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Finally, in chapter 7, a simple method for the determination of critical micellar concentrations of SDS in different media was proposed based on current-monitoring.

第七章建立了一种简单的利用电泳谱图上电流的变化测定表面活性剂SDS在不同介质中的临界胶束浓度的新方法。

Since there exists some disadvantages such as poor mechanic properties and much higher burning rate pressure exponents (?1) in the fundamental formulations, this work is devoted to the improvements of combustion characteristics and mechanic properties of LOVA propellants. The effects of the crystal shape, size and contents of nitroamine particles, the types of binder, plasticizer and surface-active agents and the contents of NC on combustion performance are studied by closed bomb tests. In the mechanic properties tests, the effects of the types of binders, plasticizers and solid fillers, the interaction between binders and solid fillers and technological procedures on propellant mechanic properties are researched.

针对基础配方具有燃速压力指数远大于1、力学性能差等特点,采用密闭爆发器等试验手段,研究了诸如硝胺粒径、硝胺晶体形状、硝胺含量、粘结剂、增塑剂、硝化棉含量及表面活性剂等因素对燃烧性能的影响;采用抗沖、抗压静态试验方法,对粘结剂、增塑剂、固体填料、粘结剂与固体填料之间的相互作用及工艺条件与力学性能之间的关系进行了研究,提出了改善低易损性发射药燃烧性能和力学性能的技术途径。

Some homologs were synthesized from polyglycerols with different polymerization degree. The polyglycerol dodecyl ether had good capacity of reducing surface tension.

并利用自制的不同聚合度的甘油,合成了一系列同系物产品,该新型非离子表面活性剂具有良好的降低表面张力的能力。

The activty of SOD in vesicle solution is then determined. But still no apparent superactivty is found due to the following reasons: 1. The lowered dielectric constant reduces not only the self-oxidation rate of pyrogallic, but also the activity of SOD; 2. There are no efficient enough interaction between vesicles and SOD.

在上述体系中进行的SOD的活性研究中,没有发现表观超活性,估计是两方面的原因:一是囊泡周围低的介电常数同样也降低了SOD酶的活性,二是由于表面活性剂浓度较小,仅为0.5%左右,使得囊泡体积分数较小,不能与SOD酶发生充分有效的结合。

A highly active hydrogen added catalytic nanometer Ru/C is made by reducing metal ruthenate, getting nanometer ruthenate metal glue under the protection of surface activator, filtering, washing glue solution drawing by the carrier to get highly scattered loading nanometer ruthenate metal catalyst.

本发明涉及一种高活性加氢催化剂纳米Ru/C的制备方法,该方法首先通过化学还原金属钌盐,制得表面活性剂保护下的纳米钌金属胶体,然后用载体吸附制得的胶体溶液,经过滤,洗涤,获得高度分散的负载型纳米钌金属催化剂。

In this paper,studying find that using sandless kaolin and tallow esters as filler and adjuvant can improve dimetachlone's total suspension s.

通过对菌核净的助剂与填料的研究发现,采用含沙量较少的高岭土及脂肪酸酯类表面活性剂可提高菌核净的总悬浮率。

The effects of many parameters, such as the amount of surfactant, airflow rates, pH, NaCl, ethanol and temperature on the solvent sublation were studied. Experimental results showed that a ratio of surfactant to Pb-dithizone complex (2∶1) was the most effective for the removal, with over 97.4% Pb removed from the aqueous solution in 40 min by solvent sublation, at the value of pH 12.6.The solvent sublation process followed first order kinetics. A characteristic parameter, apparent activation energy of attachment of the sublate to bubbles, was estimated at a value of 2.08 kJ/mol.

结果表明,当表面活性剂与硝酸铅物质的量之比为2∶1时,铅去除率达97.4%;体系去除率在pH值为12.6时最高;有机溶剂的影响不明显;少量的乙醇可提高其去除率和去除速率,但过多会产生抑制作用;适量的NaCl能提高体系去除率,但随着浓度的提高呈现下降趋势;去除速率随气流速率增加而增加,体系去除率随温度升高而递增;反应过程遵从一级动力学,表观活化能为2.08 kJ/mol。

Contrasted with the activity of the same reaction in oil-water double phased system, the hydrolyzing behavior of Camlicla Lipolytica Lipase in reversed micellar systems is much like that in oil-water double phased system. The stability and catalyzing activity are both enhanced and give rise to "superactivity". except in reverse micelles composed of cationic surfactant.

实验表明,脂肪酶CLL在反胶束体系中催化水解反应的行为与油-水双相体系中的行为大体相似,在阴离子和非离子型表面活性剂构建的反胶束中,酶的稳定性和催化活性都有所增加,呈现&超活性&。

The micelle shape transformation of tert-octylpheny phenol polyethylene glycol ether (TX-100), sodium dodecyl benzene sulfonate and tetradecyl trimethyl ammonium bromide in heavy water solutions was studied by 1H nuclear magnetic resonance spectroscopy, including an NMR self-diffusion experiment. These experiments showed that the surfactants formed several shapes of micelles (spherical, ellipsoidal, and rodlike) at the respective concentrations which were far above their critical micelle concentration.

运用核磁共振一维氢谱和自扩散实验方法研究了聚乙烯乙二醇异辛酚醚(TX-100)、十二烷基苯磺酸钠和十四烷基三甲基溴化铵三种不同类型的表面活性剂在重水溶液中的胶束形状转变,发现它们在临界胶束浓度以上的各自相应浓度都有胶束形状的变化(由球状转变为椭球状或棒状)。

These results above indicated that ordered mesoporous titanosilicate with different Si/Ti molar ratio could be obtained using trimeric surfactant C_(14-2-14-2-14) as templating agent and the Si/Ti ratio could be as low as 5 without the losing of mesostructure ordering.

上述结果说明以自组装能力强的三聚表面活性剂C_(14-2-14-2-14)为模板剂可以制得不同钛含量的介孔硅钛酸盐材料,尤其是可以得到Si/Ti比低至5的高钛含量介孔硅钛酸盐材料,这对于提高此类材料的氧化催化性能有重要意义。

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