结晶化

Take DMSO swollen treatment and DEA-SO2-DMSO decrystallization treatment for example, the X-ray diffraction and the Tobolsky's intermittent stress relaxation of treated woods were determined during soaking in water, analyzed the effects of water on crystal degree and inter-cohesion of treated woods. According to these continuous relaxation curves measured in water with different temperatures, various thermodynamic quantities were obtained by using Eyring absolute rate theory, and reviewed the chemical reactions in wood which occur in different relaxation process. For the first time quantify these crosslinkings formed in the process of tensional relaxation by using the SMCIR intermittent stress relaxation way, and defined the cross-linking reaction types. In order to find out the contribute of drying to the fixation of deformation of chemically treated wood, stress relaxation of oven-dry untreated and treated wood was measured during the process of temperature elevation and descend, then analyzed the effect of temperature change on relaxation mechanism of treated oven-dry wood. According to continuous relaxation curves of oven-dry treated wood under various constant temperature, calculated the thermodynamics of relaxation process and discussed the mechanism of molecule change in wood, at the same time, also quantified these cross-linkings produced in wood by intermittent method and on the basis of which the model of molecular change during relaxation process of chemically treated was constructed.

以DMSO膨胀处理及DEA- SO2-DMSO非晶化塑化处理为例，测定了两种处理木材在水浸渍过程中的X射线衍射及Tobolsky间歇应力松弛，分析了水对处理木材结晶度及内部凝聚力的影响；通过未处理和两种处理木材在不同温度水中的连续应力松弛测定，应用Eyring的绝对速度反应理论计算并获得了松弛过程中的各热力学量，分析了在水中松弛过程中不同阶段木材内部发生的化学反应；并首次采用SMCIR连续·不连续双曲线应力松弛法定量了轴向拉伸应力松弛过程中木材内部产生的架桥量，明确了交联反应的类型；为了了解干燥对处理木材塑性变形固定的影响，测定了未处理和两种处理绝干木材在温度下降过程和上升过程中的应力松弛，分析了温度变化对处理绝干木材应力松弛的影响；根据多个温度水平下的连续应力松弛测定曲线，计算松弛过程的热力学量，考察了绝干木材在松弛过程中内部发生的分子变化机理，同时也用间歇法定量了木材内部新形成的架桥量，并在此基础上构筑处理木材在松弛过程中内部分子构造的变化模型。

In the passivated REBAR electrode surface formed by ORCs the grain observed from AFM examination is composed of γ-Fe〓O〓 and Fe〓O〓 0 At+0.7V, the passive film on REBAR electrode formed by single-step polarization is composed of Fe (Ⅲ oxide highly doped by Fe〓. In some areas, small γ-Fe〓O〓 particals or some polymeric structure which contains dioxy and dihydroxy bridging bonds between the iron atoms may also exist in the other region.

通过AFM实验观察到的钢筋电极经循环电位扫描至+0.7V形成的钝化膜中具有的结晶颗粒主要由γ-Fe〓O〓和Fe〓O〓·yH〓O0 阶跃电位形成的钢筋钝化膜在+0.7V下主要是由掺杂了大量Fe〓的三价铁氧化物构成，在某些微小的区域可能存在γ-Fe〓O〓微晶，而在另外一些区域则具有聚合物膜的结构。

Focusing on the PGE enrichment mechanism in the basic-ultrabasic intrusions in the Panxi rift, firstly, through the interpretation of TM photograph, data processing of regional geochemical exploration and geophysical prospecting results of gravity, magnetic force and seism, we analyzed the controlling effect of structure and magmatic movement on the PGE mineralization; Secondly, through the study of volcanic apparatus, petrography, measurement of comprehensive geochemical section, isotope tracing and dating of typical PGE-rich melanocratic rock series, we discussed the sources of the PGE-bearing mafic-ultramafic intrusions and basalts, their timing, evolvement sequences, the geochemical processes of magma crystallization and fractionation, and the relationship between magma evolution and structural development; Finally, through the analysis of PGE and chalcophile elements concentrations in the melanocratic rock series and the contrastive study with the Noril''sk magmatic Ni-Cu-PGE sulfide deposit, its related continental flood basalts and Siberia Traps, we discussed PGE mineralization characteristics and its enrichment mechanisms in the melanocratic rock series in the Panxi rift.

本项目首先围绕川西地区主要的PGE矿床及伴生矿的地质环境和有关的地质构造背景，通过TM卫片解译、区域化探和重、磁及地震物探资料分析，总体把握构造及岩浆活动对PGE成矿的控制作用；然后通过对典型富PGE暗色岩套的火山机构地质构造、岩石岩相学、地球化学、同位素定年和示踪等方面的工作，分析本区基性－超基性含矿岩体与喷出岩之间的成岩物质来源、侵入时代及演化序列，研究该区同一岩浆房分异结晶的地球化学过程及其随构造发展的耦合关系；最后通过对暗色岩套PGE地球化学剖面分析以及与俄罗斯诺里尔斯克陆内裂谷溢流型玄武岩中PGE矿化的岩石－构造环境对比研究，探讨该区暗色岩套中的矿化特点和富集部位及其PGE富集机制。

For the first time, enantiomers of C2-symmetric 1,1 -spirobiindane-7,7'-diol were resolved with crude menthyl chloroformate by phase-transfer catalysis in the presence of tetrabutylammonium bromide. The reaction was carried out at 0℃-rt. The diastereomers of SPINOL bis-menthyl carbonate can be separated by simple crystallization using alcohol. The hydrolysis of the diastereomers was carried out via aqueous NaOH/EtOH solution.

首次通过相转移催化的方法对螺双二氢茚二酚进行了有效的拆分，用L--氯甲酸薄荷醇酯做拆分剂，以四丁基溴化铵为催化剂在0℃-室温下进行酯化反应生成非对映体衍生物，以乙醇作溶剂，通过重结晶的方法分离衍生物，在水-乙醇混合溶剂条件下，用强碱NaOH或KOH分别水解，制得相应的光学纯度大于99%ee的两个异构体SPINOL，其中总收率：--SPINOL，78.2%；--SPINOL，80.6%。

The results show that myristic acid radical anion of precursor Zn0.78 Al0.2220.22c13h27COO0.81H2O can be almost completely replaced by complex anion [La(TiW11 O39)2]^3- under special controlled reaction conditions.

结果表明，该产物中[La(TiW11O39)2](上标 13-)配阴离子沿其长轴垂直于层板的方向分布于水滑石层板间，产物有规整的层状结构、大的层间距(d003=3.29nm)、良好的结晶度和热稳定性，产物对二甘醇与苯甲酸的酯化反应、二甘醇的脱水环化反应和苯甲醛的氧化反应具有良好的催化性能。

To study the modulating effect of polysaccharide and protein secreted by Sphaerotilus upon the mineralization behaviors of Fe3 gel, the authors investigated the nucleation and crystallization processes of Fe3 gel inside and around the Sphaerotilus cells which were growing in the mineralization systems with urea and Stoke substrate.

本文通过观察在尿素和Stoke培养基中生长的球衣菌细胞壁内及其周围氢氧化铁凝胶的矿化过程，研究球衣菌分泌的多糖和蛋白质对氢氧化铁凝胶矿化结晶行为的调控作用。

The main influence factors yn sulphonation and crystallization process has been investigated and the optimum conditions of process have been foudn.

摘 要：介绍了杀虫单的介质法磺化反应及结晶工艺的研究，探讨了影响磺化收率和杀虫单粉剂含量及出粉率的主要因素，找出了生产高纯度杀虫单粉剂的最优工艺条件。

Parasitism and wedging-form of crystals, which often appear at regions with stress concentration and crystal defect, showed that stress, brought on by unequilibrated crystallization, existed on crystal-melt interface.

楔化、寄生晶容易在晶体应力较大的部分和缺陷处出现，楔化、寄生晶的出现反映出熔体的结晶过程处于非平衡状态，引起晶—液界面处的较大应力。

The results show that the properties of different acetylated chitosan membranes have little difference. But they all have high moisture adsorption and transparency, a certain extent permeation and adsorption of bovine serum protein, and can be degradated by lysozyme in vitro.

结果表明乙酰化壳多糖膜的性质随着乙酰化程度的不同性质会有所不同，但它们都有很好的吸水性和透光性，有比较高的结晶性，在体外可被溶菌酶降解，对于小牛血清蛋白有一定的吸附性。

After crystallization silicide is finished, the density of the silicified wood is very high, the hardness can also reach 6.5-7.0 grades, like glass, much harder, similar to the gem (more than 7 grades) than the marble (4 grades), the timber of so high hardness, it can not moved that the wood is sawn, can't saw to cut open with the general stone material either.

在硅化结晶完成之后，硅化木的密度是很高的，硬度也可达到6.5-7.0级，与玻璃一样，比大理石(4级)要硬得多，与宝石7级以上）相似，如此高硬度的木材，木锯是啃不动的，也不能以一般石材来锯剖。

Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克，果实色泽鲜艳，汁多味浓，甜酸适口，离核仁甜，清末时就驰名陕、甘两省，清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异：红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感，ED90值分别为47.65、71.67和29.17g/hm2；春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感，ED90值分别为96.91、114.20g/hm2；而番茄不敏感。