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The comonomer in the copolymer by cat247 is trend to isolated. A few amount of comonomer could make the melting point remarkably decreased and maintain the crystalline at a relative high level. This catalyst can be use to produce the material with low melting point and high intensity such as packing film with low hotsealing temperature. The copolymer by cat24 is characteristic of uniform comonomer distribution and low melting temperature and crystallinity. Therefore, this catalyst could be used to produce LLDPE and POE according the comonomer content; cat246 has a strong copolymerization ability, and the resultant polymer has relatively high blockiness. If this trend is strengthened by adjustment of polymerization condition, the polymer can be used as thermal plastic elastomer with random and crystalline blocks.

由于各个催化剂所产生的聚合物各具特点,所以其潜在的工业用途不同。cat247的产物中共单体趋于孤立分布,极少的共单体即可使熔点明显降低而结晶度仍保持较高水平,有利于制备低熔点、高强度的材料(如低热封温度的包装膜等)。cat24的催化聚合产物无规程度比较高,对降低熔点和结晶度都十分有效,通过控制产物中共单体含量的多少,可以生产LLDPE和POE;cat246共聚合能力强,且产物有嵌段倾向,通过调整聚合条件强化这一倾向后,可以用来生产具有无规-结晶嵌段结构的热塑性弹性体。

For example, the viscosity anomalies observed in theextremely dilute concentration region and the enhancement of Huggins coefficientof short polymer chain and branched polymer, have not been interpreted unitarily.

例如极稀浓度区粘度特异行为的出现,短链和支化高分子的斜率常数的异常增大,都没有统一的理论解释。

By studying the membrane preparation process for the typical membrane materials of polystyrene and cellulose acetate as well as a new type membrane material of polyvinyl butyral,the effects of operating parameters on the membranes structure are determined.By the study on the thermodynamics involved in the ternary systerms of ScCO_2/solvent/polymer and the calculation of theoretical ternary phase diagrams,the phase demixing behavior during the membranes formation by ScCO_2 induced phase separation process are described.By studying thermodynamics involved in the quaternary systerms of ScCO_2/solvent/additive/polymer,the effect of a low molecular weight additive on the quaternary phase diagram and dimixing speed are revealed.

通过对传统膜材料聚苯乙烯、醋酸纤维素及新型膜材料聚乙烯醇缩丁醛进行ScCO_2诱导相转化制膜工艺的实验研究,给出了操作参数对膜形态结构的影响规律;通过研究ScCO_2/溶剂/聚合物三元体系热力学问题,并计算出相应铸膜体系的三元相图,对ScCO_2诱导相转化膜制备过程的分相成膜行为进行了分析与描述;通过研究ScCO_2/溶剂/小分子添加剂/聚合物四元铸膜体系的热力学问题,并借助于四元体系理论相图计算的结果,分析了小分子添加剂对相分离过程的影响。

The effect of crystallization process from polymers, control laws of particles from the long-chain structure of polymer, as well as the self-assembly regulatory mechanism of nano-particles from polymer are investigated , through the control of its morphology and properties of precursor order to get large aperture, high specific surface area, has good thermal stability and catalytic cerium oxide particles.

研究聚合物对结晶过程的影响、聚合物的长链结构对粒子自组装的控制规律以及聚合物对纳米粒子自组装的调控机理,通过控制其前驱体的形貌和性能,以期得到大孔径、高比表面积、具有良好的热稳定性及催化作用的氧化铈颗粒。

However, the biggest difference between them is that polymer gels is chemistry association and hydrophobic associating polymer solution is physics association, and the intension of molecule chain coupling between them is different, too.

建议对疏水缔合聚合物溶液进行特性评价时应该同时结合HPAM溶液和聚合物凝胶溶液特性评价方法,开展深入的疏水缔合聚合物溶液与聚合物凝胶的对比研究工作。

The molecular weight dependence of the distribfition of polymer molecules between the coacervate and the dilute phases on the phase separation of polymethylmethacrylate-acetone-methanol system has been proved to follow the relation first derived by Flory for binary systems: f"_j/f′_j = Qe~_j where f"_j and f′_j are the weight fractions of the polymer molecules of molecular weight M_j in the coacervate and in the dilute phases respectively, while Q and σ are parameters.

1。聚甲基丙烯酸甲酯-丙酮-甲醇体系的两次分相实验用θ-溶剂中的沉降速度法测定分相前试样和浓相的分子量分布曲线,得到高分子在浓稀相重量分配的分子量依赖关系 f_j=Qe~证实Flory的溶度函数形式与实际相符,并适用于三元体系的相分离,但Q值与两相体积比R值并不相同。 2。再分级使级分的分子量分布宽度随再分级次数的增加而减小,通常认为到第三次再分级其效果已不显著并不确实。

And VTMS is added in late stage of polymerization, in this situation the system has the lowest coagulum. When the hydroxyl value of such polymer increases, the coagulum decreases; and solid content of such polymer increases, the coagulum increases greatly, so it is difficult to get higher solid content emulsion.

采用正交实验方法,通过对有机硅改性丙烯酸乳液聚合过程中凝聚物含量、乳液粘度影响的研究,确定的最佳的反应条件是:以SLS/OP为乳化剂、比例为4/6、用量为2%、丙烯酸单体的用量1.5%、反应温度为75℃、改性剂VTMS用量是1.5%、改性剂后加入方式下聚合反应过程中有最低的凝聚物含量。

This stage takes raw materials from the earth and transforms them, with the addition of energy, into polymers. The raw polymer is then shipped in bulk to the compounder which mixes it with additives in order to bestow the polymer with the required properties for its future application.

简而言之,这个阶段就是利用能量把氧化原材料转换成为聚合物,接着将未经加工的聚合物成批传送到混合器,并将其与添加剂混合,根据该模具未来的应用为其提供相应的性能。

This is due to the large amount of water, the polymer has a high degree of branching structure, adding a small amount of water so that they can support each other elements of the polymer condensation to form larger, supporting a higher degree of macromolecules, Generate up to form a mesh structure on the gel.

这是由于水用量较大时,聚合物已经呈现较高支化度的结构,少量水的加入就可以使这些支化的聚合物分子相互缩聚形成更大、支化度更高的大分子,直到生成网状结构时就形成凝胶。

At last the conductibility of base and doping conducting polymer was mensurated The researchful result shows that the new conducting polymer ,whether doping or not, all have better fluorescence and conductivity at the same time, and the complexes have better fluorescence coordinated with Al3+、Zn2+ in solution.

经上述的研究表明,新型的导电聚合物无论是本征态还是掺杂态,既具有比较好的导电性,同时具有比较好的荧光特性,在溶液中与Al3+、Zn2+配合形成的配合物具有较好的荧光特性。

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I want to be a big fish in a small pond.

我要做一条在小池塘里的大鱼。

While the software functioned well, we did not feel the same about their customer support!

虽然该软件运行良好,我们没有同样的感觉他们的客户支持!

I have heard nothing to the contrary.

我还没有听到任何相反的情况。