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In the dissertation, a new stabilization method, equal-density method was adopted to prepare modified asphalts with storage stability at high temperature. In this method, a compound was prepared by premixing polymer and filler, and the compound was mixed with asphalt to prepare Polymer-Modified Asphalt by changing the ratio of polymer and filler. The asphalts with good storage stability were formed with the addition of filler, by regulating the density difference between polymer and asphalt. With identifying the effect of composition factor and the technique conditions on mechanical properties of polymer/filler compound and the molecular distribution of the polymer, identifying the effect of composition factor and the technique conditions on the properties and structure of polymer/filler modified asphalt, Styrene-Butadiene-Styrene copolymer, Low Density PolyEthylene, Styrene-Ethylene-Butadiene-Styrene block copolymer modified asphalts with good storage stability and performance were prepared. Rheological method, gel content analysis and swelling measurement were adopted to elucidate the interaction between the polymer and filler. Filler reduced the difference between the polymer and asphalt with the premixing technique, which led to the improvement of the storage stability of the modified asphalts. The thermo-oxidative aging process of base asphalt and PMA were studied and the effect of antioxidant additives on the base asphalt and PMA were analyzed.

本论文采用等密度方法，即预先混合聚合物与填料制备复合物，复合物在沥青中会吸收油份而溶胀，改变填料的用量从而调节聚合物与沥青的密度差异的方法，制备出高温贮存稳定的改性沥青，并研究了工艺条件和配方因素对聚合物/填料复合物力学和聚合物分子量分布的影响，系统考察了工艺条件和配方因素对聚合物/填料改性沥青性能与形态结构的影响，研制出性能优良、高温贮存稳定的苯乙烯-丁二烯-苯乙烯三嵌段共聚物、氢化SBS、低密度聚乙烯改性沥青，并通过流变学分析方法及凝胶和溶胀测试探讨了聚合物与填料的相互作用，指出经过预混工艺填料改变了聚合物与沥青的密度差异，以此说明聚合物/填料改性沥青高温贮存稳定的原因；研究了基质沥青和聚合物改性沥青热氧老化过程，并分析了抗氧剂对基质沥青及聚合物改性沥青的影响，探讨了抗氧剂提高沥青耐老化性能的原因。

The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.

通过研究阐明：紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移，νC=O振动吸收峰在聚合24h后红移；TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01，α为2.28，优于其它功能单体参与得到的聚合物识别特性；TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间，作为色谱固定相具有良好的通量和低的柱压；在乙腈流动相中，TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动，低温有利于分子印迹固定相分离甾醇结构类似物；TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融，Tp=257.40℃，聚合物CP的降解温度在267.79℃，MIP降解温度在343.11℃，制备的固相微萃取头初步经GC/MS 270℃的耐热性测定；不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应；分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性，可作为此类化合物的吸附材料，特别对孕酮强保留的富集特性，可作为孕酮的选择性识别吸附剂，其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡，具有作为传感器核心敏感材料的潜力；对比萃取奶粉中17β-雌二醇性能，MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留，回收率依次为85.5%，43.7%和30.7%。

The dynamics and heat transfer on the spinning line during the air drawing process are discussed in detail, mainly relating the forces acting upon the polymer along the spinning line and the expressions of the air drawing coefficient C〓 and heat transfer coefficient h. By introducing the power-law model as the constitutive equation to describe the theological properties of polymer melt and considering the changing of the density and specific heat capacity of polymer melt at constant pressure with the polymer temperature, the former model of polymer air drawing is improved and a complete polymer air drawing model is established, which is integrated with the model of air jet flow field of dual slot die.

在此基础上，对前人的聚合物拉伸理论模型进行了改进，以幂律模型作为描述聚合物熔体流变行为的本构方程，并考虑了聚合物熔体密度和定压比热随聚合物熔体温度变化而变化这个因素，从而建立了完整的熔喷聚合物拉伸理论模型。

The oil-displacing agents for crosslinked polymer oil-displacing system are mainly as follows:the polymer containing monomers with heat resistance and salt tolerance ,zwitterion polymer,hydrophobically associating water-soluble polymer,polymer complex system,and comb polymer.

用于交联聚合物驱油体系的驱油剂主要有含耐温抗盐单体的聚合物、两性离子聚合物、疏水缔合水溶性聚合物、聚合物复合体系和梳形聚合物。

The features of AAA adsorbed on the ethylatedβ-CD polymer were similar with those of the parentalβ-CD polymer, but theadsorption ratios of AAA on the ethylatedβ-CD polymer were higher than those of the parentalβ-CD polymer. It may be due to the strengthened hydrophobic interactions between AAA and the ethylatedβ-CD polymer, which was caused by the ethylation of the parentalβ-CD polymer.

研究表明其对芳香氨基酸的吸附规律与母体β-环糊精聚合物类似；与母体β-环糊精聚合物相比，芳香氨基酸在该聚合物上的吸附率有所增加，这可能是因为乙基化增强了β-环糊精空腔外沿的疏水性，从而增强了乙基化β-环糊精聚合物与芳香氨基酸之间的疏水相互作用。

Through the analysis of De, an alternative mechanism interpreting of the"overshoot"phenomena can be obtained: when the diffusing time of small molecular penetrants is shorter than relaxation time of the involved polymer, small molecular substance penetrates into the polymer quickly and its concentration reached a maximum, then the swelling of the polymer by the small molecules makes the chain structure of the polymer relaxed, thus the free volume in polymer matrix, which is occupied by small molecule, decreased, and will squeeze part of the small molecular substance out of the polymer, and therefore overshoot behavior can be observed.

通过对De的分析，可以得出产生&超调&现象的机理的另一种解释：小分子渗透物质的扩散时间相对于聚合物的松弛时间要短（相当于有个更快的扩散速度），所以小分子迅速扩散进聚合物中达到一个极值，由于小分子物质对聚合物的溶胀，使得聚合物链结构产生松弛，由于聚合物链结构的变化，小分子物质占有的自由体积会减小，这样会挤出小分子物质，使得小分子物质在聚合物中的浓度减小，如果高聚物粘弹性明显，甚至可能出现多个浓度的衰减振荡并达到平衡值。

The rheological character of a polymer often appears as shear-thinning. Most polymers behaviour in a solution can be explained by the polymer chain or hard sphere theory. Other than that, shear-thickening polymer solution also exists. Its behavior can be explained by dilatant theory, which suggests that the shear-thickening of the solution is due to the swelling of the polymer particles. This phenomenon often occurs in suspension or emulsion. Solution exhibits a mixed behavior can also be found whose behavior is such that shear-thinning occurs under low shear force and shear-thickening occurs under high shear force. Under this circumstance, the viscosity versus shear force graph exhibits a spoon shaped curve. The rheological study can be applied to the dispersion of paint which can predict the dispersion effect of various polymer materials in solution.

中文摘要一般高分子聚合物溶液的流变行为多半呈现剪稀(shear-thinning)的现象，而大部分的高分子在溶液中的行为是以分子链或是硬球观点来解释，另外也有剪稠(shear-thickening)现象的高分子溶液，其流变行为则是以膨胀体观点来解释，即在高剪切力下，由於高分子团体积变大而使溶液黏度升高，这在悬伏液、乳液等常见；但也有在低剪切力下，溶液具有剪稀的行为，而在高剪切力下却成现剪稠的行为，在黏度对剪切力作图时，会呈现出一个勾形曲线的图形；流变行为的探讨可应用在涂布材料的分散技术上，以推测不同的高分子溶液对分散效果的影响。

It is included that 4-5 types of active sites exist in the catalytic system and the active site produced polymer with low molecular weight is easy to be activiated while TEA is used as the cocatalyst. While TIBA, the active site produced polymer with high molecular weight and seldom active site produced polymer with low one is prone to be activiated. MAO tends to activiate the active site produced polymer with middle-level molecular weight. In TEA-TIBA catalytic system, TEA and TIBA activiate the corresponding active site and the weight of every active site gradationally varied with the change of the ratio of the two cocatalysts. And the activity of the active site produced polymer with high molecular weight is proportion to the concentration of TIBA.

发现：TEA作为助催化剂时产生低分子量产物的活性中心易于活化，且体系中具有活性的活性中心有4～5种；TIBA易于活化产生高分子量的活性中心，基本上不能活化产生低分子量产物的活性中心；MAO对产生中等分子量产物的活性中心活化能力较强；在TEA-TIBA混合物体系中，TEA和TIBA各自对活性中心的作用表现为明显的互补现象，各活性中心的相对强度随着两种助催化剂之间的比例改变呈现渐次变化，其中产生高分子量产物的活性中心的相对活性(来源：c5AB3fC论文网www.abclunwen.com)与TIBA的浓度有明显的正相关性。

The preliminary plan and actualized blue prints were presented,which was to construct an interact teaching,interpenetrative and flexible polymer science experiment course combined polymer chemistry,polymer physics and polymer process.Students learn from molecular design to synthesize polymer compounds and character properties of the materials,them process them to an utilized produce in this course.

设想将高分子化学、高分子物理和高分子成型加工三门实验课程有机地串联起来，组建成一门包括从高分子材料设计(用计算机软件进行分子设计、性能模拟)、聚合物合成、性能测试到加工成型，能环环相扣、互动式的、柔性化的高分子科学实验课程；提出了初步的实践方案。

However, the thermal stability of metallic coordination polymer hardly enhanced in comparison with the polymer never coordinated transitional metallic ions. The reason might be that the energy of coordinate bond formed between metallic ion and polymer was trival in comparison with that of covalent bond in polymer. It started with coordinate bond when the coordinate polymer decomposed under high temperature, so it engendered little for the thermal stability at high temperature.

而金属配聚物较未配位金属的配体高温热稳定性提高不大，可能是由于金属离子与配体之间形成配位键的键能与配位体内的共价键键能相比要小得多，当金属配聚物受热裂解时，首先从配位键开始，因此对高温热稳定性的影响甚微。

It's rather showy.I'd like something plainer.

赶花了，我想要素净些的。

The Kremlins Spassky Tower and passers-by are reflected in the wet cobblestones of Moscows Red Square on Feb.

克里姆林宫的斯巴斯克塔和旅客的身影倒映在潮湿的鹅卵石墙上。