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Single component and multi\|component of iron system colloidal catalyst \Ali\|Bu\-3CH\-2CHCH\-2Cl\ were mixed by different ratios in hydrogenated gasoline medium at 25℃.This paper studied the relationship between the nonaqueous systematic electroconductivity and the concentration of catalyst components.In combination with Tyndall effect,polymerization experimental results,Ali\|Bu\-3 existed in associated state and dissociated into ionpair.The reaction between Ali\|Bu\-3 and Fenaph\-2 was the main reaction which formed colloidal core.Ali\|Bu\-3 reacted on CH\-2CHCH\-2Cl and Ali\|Bu\-2Cl was yielded which joined the formation of active center on the surface of colloidal core.The excessive Ali\|Bu\-3 was dissociated into ionpair which formed double electrode layer,and the double electrode layer kept the colloidal particles relatively stable.

研究了在25℃加氢汽油介质中,铁系胶体催化剂[Fenaph2Ali-Bu3―CH2==CHCH2Cl]单组分、多组分按不同配比混合,非水体系电导率与浓度的关系,结合Tyndall效应,聚合实验结果,得出Ali-Bu3以缔合状态存在并解离成离子对它同环烷酸亚铁的作用是形成胶核的主要反应,与氯丙烯反应生成的氯化异丁基铝,在胶核表面参与形成活性中心由过量Ali-Bu3解离的离子对形成的双电层结构,使胶粒保持相对稳定。

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