polymer ['pɔlimə]
- polymer的基本解释
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n.
聚合体
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In the dissertation, a new stabilization method, equal-density method was adopted to prepare modified asphalts with storage stability at high temperature. In this method, a compound was prepared by premixing polymer and filler, and the compound was mixed with asphalt to prepare Polymer-Modified Asphalt by changing the ratio of polymer and filler. The asphalts with good storage stability were formed with the addition of filler, by regulating the density difference between polymer and asphalt. With identifying the effect of composition factor and the technique conditions on mechanical properties of polymer/filler compound and the molecular distribution of the polymer, identifying the effect of composition factor and the technique conditions on the properties and structure of polymer/filler modified asphalt, Styrene-Butadiene-Styrene copolymer, Low Density PolyEthylene, Styrene-Ethylene-Butadiene-Styrene block copolymer modified asphalts with good storage stability and performance were prepared. Rheological method, gel content analysis and swelling measurement were adopted to elucidate the interaction between the polymer and filler. Filler reduced the difference between the polymer and asphalt with the premixing technique, which led to the improvement of the storage stability of the modified asphalts. The thermo-oxidative aging process of base asphalt and PMA were studied and the effect of antioxidant additives on the base asphalt and PMA were analyzed.
本论文采用等密度方法,即预先混合聚合物与填料制备复合物,复合物在沥青中会吸收油份而溶胀,改变填料的用量从而调节聚合物与沥青的密度差异的方法,制备出高温贮存稳定的改性沥青,并研究了工艺条件和配方因素对聚合物/填料复合物力学和聚合物分子量分布的影响,系统考察了工艺条件和配方因素对聚合物/填料改性沥青性能与形态结构的影响,研制出性能优良、高温贮存稳定的苯乙烯-丁二烯-苯乙烯三嵌段共聚物、氢化SBS、低密度聚乙烯改性沥青,并通过流变学分析方法及凝胶和溶胀测试探讨了聚合物与填料的相互作用,指出经过预混工艺填料改变了聚合物与沥青的密度差异,以此说明聚合物/填料改性沥青高温贮存稳定的原因;研究了基质沥青和聚合物改性沥青热氧老化过程,并分析了抗氧剂对基质沥青及聚合物改性沥青的影响,探讨了抗氧剂提高沥青耐老化性能的原因。
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The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.
通过研究阐明:紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移,νC=O振动吸收峰在聚合24h后红移;TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01,α为2.28,优于其它功能单体参与得到的聚合物识别特性;TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间,作为色谱固定相具有良好的通量和低的柱压;在乙腈流动相中,TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动,低温有利于分子印迹固定相分离甾醇结构类似物;TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融,Tp=257.40℃,聚合物CP的降解温度在267.79℃,MIP降解温度在343.11℃,制备的固相微萃取头初步经GC/MS 270℃的耐热性测定;不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应;分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性,可作为此类化合物的吸附材料,特别对孕酮强保留的富集特性,可作为孕酮的选择性识别吸附剂,其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡,具有作为传感器核心敏感材料的潜力;对比萃取奶粉中17β-雌二醇性能,MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留,回收率依次为85.5%,43.7%和30.7%。
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The dynamics and heat transfer on the spinning line during the air drawing process are discussed in detail, mainly relating the forces acting upon the polymer along the spinning line and the expressions of the air drawing coefficient C〓 and heat transfer coefficient h. By introducing the power-law model as the constitutive equation to describe the theological properties of polymer melt and considering the changing of the density and specific heat capacity of polymer melt at constant pressure with the polymer temperature, the former model of polymer air drawing is improved and a complete polymer air drawing model is established, which is integrated with the model of air jet flow field of dual slot die.
在此基础上,对前人的聚合物拉伸理论模型进行了改进,以幂律模型作为描述聚合物熔体流变行为的本构方程,并考虑了聚合物熔体密度和定压比热随聚合物熔体温度变化而变化这个因素,从而建立了完整的熔喷聚合物拉伸理论模型。
- 更多网络解释 与polymer相关的网络解释 [注:此内容来源于网络,仅供参考]
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polymer:聚合物
今天的化学课是讲 "复合聚合物" (Polymer):尼龙 (Nylon) 的应用. 」骚动总算是平静了下来,我也开始站在讲台上讲课. 虽然表面上他们是在听讲,但我总是觉得他们的目光和视线有点奇怪. 「尼龙(Nylon)是一种复合聚合物,外形是像纤维般的幼细丝线.
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polymer:聚合体
[材质说明]提把/聚氯乙烯(PVC)分体式内胆/聚乙烯(PE)保温层/聚合体(Polymer)防水外层/聚氯乙烯(PVC)
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polymer:聚合物,高分子
硅材质的微加工材料将成市场主流 拓墣产业研究所表示,制作微机电组件的主要材料依出货比例排名分别为硅、聚合物高分子(Polymer)及金属三大类. 其中硅材质由于本身具有极佳的机械性质、电性及耐久度,加上全球微电子产业已投入庞大资金、人力,
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polymer:高分子化合物
(一)塑胶由高分子化合物(Polymer)与添加物构成,在高分子中还含有反应剩余的单体(monomer),催化剂的残渣及添加物,包括防止其劣化的抗氧化剂、紫外线吸收剂等安定剂,改进其物理性质之可塑剂(Plasticizer),润滑剂,以及著色用的染料等.
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amorphous polymer:无定形聚合物
17、 聚合物:polymer | 18、 无定形聚合物:amorphous polymer | 19、 结晶现象:crystalline polamer
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