查询词典 derivatives

There are 65 species of Chinese herbs with confirmed anti-HBV activityd, in which 16 probable active constituents are pointed out. They are arene, ketone derivatives, alicyclic carboxylic acid, aromatic carboxylic acid, ester, lactone, cyanide derivatives, heterocycle derivatives, carotenoids, anthraquinones, flavonoids, vegetable tannin, alkaloid, terpenoids, steroids and protein. Among them, the complexes of flavonoids, terpenoids, steroids and alkaloids are more abundant.

确定了具有抗乙肝病毒活性的中草药品种65种，其中含可能活性成分共16种，即芳烃、酮类衍生物、脂环族羧酸、芳香族羧酸、酯、内酯、氰类衍生物、杂环衍生物、类胡萝卜素、蒽醌类、黄酮类、植物鞣质、生物碱、萜类、甾类和蛋白质，而16种中以黄酮类、萜类、甾类和生物碱类成分为多。

The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应，用茚〓和1，1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物，发现可控制反应条件，使1，1'-联茚与〓反应，并高产率地得到具有新颖结构的单加成物，用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征，测得它的两个〓杂化的桥头碳的化学位移为〓ppm，证明生成的衍生物为6∶6闭式环加成，〓NMR谱中共给出38个信号，表明〓联茚衍生物分子具有〓对称性；在波长532nm，脉冲宽度8ns的激光下，〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近，由于〓联茚单加成衍生物熱稳定性好，在四氢呋喃，丙酮等极性溶剂中溶解性好，能分别均匀地掺入溶胶-凝胶中，已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能；使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究，通过等温压缩曲线测试，证明浓度为〓〓时，〓联茚衍生物能够形成单层膜。

Therelationship of the amount of catalyst and the ee% of product was seen to be negative nonlin-ear. Catalyst 3 was used in the enantioselective addition of diethylzinc to aromatic aldehydesand gave good results. The configuration of products was determined by the configuration ofthe catalysts' chiral carbon linked with hydroxy group. Using β- amino alcohols bearing only one chiral center as catalysts for the enantiose-lective addition were studied. D-N, N-dialkyl-2-amino butanol gave poor catalytic effect be-cause of their structure. The configuration of the product is the same as the catalyst. Anotherkind of β- amino alcohols - phenylglycine derivatives and valine derivatives have chiralcenter on the carbon linked with amino group. Catalyzed by-phenylglycine derivatives 6,7, 9, 10, the reactions gave satisfied results. The optical yields exceeded 80%.

在探讨了含有两个手性中心的β-氨基醇之后，选择了只有一个手性中心的β-氨基醇，一是手性中心为连羟基的手性碳原子：D-N，N-二烷基-2-氨基丁醇；二是手性中心为连氨基的手性碳原子：D-苯基甘氨酸衍生物和L-缬氨酸衍生物。D-2-氨基丁醇的催化效果不太好，这与其结构的空间位阻较小有关系，反应产物与连羟基手性碳构型一致；由苯基甘氨酸和缬氨酸出发合成五种β-氨基醇6-10，研究了不同ee％的-6作用下的二乙基锌-苯甲醛加成反应，发现该催化剂具有不对称放大效应；-7，9，lO的催化效果也比较令人满意，光学产率80％以上，所得产物构型与催化剂构型一致。

The rules of photo bioactivities are: Without illumination, the tested xanthene derivatives showed almost the same level of inherent toxicity to the same organism, which showed the inherent toxicity of xanthene derivatives were primarily dependent on the structure of parent molecule. Upon illumination, the photosensitizers showed obvious phototoxicity to all organisms. The xanthene derivatives showed stronger phototoxicity to Gram-positive bacteria. With the increasing number of halogen substituents, the singlet oxygen yields increased and the phototoxic activity increased too.

呫吨类化合物的生物活性的变化规律为：未经光照的条件下，呫吨类化合物的对同种待测微生物的固有生物活性基本相同，说明固有毒性可能主要决定于化合物分子的母核结构，其卤素取代基团对其影响较小；经实验光源照射下，所测MLC值明显低于未经光照条件下的值，表明呫吨类化合物对三种微生物的光敏活性明显强于对其相应的固有活性；呫吨类化合物对革兰氏阳性菌能发挥较大的光敏活性。

For systematically studying the quantitative structure-property relationships for electrolytes, the thesis chapter 6, 7 and 8 systematically studied molecular structure and quantitative structure-property relationships, including the relationship between molecular structure and conductivity, anions structure and electrochemistry stability, on anions of 1,2-Dihydroxycyclo-pentenetrione (croconic acid, H_2C_5O_5) and the whole series of dicyanomethylene derivatives, anions of 1,2-dihydroxycyclobuten- 3,4-dione (squaric acid, H_2C_4O_4) and the whole series of dicyanomethylene derivatives, and anions of 1,2-Dihydroxy-cyclobuten- 3,4-dione (squaric acid, H_2C_4O_4) and the whole series of dicyanomethylene derivatives.

为了系统地研究锂盐的分子结构与电解质的关系，论文第六、七、八三章系统地从理论上研究了方酸及其氰基亚氨基衍生物、方酸及其二氰亚甲基衍生物、克酮酸及其二氰亚甲基衍生物等各系列电解质分子结构、分子结构与电导率、阴离子结构与电化学稳定性的关系。

The results show that temperature does not have a significant impact on derivatization reaction; the derivatives are rapid degraded in sun light; the derivatization reaction is inhibited when the derivatization reagent is at high concentration; the reaction to produce the fluorescent derivatives is finished in 30 min, and the derivatives are stable for about 8 h at normal temperature and lightless.

研究结果表明，环境温度对衍生反应影响不显著；衍生反应对太阳光线敏感，其机理是阿维菌素衍生产物易快速发生光解；高浓度的衍生试剂对反应表现一定抑制作用；衍生反应在30min左右达到峰值，其产物在室温、避光条件下8h内保持稳定。

Nitrogen species in FCC diesel oil include basic species (such as aniline, quinoline, and their derivatives) and nonbasic species (such as indole, carbazole, and their derivatives), and only 0.1% of the nitrogen compounds are quinoline and about 64% of them are carbazole and their derivatives.

氮化物主要为碱性氮化物和非碱性氮化物两大类型，其中碱性氮化物主要是苯胺及其衍生物，喹啉含量很低，约占总氮质量分数的0.1%，非碱性氮化物主要包括吲哚及其衍生物和咔唑及其衍生物，而咔唑类氮化物一般约占总氮质量分数的64%。

Tetrahydroisowuinolin derivatives and phthalide derivatives were designed and synthesized on the basis of a PDE4 inhibitor pharmacophore model set up through computer simulation. Some tetrahydroisowuinolin derivatives synthesized were evaluated on their activity against PDE4 for study on the structure-activity relationship.(7-cyclopentyloxy)-6-methoxy-3,4-dihydroisoquinolin-2(1H)-yl(4-hydroxy-3-methoxyphenyl)methanone (155) and Methyl 7--6-methoxy-2-(4-methoxy- benzoyl)-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate (170) showed good activity against PDE4, which were chosen as the lead compounds to design and synthesize another analogs in order to develop selective PDE4 inhibitors with better activity.

分别设计合成了以四氢异喹啉和氨基苯酞为骨架的两类小分子杂环化合物，并对部分四氢异喹啉衍生物测试了其相关的生物活性，初步确定了其构效关系，发现了两个对PDE4有较好抑制活性的先导化合物(7-cyclopentyloxy)-6-methoxy-3，4-dihydroisoquinolin-2(1H)-yl(4-hydroxy-3-methoxyphenyl)methanone (155)和Methyl 7--6-methoxy-2-(4-methoxy- benzoyl)-1-phenyl-1，2，3，4-tetrahydroisoquinoline-3-carboxylate (170)。

In comparison with the pure standards and the retention indices RI(subscript s reported in the literature, a total of 302 volatile compounds were identified in Changyu XO brandy, including 30 alcohols, 35 aldehydes and ketones, 20 carboxylic acids, 104 esters, 24 substituted benzenes and derivatives, 14 phenolic derivatives, 14 acetals, 16 furan derivatives, 22 terpenic and norisoprenoidic derivatives and 23 others.

实验先采用液－液萃取方法提取张裕XO级白兰地的挥发性成分，然后将酸性成分与碱性和中性成分分离，再采用柱色谱分离手段将其分离为若干个级分并浓缩，采用气相色谱-质谱、标准品比对、保留指数值比较等方法对分离得到的各级分中的成分进行了鉴定，在白兰地中共鉴定出302种挥发性成分，包括醇30种、醛酮类35种、酸类20种、酯类104种、苯同系物及其衍生物24种、酚类14种、缩醛14种、呋喃类16种、萜烯类22种和其他物质23种。

The neutral/basic fraction was furthermore separated into 4 fractions using silica gel normal phase chromatography, and each fraction was then concentrated and analyzed using gas chromatography-mass spectrometry. In comparison with the pure standards and the retention indices reported in the literature, a total of 302 volatile compounds were identified in Changyu XO brandy, including 30 alcohols, 35 aldehydes and ketones, 20 carboxylic acids, 104 esters, 24 substituted benzenes and derivatives, 14 phenolic derivatives, 14 acetals, 16 furan derivatives, 22 terpenic and norisoprenoidic derivatives and 23 others.

实验先采用液-液萃取方法提取张裕XO级白兰地的挥发性成分，然后将酸性成分与碱性和中性成分分离，再采用柱色谱分离手段将其分离为若干个级分并浓缩，采用气相色谱-质谱、标准品比对、保留指数值比较等方法对分离得到的各级分中的成分进行了鉴定，在白兰地中共鉴定出302种挥发性成分，包括醇30种、醛酮类35种、酸类20种、酯类104种、苯同系物及其衍生物24种、酚类14种、缩醛14种、呋喃类16种、萜烯类22种和其他物质23种。

In her eyes, because that is the doorway toher heart * the place where love resides.

女人的漂亮必須從她的眼睛中去看，因為那是她心靈的窗戶和愛居住的地方

I will send some postcards to you.

我会向你发送一些明信片。