嵌段共聚物

Hybrid mesoporous molecular sieve materials with hexagonal mesoporous structure and covalent bonded polyoxometalates were synthesized based on tetraethoxysilane anti lacunary polyoxometalate, SiW11, via sol-gel method in the presence of triblock copolymers P123 as the structure-directing agent. The influences of molar ratio of inorganic precursors and aging temperature on the structure and the loadings of SiW11 in the hybrid materials were investigated. Some reaction details in the synthesis were revealed.

用嵌段共聚物P123为模板剂，正硅酸乙酯和缺位结构的多金属氧酸盐SiW11为无机前驱体，由溶胶－凝胶法合成了具有六方结构和SiW11共价键联的介孔分子筛杂化材料SiW11/SBA-15，着重考察了无机前驱的配比和老化温度对杂化材料结构及SiW11负载量的影响。

The hybrid mesoporous materials, PW11/SBA-15, were synthesized using tetraethoxysilane and lacunary polyoxometalate Na7PW11O39 (PW11) by a co-condensation approach in the presence of triblock copolymer EO20PO70EO20 (P123) as a template.

采用三嵌段共聚物EO20PO20(P123)为模板剂，正硅酸乙酯和缺位Keggin型多金属氧酸盐Na7PW11O39(PW11)为无机前驱体，由共缩合法一步合成了PW11/SBA-15介孔杂化材料。

GPC analysesand particle size results indicated that using PFAMA macro-CTA as the first block wasbetter than using the PBMA RAFT agent with respect to the colloidal stability and thenarrow molecular weight distribution of the F-copolymers latices.

改变合成顺序，首先在本体中合成PFAMA大分子链转移剂，然后在细乳液体系中进行BMA的聚合，凝胶渗透色谱和粒径分析表明：可以得到稳定的细乳液和分子量分布窄的含氟嵌段共聚物PFAMA-b-PBMA。

The shape of micelles could be nonspherical.

使用傅立叶变换红外光谱技术研究了PEO-PPO-PEO嵌段共聚物Pluronic L64在不同的水含量，存在和不存在牛血清白蛋白的水/Pluronic L64/对二甲苯的微乳体系。

The star shaped block copolymers were prepared by ring opening polymerization of ε caprolactone in the presence of multiarm PEG using stannous octoate as a catalyst.

以辛酸亚锡为催化剂，通过星型聚乙二醇引发ε己内酯开环聚合，制备了PEG b PCL嵌段共聚物，进一步以丙烯酸酯封端，合成了 3种水溶性大分子单体。

Inside benzene or toluene solvent, in the presence of stannous octoate as catalyst and under the conditions of no water, no oxygen, heating and stirring, MPEG and aliphatic cyclic monomer are ring-opening polymerized to obtain binary block MPEG-aliphatic polyester copolymer.

聚乙二醇单甲醚和脂肪族环酯单体，在苯或甲苯溶剂中，在无水无氧，加热和搅拌的条件下，用辛酸亚锡为催化剂，开环聚合得到聚乙二醇单甲醚-脂肪族聚酯二嵌段共聚物。

The star-shaped block copolymers were prepared by ring-opening polymerization of ε-caprolactone in the presence of multiarm PEG using stannous octoate as a catalyst.Based on these star-shaped PEG- b -PCL,soluble macromers terminated with acrylate groups were synthesized.

以辛酸亚锡为催化剂，通过星型聚乙二醇引发ε-己内酯开环聚合，制备了PEG- b -PCL嵌段共聚物，进一步以丙烯酸酯封端，合成了3种水溶性大分子单体。

Hydrogenated poly (styrene-b-butadiene) copolymer/organophilic montmorillonite nanocomposites were prepared by a solution approach.

采用溶液混合方法制备了氢化苯乙烯／丁二烯三元嵌段共聚物／有机蒙脱土纳米复合材料。

A kind of spherical microporous silica was synthesized by precipitation with the tetraethyl orthosilicate as a silica precursor and the block ploymer P_(123 as a template. The characterizations by the BET, FSEM and XRD showed that the spherical microporous silica has diameter of 3～4 μm, amorphous pore size of 0.9～1 nm and the specific area of 216±

以正硅酸乙酯作硅源，嵌段共聚物为模板剂，采用沉淀法合成均匀的实心球形二氧化硅微孔材料，BET、FSEM和XRD等表面分析手段表征表明，我们合成的二氧化硅微孔材料具有3～4μm的粒径和不规则分布的0.9～1nm的孔径以及216±3.5m2/g的比表面积。

The preparation of avermyctin emulsions in water was achieved by mixing the surfactants polyoxyethylene (10) octylphenyl ether (OP10), polyoxyethylene styrenated phenol ether (602), and polyoxyethylene (40) castor oil ether (EL-40) with polyoxyethylene (20) castor oil ether (EL-20), separatively. Emulsion stability was investigated by analyzing the hydrophile-lipophile balance, critical micelle concentration, and surface tension. Then, the surfactants of polyoxyethylene polyoxypropylene styrenated phenol ether (1601), block copolymer (L64), and octyl phenyl polyoxyethylene phosphonate were added to the emulsion made by blending EL-40 and EL-20, separatively. The stability of the emulsions was investigated further and discussed in terms of droplet size, surface tension, and zeta potential.

首先将辛基酚聚氧乙烯醚(OP10)、苯乙烯基酚聚氧乙烯醚(602)和蓖麻油聚氧乙烯(40)醚(EL-40)分别与蓖麻油聚氧乙烯(20)醚(EL-20)复配制备阿维菌素水乳剂，从亲水亲油平衡值、临界胶束浓度、表面张力等方面分析了二元表面活性剂复配对乳液稳定性的影响；其次，在EL-40与EL-20复配基础上，将苯乙烯基酚聚氧乙烯聚氧丙烯醚(1601)，嵌段共聚物(L64)和辛基酚聚氧乙烯醚磷酸酯分别添加到乳液中，从粒径、表面张力和zeta电势等方面考察三元表面活性剂复配对乳液稳定性的影响。

Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克，果实色泽鲜艳，汁多味浓，甜酸适口，离核仁甜，清末时就驰名陕、甘两省，清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异：红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感，ED90值分别为47.65、71.67和29.17g/hm2；春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感，ED90值分别为96.91、114.20g/hm2；而番茄不敏感。