烯烃

In chapter 2, concerning the chemistry of many kinds of olefin-coordinated alkoxycarbene iron complexes and their isomerized products previously synthesized by our group, we examined their thermolysis reactions and many novel thermolysis products were isolated.

第二章中，对于我们小组以往合成的各类烯烃配位的铁卡宾络合物及其异构化产物，为了研究其反应性能，我们从热解反应着手，研究了一系列烯烃配位的铁卡宾络合物及其异构化产物的热解反应，获得了一系列新奇的热解产物。

In part one, the reactions of some active fluorine-containing compounds such as 2, 2-dihydropolyfluoroalkanoic acids and ethyl 2-hydropolyfluoroalkenoates were studied and various fluorine-containing heterocyclic compounds were synthesized. Using 2, 2-dihydropolyfluoroalkanoic acids as the starting material, 4-fluoroalkyl quinolin-2-ols, 2- [ -1-hydropolyfluoro-1-alkenyl] -4H-3, 1-benzoxazin-4-ones, 1-aryl -4, 9-dihydro-3-fluoro-alkyl-1H-pyrazo [3, 4-b] quinolin-4-ones, 5-fluoroalkyl-12H-quin olino [2, 1-b] quinazolin-12-ones, 4-fluoroalkyl-1, 3-dihydro-1, 5-benzodiazepin-2-ones and 4-fluoroalkyl-2H-pyrido [1, 2-a] pyrimidin-2-ones were synthesized through its condensation reaction with anilines, anthranilic acid, N'-aryl-o-aminobenzamides, o-nitro aniline, o-amino pyridine and their derivatives and the subsequent transformations. 5-Fluoroalkyl isoxazolidines, 3-fluoro-3-fluoroalkylisoxazolidino [4, 3-c] quinolin-4-ones, 3-fluoroalkylisoxazolino [4, 3-c] quinolin-4-ones and 2-aryl-3per fluoroacylindoles were synthesized by inter-and intramolecular 1, 3-dipolar cycloaddition of fluorine-containing olefins and nitrones.

第二部分，我们研究了α，α-二氟苄基卤类化合物的亚磺化脱卤反应、产物的转化及全氟烷基亚磺酸盐与芳环化合物的全氟烷基化反应，发现全氟苄基碘或溴及α，α一二氟苄基溴在保险粉等亚磺化脱卤试剂引发下可生成相应的亚磺酸盐；全氟苄基亚磺酸盐与氯气或溴反应可生成全氟苄基磺酰氯或磺酰溴；在烯烃存在下，全氟苄基碘则与烯烃发生加成反应，生成相应的1：1加成产物；在三价醋酸锰的作用下，部分芳香化合物如茴香醚，二甲氧基苯，吡啶，喹啉等可以和过量的全氟烷基亚磺酸盐发生双全氟烷基化反应，反应表现出一定的区域选择性，产率良好。

Effects of different additives such as sulfurized olefin,mixtures of amine phosphates,ester thiophosphates,N-containing agents and ashless rust-resistant agents on the emulsion stability ,EP/AW properties and rust-resistance of industrial gear oil were studied.

研究了硫化烯烃、磷酸酯胺盐、硫磷酸酯极压抗磨剂，含氮杂环衍生物多功能添加剂和防锈剂等，对工业齿轮油抗乳化性能、极压抗磨性能、防锈性能的影响；以及硫化烯烃、磷酸酯盐极压抗磨剂与含氮杂环衍生物多功能添加剂之间的协和效应。

The speed of electrophilic addition reaction of Alkene is inferenced greatly by the electron-withdrawing group or electron-releasing group on C=C of Alkene And the main addition product is decided by stability of carbonium ion.

烯烃C=C上连有供电子基和吸电子基时，对于烯烃亲电加成反应速度的影响是很大的。加成产物是由碳正离子中间体的稳定性来决定。

It is seen that oxygen group function of additives is very remarkably in tribological characteristics, that is EP property of dihydroxy docosanoic acid without active element is very near to that of SO with active element sulfur.

双羟基廿二酸的极压性与不含氧基团的硫化烯烃十分接近，以液体石蜡为基础油，最大无卡咬负荷P〓值，前者为539N，后者为588N，再者相差49N，可以看出，氧基团的作用是十分显著的，即无活性元素的双羟基廿二酸的极压性可以十分接近于含活性元素的抗磨极压剂硫化烯烃。

Methodologies for stereoselective synthesis of alkenes are of great interest in synthetic organic chemistry since many biologically active compounds occuring in nature possess the structural skeleton of disubstituted or trisubstituted alkenes.

烯烃的立体选择合成方法学研究是有机合成化学中的重要课题，因为许多重要的天然产物中均含有双取代或三取代烯烃的结构单元。

The present invention relates to an ethylene/alpha-olefin interpolymer product comprising at least one alpha-olefin interpolymerized with ethylene and, characterized in at least one aspect, as having improved properties when utilized in a hot melt adhesive formulation.

本发明涉及包括至少一种与乙烯互聚的α-烯烃的乙烯/α-烯烃共聚体产物，其特征为在至少一方面，当用于热熔粘合剂配制剂时具有改进的性能。

The free-radical addition reaction of malonic ester with a series of alkenes under the uniform conditions has been studied.

在相同反应条件下，进行一系列烯烃与丙二酸二乙酯的加成反应，求得产率与烯烃结构间的定量关系，即反S型曲线。

The catalyst of RFG-DQ and DOCO(1) can both reduce the olefine content of gasoline dramatically, with the yield of LPG ,diesel and coke reduced and the yield of gasoline increased, as well as octane number of gasoline reduced more greatly.The olefine content of gasoline can be effectively reduced by optimizing the operation condition, lowering the reaction temperature, increasing the catalyst-to-oil ratio and using catalyst, which can improve the gasolines quantity and upgrade the gasoline.

通过优化操作条件、降低反应温度、增大剂油比和采用有效降烯烃催化剂等措施可以有效的降低催化裂化汽油的烯烃含量，提高催化裂化汽油的产品质量，达到我厂汽油产品升级换代的目的。

Olefinic oxides,such as epoxides,ketones and aldehydes mainly prepared by oxidation of olefines,are important chemical intermediates, which are widely used in fine chemicals,polymer materials,organic synthesis,perfumer and medicament.

烯烃的氧化物是重要的化工原料，主要通过烯烃的氧化反应得到，广泛应用于精细化工、高分子材料、有机合成香料及医药等行业。

He and Nina moved to California and lived at 2005 Ivar Street, Apt.

他和Nina搬到加州，并在2005年伊瓦尔街，公寓生活。

Droperidol （ potently inhibits transfected HERGchannels and this is the probable mechanism for QT prolongation.

氟哌利多有效地抑制了转染的 HERG 钾通道，可能是 QT 间期延长的机制。