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The results showed that the maximum UV absorption wavelengths of those 1,3,4-oxadiazole derivatives in dichloromethane were in the range of 268~327 nm, and their maximum photoluminescent wavelengths in dichloromethane and solid film were located at 332~390 nm and 359~439 nm, respectively. The 1,3,4-oxadiao1e derivatives exhibit a first endothermal peak at 120~328℃ in the DSC heating process, and the symmetrical 1,3,4-oxadiazole derivatives display a higher melting temperature. The CV curves of those 1,3,4-oxadiazole derivatives indicate that the reductive potentials of the 1,3,4-oxadiazole derivatives are located at -1.03~0.98 V, and their LUMO(the lowest unoccoupied molecual orbit) energy levels are -3.71~-3.76eV.
结果表明,该类衍生物在二氯甲烷溶液中的最大紫外吸收波长在268~327nm范围,在二氯甲烷溶液和固体膜中的最大荧光发射波长分别在332~390nm和359~439nm范围;DSC分析结果表明,5个噁二唑衍生物的起始吸热峰位于120~328℃之间,其中对称结构的噁二唑衍生物显示了较高的熔融温度;由循环伏安图和相关计算结果表明,5个噁二唑衍生物的还原电位位于-1.03~-0.98V,其相应的最低非占有分子轨道能级在-3.71~-3.76 eV之间。
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In this thesis, a series of derivatives of -Huperzine A and benzylpiperidine were designed and synthesized, including nonsteroidal anti-inflammatory drug derivatives, heterocycle derivatives, aromatic derivatives and its sckiff derivatives, etc.
全部目标化合物进行了胆碱酯酶的活性测试,石杉碱甲类衍生物的乙酰胆碱酯酶活性比母体差,说明该类取代基在胺基上取代可能会使石杉碱甲衍生物的活性降低。
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The main compositions of LPs include shorter chain carboxylic acid derivatives, furan derivatives, cyclopentanone, phenol derivatives, benzene derivatives, cinnamic acid derivatives, longer chain carboxylic esters and sterides.
秸秆在亚/超临界醇中液化产生的LPs的主要组成成分包括短链脂肪酸衍生物、呋喃衍生物、环戊酮衍生物、含有取代基的肉桂酸衍生物、芳醛或酮衍生物、苯酚衍生物、苯衍生物,长链脂肪酸衍生物和甾族化合物。
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The achievements of this paper are as follows:(1) A series of cantharidin derivatives, saccharide-cantharidin derivatives compounds, saccharide-5-fluorouracil derivatives compounds and 5-fluorouracil derivatives organotin complexes have been firstly synthesized.
本论文的创新点在于:首次合成了一系列斑蝥素衍生物,斑蝥素衍生物-糖化合物,5-氟尿嘧啶衍生物-糖化合物和5-氟尿嘧啶衍生物-有机锡配合物。
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The main compositions of LP are shorter chain carboxylic acid and their ethyl esters, furan derivatives, cyclopentanone, phenol derivatives, benzene derivatives, aromatic ketone, aromatic acid derivatives, longer chain carboxylic ethyl esters and sterides. After upgrading, the main indexes reach the standard of fuel oil.
结果表明,LP的主要成分包括短链或环状脂肪酸及其酯、呋喃衍生物、环戊烯衍生物、苯酚衍生物、苯衍生物、芳酮、芳酸及其乙酯、长链脂肪酸乙酯和甾族化合物,经提质其主要指标达到了燃料油的标准。
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The major products were methane, ethylene, propylene, butylene, butadiene, cyclopentadiene, benzene, toluene, styrene, vinyl-substituted cyclopentene derivatives and C5/C6 isomers (pentadiene, methyl-substituted cyclopentene derivatives, cyclohexene, hexadiene and methyl-substituted cyclopentadiene derivatives), and the main primary products were determined to be C1~C4 compounds, cyclopentadiene, benzene, toluene and vinyl-substituted cyclopentene derivatives.
热裂解主要产物为甲烷、乙烯、丙烯、丁烯、丁二烯、环戊二烯、苯、甲苯、苯乙烯、环戊烯的乙烯基取代物及C5, C6异构体(戊二烯、环戊烯的甲基取代物、环己烯、己二烯和环戊二烯甲基取代物),其中, C1~C4、环戊二烯、苯、甲苯、乙烯基取代环戊烯为初始产物。
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Synthesis of organic sulfuric compounds in aqueous media is carried out by: using thio-olefin compounds with carbonyl compounds, acetal/keltone, hydrazone, oxime, osazone and enamine to synthesize mercaptal/keltone compounds in aqueous media; using thio-olefin compounds with alpha-hydroxyaldehyde/keltone or alpha-halogenated aldehyde/keltone to synthesize thia-olefin derivatives in a queous media; using thio-olefin compounds with alpha, beta-unsaturated hydroxy compounds, C-C treble bond, C-N treble bond, C-C double bond, N-N double bond, C-N double bond, C-S double bond, epoxy and its derivatives, aziridine and its derivatives, cyclopropane and its derivatives and halogenated carboxy to synthesize sulfoether compounds in a queous media.
含水介质中有机硫化合物的合成方法,本发明属于有机合成方法,用硫缩烯酮类化合物与羰基化合物、缩醛/酮、腙、肟、脎、烯胺在含水介质中合成缩硫醛/酮化合物,与α-羟基醛/酮或α-卤代醛/酮在含水介质中合成噻烯类衍生物,与α,β-不饱和羰基化合物、碳碳叁键、碳氮叁键、碳碳双键、氮氮双键、碳氮双键、碳硫双键、环氧乙烷及其衍生物、氮杂环丙烷及其衍生物、环丙烷及其衍生物、卤代烃等在含水介质,中合成硫醚化合物。
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In this paper, the electrostatic potentials at the midpoint of C-NO2 bond and the net electric charge on every element in nitrobenzene derivatives, nitrotoluene derivatives, nitrophenol derivatives and nitroaniline derivatives were calculated using ab initio.
根据分子结构、静电势最大值、实验撞击感度及分子中各元素所带的净电荷,对影响炸药感度的因素及DATB和TATB的特殊稳定性进行了分析。通过分析,我们发现,影响上述炸药撞击感度的因素主要有硝基、甲基、羟基和胺基。
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The charges on the substituents affected OWF〓 greatly for some azobenzene derivatives, pyridone derivatives, nitrodiphenylamine derivatives, some reactive dyes and 1, 4-diamino anthraquinone derivatives, in this instance, OWF〓 changed linearly with the change of the charges.
2给电子取代基或吸电子取代基的电荷对OWF〓有较大的影响,OWF〓随电荷的变化而线性变化,如某些偶氮苯衍生物、吡啶酮类染料母体、硝基二苯胺类化合物、偶合组分和重氮组分之间夹角α变化不大的活性染料、1,4—二氨基蒽醌衍生物等。
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In comparison with the pure standards and the retention indices RI(subscript s reported in the literature, a total of 302 volatile compounds were identified in Changyu XO brandy, including 30 alcohols, 35 aldehydes and ketones, 20 carboxylic acids, 104 esters, 24 substituted benzenes and derivatives, 14 phenolic derivatives, 14 acetals, 16 furan derivatives, 22 terpenic and norisoprenoidic derivatives and 23 others.
实验先采用液-液萃取方法提取张裕XO级白兰地的挥发性成分,然后将酸性成分与碱性和中性成分分离,再采用柱色谱分离手段将其分离为若干个级分并浓缩,采用气相色谱-质谱、标准品比对、保留指数值比较等方法对分离得到的各级分中的成分进行了鉴定,在白兰地中共鉴定出302种挥发性成分,包括醇30种、醛酮类35种、酸类20种、酯类104种、苯同系物及其衍生物24种、酚类14种、缩醛14种、呋喃类16种、萜烯类22种和其他物质23种。
- 推荐网络例句
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If I didn't care what anyone thought, I would.....
如果我不介意别人怎么看,我会。。。。
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In recent decades, Chile has mandated earthquake-proofing for new structures, requiring that materials like rubber and features like counterweights be built into the architectural designs to allow buildings to bend and sway during temblors rather than break.
在最近数十年里,智利已经为兴建防震的新土建结构而对建筑材料提出要求,需要的材料类似于橡胶,而特性就象运用在建筑设计中的平衡物体,一旦应用以后,当地震发生时建筑就能弯曲摇摆。
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The condemnation of Monophysitism alienated the churches of Egypt, Syria, Mesopotamia, and Armenia, creating dissention in the Eastern Roman Empire and lessening its ability to withstand the Islamic invasion in the 7th century.
谴责monophysitism疏远了教会的埃及,叙利亚,美索不达米亚,亚美尼亚,造成离心的,在东罗马帝国,并减少它有能力抵御伊斯兰入侵,在公元7世纪。