再沉淀和物理气相输运法制备了多环芳烃的单晶纳米片;而Zhang和他的同事提出,具有分子内电荷转移偶极矩的分子可以生长成准二维的纳米结构[7]。

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Chrysanthemum of 10 thousand birthday is lax to edaphic requirement, with the arenaceous qualitative loam with fecund, good drainage had better.

万寿菊对土壤要求不严,以肥沃。排水良好的砂质壤土为好。

He unstepped the mast and furled the sail and tied it.

他拔下桅杆,把帆卷起,系住。

Therefore, positively advances the interest rate marketability reform is one of current our country finance reform important tasks.

因此,积极推进利率市场化改革是当前我国金融改革的重要任务之一。