查询词典 intermediate conversion

Started from D-tyrosine, we obtained the tetramic acid 96 using Jouin reaction. The assembly of the second fragment 109 was stared from 1,4-butandiol,using asymmetric alkylation reaction developed by Oppolzer as a key step. Coupling of the tetramic acid 96 with 109 provided the key intermediate 110 according to Yoshii\'s procedure. After remove protective group and Sharpless epoxidation, we obtained the key intermediate 113. Its macrocyclization to form the final product is in progress.

本论文的第二章主要对Macrocidin A开展了合成工作，我们从D构型的酪氨酸出发，经过官能团转换；利用Jouin反应生成Tetramic acid 96，另外一个片断从1，4-丁二醇开始经过多步反应生成碘化物104，利用Oppolzer发展的手性樟脑磺酰胺为辅基参与的不对称烷基化反应，引入手性甲基，生成关键中间体109，接着通过Yoshii发展的方法连接96和109生成110，经过Sharpless不对称环氧化反应建立环氧化合物，然后脱去保护基得到关环前体113，分子内的Mitsunobu反应进行关大环反应正在进行之中。

Acenaphthene: Intermediate for naphthalic acids, naphthalic anhydride and for acenaphthylene; Intermediate for dyes, soaps, pigments, pharmaceuticals, insecticide, fungicide, herbicide and plant growth hormones.

苊： 萘酸/萘酐/亚苊的中间体，染料/肥皂/颜料/药品/杀虫剂/：//，/////杀真菌剂/除草剂和植物生长激素的中间体。

A series of p-toluene sulfonylamido acetacylhydrazone derivatives were synthesized from p-toluenesulfonyl chloride which reacted with glycine to get the intermediate p-toluene sulfonylamido glycine, then through the esterification, hydrazinolysis to afford another intermediate p-toluene sulfonylamido acethydrazide, which condensed with different aldehydes to obtain the target compounds that were characterized by IR, 1H NMR, 13C NMR spectra and elemental analysis.

魏太保 ；冷艳丽；王永成；张建辉；张有明*摘要：以对甲苯磺酰氯为原料，通过与氨基乙酸反应得到中间体对甲苯磺酰氨基乙酸，再经酯化、肼解得到对甲苯磺酰氨基乙酰肼，然后与相应的醛缩合得一系列对甲苯磺酰胺基乙酰腙类化合物。其结构经元素分析， IR， 1H NMR和13C NMR确证。

Based on the classical Ekman theory, a series of intermediate Ekman boundary layer models, which retain the nonlinear advective process while discard embellishments, have been developed with the intention to understand the complex nonlinear features of the Ekman boundary layer and its interaction with the free atmosphere. In this paper, the recent advances in the intermediate boundary-layer theoretical models are reviewed.

摘要大气边界层及其与自由大气之间的相互作用具有明显的非线性特征，而这些特征是经典Ekman理论所不能描述的，因此，发展中等复杂程度（介于完全模式与经典Ekman模型之间）的大气边界层动力学模式，简称中间模式，对人们从理论上认识大气边界层动力学过程的非线性特征具有重要意义。

A complex suite of intermediate-basic to intermediate-acid and relatively alkaline volcano-intrusive rocks of dominant andesitic composition and a group of iron ore deposits of somewhat different genetic types associated with them, including late magmatic, pegmatitic, pneumato-hypothermal, pyrometasomatic, meso- to epithermal deposit and the possible ore-magmatic and volcanic-sedimentary deposits, which are the successive products of the magmatic evolution, widely distributed in the faulted basins in the mi...

在长江中下游的若干断陷盆地中，发育着一套中、基性到中、酸性而含碱较高的、并以安山质为主的火山-侵人杂岩，与这一套有关的岩浆的演化过程相联系，形成一组从岩浆晚期到伟晶、高温气液、高温接触交代、中、低温热液及可能的矿浆充填、火山喷发沉积成因的铁矿床。

Based on the results of this report and the results of literature reports on the preferred conformation of enantiomeric 3-substituted-1, 4-benzodiazepines, a nucleophilically solvated C3 carbonium ion intermediate resulting from either a P or a M conformation is proposed to be an intermediate.

基於本文所报导的结果及文献所记述之对映异构性在C3位有取代基时的1，4-苯并二氮类的倾向构象，设想提出所观察之现象是由正或负构象所致的一个亲核性经溶剂化的C3阳碳离子为中间体。

These intermediate days on which work is permitted are referred to as Chol Ha-Mo'ed, as are the intermediate days of Sukkot.

这中间的日子，而工作，是不允许被称为哲夏mo'ed ，由於是中介的日子住棚。

The acetic aldehyde is produced upon oxidation with alcohol as raw material. It is an intermediate product for producing acetic acid and crotonaldehyde, and also basic chemical and important intermediate for chemical products with vast use.

乙醛是以酒精为原料氧化生成，它是生产醋酸和巴豆醛的中间产品，又是用途极广的基础化工原料和重要的化工产品中间体。

The intermediate decyl-glycidol ether of Gemini phosphate surfactant was synthesized with decanol and epichlorohydrin in the presence of phase-transfer catalyst; the intermediate decyl digomeric glycol of Gemini phosphate surfactant was prepared by opening ring reaction of decyl glycide ether and glycol in the presence of potassium as catalyst; and the influence of type and dosage of phase-transfer catalysts was studied.

以正癸醇与环氧氯丙烷为原料在相转移催化剂存在的条件下合成Gemini磷酸酯表面活性剂的中间体I-正癸基缩水甘油醚，讨论催化剂种类及用量对反应的影响；以乙二醇和正癸基缩水甘油醚为原料，金属钾为催化剂合成Gemini磷酸酯表面活性剂的中间体Ⅱ-正癸基低聚二醇，讨论催化剂种类与用量对反应的影响；以P2O5与正癸基低聚二醇为原料合成Gemini磷酸酯表面活性剂，讨论投料比、反应温度和反应时间等因素对反应的影响。

A REE partition simulation suggests that the Tianzhushan intermediate rocks can be generated by partial melting, in coupling with fractional crystallization, of dioritic gneiss which is similar in chemical compositions to the mafic rocks in the lower crust in North Dabie; partial melting of intermediate grey gneiss which is similar in chemical compositions to the middle crust in North Dabie can generate the Tianzhushan felsic rocks.

REE配分的定量模拟计算结果表明，与基性下地壳相似的北大别基性闪长质片麻岩部分熔融并经过结晶分异能够形成与天柱山中性岩类似的稀土元素组成，而与中性地壳相似的北大别中性灰色片麻岩部分熔融能够形成与天柱山花岗岩类似的稀土元素组成。

Molecular Distillation is a kind of high vacuum distillation method, which is suitable for the separation of high boiling, heat sensitivity and viscidity products.

分子蒸馏技术是一种在高真空条件下进行的连续蒸馏过程，适合于分离高沸点、热敏性及具有生物活性的混合物。

They are to the Noughties what yuppies were to the Eighties .

那在六十年代是时髦的，但在八十年代肯定是过时了