烯烃

The reaction of α-hydroxyketone with Michael acceptor nitroalkene.was studied. After many experiments, we then found that in the presence of Zn2 and cinchonine, the α-hydroxyketone could successfully react with nitroalkene. Under our optimized condition, we gained the 95% yield of product with the ratio of syn : anti of 3:1 and 72% ee value for syn-product.

有机碱作用下α－羟基酮对硝基烯烃的加成反应研究研究了α－羟基酮类化合物与Michael受体硝基烯烃类化合物的反应，通过分析和实验发现在Zn2和辛可宁的作用下α－羟基苯乙酮能够与硝基烯烃化合物顺利反应，在优化的条件下以95%产率和3：1的Dr主要得到顺式产物，其中顺式产物的ee值最高为72%。

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解，随着烯烃配体上取代基的不同，而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

The industrial manufacturing technique, the trend of development of neohexene ,and the characteristics of these production technique were reviewed and analyzed in the paper, particularlyabout the selective dimerization of isobutylene and metathesis of βdiisobutylene with ethylene were introduced.

对新己烯生产技术的现状和今后的发展趋势进行了综述，分析了由异丁烯和乙烯生产新己烯的技术特征，讨论了烯烃二聚工艺和催化剂、烯烃复分解工艺及相应的催化剂，指出了各种工艺的优势和不足。

The result shows at the mild condition chain olefin that nCl7, polyethylene can be cracked into solutions of ethane, propane, butane, benzene and toluene and other small molecular compounds, polyethylene reacted fluids are mainly composed of a-olefin at the range 12 to 38, by which α-ωdiene, saturated hydrocarbon and aromatic hydrocarbon, anthracene, phenanthrene of albocarbon series are contained.

结果表明，在温和条件下可以将链状烷烃如正十七烷烃、聚乙烯通过微波及炭催化剂的作用，裂解成乙烯、丙烷、丁烷、苯、甲苯等溶剂及小分子化合物。聚乙烯反应液体产物以碳数在12~38范围的α-烯烃为主，也产生α-ω二烯、饱和烃及芳烃，芳烃主要有萘系列、葱、菲等。

The results of AD reactions are as follows:(1) When the AD reaction of eight olefins was performed at 0.5mo1% OsO〓 and 2mol% ligand 8 in PEG/NMO system, the diols were obtained in 78～90% yields and 78～96% ees (except for trans-5-decene and ally naphthyl ether).

催化结果如下：(1)在PEG/NMO体系中，将配体8用于八种烯烃的AD反应，配体、OsO〓和底物的摩尔比为0.02/0.005/1时，化学产率为78～90％，除反式-5-癸烯和萘基烯丙基醚较低外，其它六种烯烃的相应二醇产物的ee值为78～96％。

The result of potassium malonyloxyborohydride as a new hydroboration reagent reacts with terminal alkenes and alkynes is described.

介绍新的硼氢化试剂丙二酰氧基硼氢化钾与链端烯炔烃的作用，烯烃的硼氢化物在PTC条件下，插入∶CCl2 ，可得饱和羧酸；炔烃则难以与之硼氢化。

This PhD thesis mainly summarizes the original results on studies of aromatic amide-derived phosphines,including the precatalyst system consisting of Aphos and Pd_2 and the applications for promoting room temperature Suzuki cross-coupling of aryl chlorides and aryl/vinyl bromides,respectively,with aryl/vinyl boronic acids,and alkyl boranes.

本博士学位论文主要总结了对芳基酰胺衍生的膦配体的研究，以及该类型配体与Pd_2组成的催化剂在室温下催化氯代芳烃、溴代芳烃、溴代烯烃分别同芳基硼酸、烯基硼酸及烷基硼试剂进行的Suzuki偶联反应中的表现。

The C2 to C5 and heavier acetylenes and dienes in a thermally cracked feed stream are hydrogenated without significantly hydrogenating the C2 and C3 olefins.

使经过热裂解的进料物流中的C2－C5及更重的炔烃和二烯烃加氢，而不使C2和C3烯烃发生显著的加氢。

In particular, the present invention concerns a process and an apparatus for continuous polymerisation olefin monomers like ethylene and other monomers, wherein an olefin monomer is polymerised in slurry phase in an inert hydrocarbon diluent in at least one loop reactor.

本发明尤其涉及连续聚合烯烃单体如乙烯和其它单体的方法和设备，其中烯烃单体在至少一个回路反应器内惰性烃稀释剂中的浆料相内聚合。

When the reaction was finished, the ligand was extracted with CH2Cl2 and precipitated upon addition of diethyl ether followed by filtration.

2配体2在丙酮/水体系中催化/又种烯烃的AD反应，非链端烯烃的立体选择性(80一99%ee)明显优于链端烯烃(51一62%ee)。

He and Nina moved to California and lived at 2005 Ivar Street, Apt.

他和Nina搬到加州，并在2005年伊瓦尔街，公寓生活。

Droperidol （ potently inhibits transfected HERGchannels and this is the probable mechanism for QT prolongation.

氟哌利多有效地抑制了转染的 HERG 钾通道，可能是 QT 间期延长的机制。