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New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.
本工作的新贡献如下:(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2,3-双(2,6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2,6-二[1-(2,4,6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上,研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响,研究表明: 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理,可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体; 2、BET,XRD,IR,SEM,GPC和DSC研究表明,脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。
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The output of electron acoustic signal in the ferroelectrics is calculated on the basis of their piezoelectric properties. The results show that the magnitude of electron acoustic signal not only related with beam currents, beam power and modulation frequency, but also with sample properties especially electric parameters such as dielectric constant and spontaneous polarization.
本文首次以典型的铁电BaTiO〓材料为试样,从其具有的压电性出发,推导了这类材料的电声信号理论表达式,结果表明电声信号的大小不仅与实验参数如入射电流、入射电子能量以及调制频率等有关。
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With this approach, a mathematical model of ASVG is developed. The method is simple and can be used to analyze the detailed internal properties of an ASVG. It overcomes the disadvantages of the two methods generally used, one is a method for modeling an ASVG by getting differential equations according to the topology of the ASVG circuit, which is very complicated and it is difficult to get a unified model expression of an ASVG; the other is a method for modeling an ASVG by considering the whole ASVG as a voltage source, which is too simple to analyze the detailed internal properties of ASVG.
该方法既克服了根据ASVG装置拓扑结构列写微分方程组的建模方法过于复杂且不易获得统一模型表达式的缺点,同时又克服了将ASVG装置等效为电压源的建模方法太简单而无法用于分析ASVG装置内部性质的缺点,具有建模简单又能分析ASVG装置的内部性质的优点。
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And the devices'properties and improve the properties to prepare the artificial boundary. The bi-epitaxial YBCO superconducting film with 45°grain boundary in a-b plane was made for the first time in China in this article by magnetic sputtering instrument that was designed and fabricated by ourselves. The x-ray θ~ 2θ scan 、Ф scan、rocking curve、non-symmetry diffraction and SEM、 TEM、AES etc. were utilized in the study.
为此,本工作采用自行设计制造的全金属密封超高真空磁控溅射设备,利用x射线θ~2θ扫描、Ф扫描、摇摆曲线、非对称衍射及SEM、TEM、AES等分析测试手段,在国内首次、也是至今唯一的一家,制得a—b平面内具有45°人工晶界的双外延YBCO超导薄膜,并进而得到双外延晶界Josephson结。
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The complexes of disk - like crown ether liquid crystal with Eu have theproperties of liquid crystals and havn't the properties of fluorescence. The complexes of disk -like crown ether liquid crystal with Eu and β-diketone have the properties of fluorescence and electroluminescence.
盘状冠醚液晶Eu配合物具有液晶性质而无荧光特性;盘状冠醚液晶与EuⅢ)和β-二酮形成的配合物具有荧光特性,和电致发光性质。
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Dynamic mechanical analysis,mechanical properties and the thermal dilatability measurements were used to study the effects of SF content on dynamic mechanical properties,impact strength,bending strength,bending modulus,specific strength,specific modulus,wear resistance and thermal dilatability.
采用动态力学、力学性能、热膨胀性能等测定研究了剑麻纤维的加入量对复合材料的动态力学性能、冲击强度、弯曲强度、弯曲模量、比强度、比模量、耐磨性能、热膨胀性能的影响,用扫描电镜观察了材料冲击断面和磨损面的形态。
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In this dissertation, the ideas of simulating directed Hamilton path problems by sticker systems are designed using their massive parallelism; Then some properties of directed graphs and sufficiency and necessity conditions of existing Hamilton paths in graphs are presented based on the analysis to directed Hamilton path problems according to the properties of languages generated by the sticker systems.
本文利用粘贴系统的巨大并行性,首先设计了模拟有向哈密顿路问题的粘贴系统,然后通过此粘贴系统所产生语言的性质对有向哈密顿路问题进行分析,给出了有向图的若干结构性质以及图中存在有向哈密顿路的充要条件。
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Those results make basis for fabricating discontinuously reinforced titanium matrix composites with high properties and broadening the application area of discontinuously reinforced titanium matrix composites. They also provide practical way for commercial production of titanium matrix composites with high properties.
这些研究为以后制备高性能的钛基复合材料和拓展钛基复合材料的应用领域打下了坚实的理论基础和为批量生成提供了实用途径。
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It is very difficult to eliminate these influence factors completely by conventional treatment. Surface properties and surface treatment of ultrafine red phosphorus and MMT and their interface properties with polymer matrices were studied in this thesis. The results were characterized by GC, FTIR, XRD, DTA, TG, XPS, UV, SEM, TEM and other physical and chemical methods. The main contents are as following: 1. The study of factors influencing ultrafine red phosphorus's invariability and phosphine liberation indicated red phosphorus undergone oxidation and dismutation reaction in air, and trace ion of iron, copper and nickel fastened water absorption and oxidation, in which the effect of copper ion was the most, while aluminium and zinc ion could slow down red phosphorus'oxidation, and silver ion had the best effect on red phosphorus moisture absorption. Inhibitors such as aluminium hydroxide, magnesium hydroxide, organic phenol and ferrous potassuim cyanide had a good effect on reducing red phosphorus moisture absorption and restraining phosphine liberation.
本文围绕纳微米材料的表面处理及其在高聚物基体中的应用这一主题,系统地研究了超细红磷和蒙脱土两种常见材料的表面特性、表面处理方法及其与高聚物基体的界面特性,通过气相色谱、红外光谱、X射线衍射、差热、热重、X射线光电子能谱仪、紫外光谱、扫描电镜、透射电镜等现代分析仪器以及其它物理、化学方法对实验结果进行了表征和分析,全文主要内容如下: 1、对影响超细红磷安定性的因素以及磷化氢的缓释研究表明:红磷在空气中发生缓慢氧化、歧化反应,微量的铜、铁、镍等金属离子增加了它的吸水和氧化速度,其中铜离子的作用最为明显,而铝、锌等离子减慢了红磷的氧化速度,银离子对减少红磷的吸湿性效果最好。
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Effects of dispersant, reaction temperature and time on soluble properties and the grafting properties were discussed.
研究了反应温度,引发剂用量,反应时间对接枝性能的影响及溶解性能。
- 相关中文对照歌词
- Properties Of Propaganda (Fuk This Shit On Up)
- Get 'Em Out By Friday
- PEEWAGON
- Reppin Time
- The Flow
- Rabbit Song
- The Big Picture
- Chain Link
- Poet Laureate II
- Only Slaves D.R.E.A.M.
- 推荐网络例句
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Mr. Putin said there were signs of genocide against the Ossetian people.
普京说,有迹象表明对南奥塞梯人进行了种族清洗。
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What I'm trying to say, Tristan is...
特瑞斯坦。我想说的是。
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Petersen largely pays attention to nanotech, but she also draws connections between technology and how it's used.
Petersen的注意力主要放在纳米技术上,不过她也研究技术与如何使用之间的联系。