结晶化

Study on the Crystallization Process of Labeled GL-7-ACA Acylase CA130 Complex 7β-bromoacetyl amino cephalosporanic acid (BA-7-ACA), an analog of glutaryl-7-amino cephalosporanic acid (GL-7-ACA), can inhibit and specifically alkylate GL-7-ACA acylase (CA130) from Pseudomonas sp. 130, forming a carbon-carbon bond between BA-7-ACA and the C-2 on indole ring of Trp-β4 residue of CA130.Here we reported that BA-7-ACA labeled CA130 (BA-C130) could self-catalyze the hydrolysis of BA-7-ACA during crystallization process. The hydrolysis was confirmed to be a reaction analogous to the one of GL-7-ACA by comparative MALDI-TOF (matrix-assisted laser desorption/ionization-time of flight) spectrometry analysis.

二、GL-7-AcA酰化酶CA130标记复合物的结晶过程研究溴乙酰氨基头孢烷酸（7β-bromoacetyl amino cephalosporanic acid，BA-7-ACA）作为戊二酰-7-氨基头孢烷酸（GL-7-ACA）的类似物，不仅能够抑制GL-7-ACA酰化酶CA130的活力，而且能通过在BA-7-ACA和CA130的β亚基第四位色氨酸吲哚环二位碳原子之间形成碳-碳共价键而将CA130特异的烷基化。

After acetylation of cellulose, the allomorph of CTA changed and the crystallinity decreased; however, amorphism is dominant in CDA obtained by hydrolysis from CTA and spinning resulted in the reduction of crystallinity in CDA.

纤维素乙酰化后形成CTA，其晶型发生变化，结晶度降低；而CTA水解后得到的CDA，无定形占明显优势，纺丝过程中的取向又会进一步降低CDA的结晶度。

The results show that the flow stress decreases with increasing deforming temperature and increases with increasing strain rate. The flow stress of the alloy during hot compression deformation can be described by constitutive equation in hyperbolic sine function with a hot deformation activation energy of 196.27 kJ/mol. Partial recystallization takes place in the alloys deformed at a high temperature or at a low strain rate, and large number of dislocations and subgrains are observed in the alloy. The elongated grains observed in the samples coarsen with increasing temperature and decreasing strain rate. Correspondingly, the subgrain size increases and the dislocation density decreases. The main soften mechanism of the alloy transforms from dynamic recovery to dynamic recrystallization.

结果表明：Al-Cu-Mg-Ag耐热铝合金在热压缩变形中的流变应力随着温度的升高而减小，随着应变速率的增大而增大；该合金的热压缩变形流变应力行为可用双曲正弦形式的本构方程来描述，其变形激活能为196.27kJ/mol；在变形温度较高或应变速率较低的合金中发生部分再结晶，并且在合金组织中存在大量的位错和亚晶；随着温度的升高和应变速率的降低，合金中拉长的晶粒发生粗化，亚晶尺寸增大，位错密度减小，合金的主要软化机制逐步由动态回复转变为动态再结晶。

This is because the crystal layers that form on it are not static; they change with temperature and light intensity.

这是由于氢化金刚石上形成的结晶层不是静态的，这些结晶层会随着温度的高低和光线的强弱而变化。

We derived the scalar quantity of magnetic quasi-static vector equation in the electromagnetic crystallizer in the cylindrical coordinates by assuming condition for the mathematical modeling of the electromagnetic crystallizer and dimensionless method and reduction of parameters of electromagnetic governing equations.

在假设了对电磁结晶器数学建模的依据条件下，通过对电磁控制方程组进行参数无量纲化和简化，在柱坐标系中，推导出电磁结晶器内的磁准静态矢量方程的标量形式。

Optimal conditions for crystallizing have been investigated on a laboratory scale pellet reactor initially seeded with phosphorite.

在流化床诱导结晶法除氟研究中，确定了以磷灰石为结晶核的氟化钙结晶过程中的最佳工艺参数。

Epitaxial growth of GaN on sapphire and novel substrate LiAlO〓 1 The growth mechanism of GaN on sapphire substrate was investigated using AFM, X-ray diffraction, X-ray double crystal diffraction, Rutherford back scattering etc.

阐明了衬底表面的氮化处理、缓冲层的生长对外延膜结晶形貌、结晶质量、以及外延匹配关系的影响规律。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

In order to achieve the low temperature process, we used metal-induced lateral crystallization to fabricate it . Ni can lower the temperature of process and annealing time because the reaction between Ni and Si of forming Nickel Disilicide(NiSi2) which lowers the annealing time in further process.

在低温制程上采用的是金属侧向诱发结晶(Metal-induced Lateral Crystallization)方式，此方式是使用镍降低制程的温度以及生长时间，原理主要是藉由镍与矽之间的反应产生二矽化镍(NiSi2)，进行退火后可产生金属诱发结晶与金属侧向诱发结晶两种结构，再进行其微结构观察。

At first, the broth was acidified, then centrifuged to get mycelia, which was heated and powdered; finally we use acetic ether to soak the powder. After that, the phase of acetic ether was washed using the solution of ammonium sulfate and the solution of ethanedioic acid, then concentrated to gain pulps. It was crystallized at 4℃.The coarse crystals was decolorized by activated carbons, the pure needle crystal of lovastatin was obtained.

发酵液经酸化处理后，离心得到菌体，烘干后过筛得到菌粉；用乙酸乙酯浸泡，乙酸乙酯相需用(NH_4)_2SO_4溶液和草酸溶液洗涤两次；乙酸乙酯相经薄膜浓缩得到浆状物，于4℃结晶，得到粗晶体；再经粉末活性炭脱色和重结晶后得白色针状结晶，为lovastatin的纯品。

Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克，果实色泽鲜艳，汁多味浓，甜酸适口，离核仁甜，清末时就驰名陕、甘两省，清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异：红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感，ED90值分别为47.65、71.67和29.17g/hm2；春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感，ED90值分别为96.91、114.20g/hm2；而番茄不敏感。