嵌段共聚物

A very mild and extremely efficient hydrolysis method for transformation of polystyrene-b-poly (tert-butyl acrylate) to polystyrene-b-poly was designed and carried out using more convenient and inexpensive chlorotrimethylsilane/sodium iodide as reagents.

在温和的条件下使用廉价方便的三甲基硅氯烷/碘化钠作试剂，在乙腈溶剂中，50℃下使聚苯乙烯-嵌-聚丙烯酸特丁酯高效的水解。用透射电镜和动态光散射对嵌段共聚物聚苯乙烯-b-聚丙烯酸在水介质中的胶束化进行了研究。

Objective To study the pH and temperature sensitive properties of sulfamerazine oligomers-polyε-caprolactone-co- DL -lactide-b-ethyleneglycol- b -ε-caprolactone-co-DL-lactide-sulfamerazine oligomers（OSM1-PCLA-PEG-PCLA-OSM1）block copolymer and evaluate sustained release effect of 5-fluorouracil release from the loaded hydrogel in vitro.

摘要目的为嵌段共聚物磺胺甲嘧啶低聚物-聚-ε-己内酯-丙交酯-聚乙二醇-聚-ε-己内酯-丙交酯-磺胺甲嘧啶低聚物（sulfamerazine oligomers-poly(ε-caprolactone-co- DL -lactide-b-ethyleneglycol- b-ε-caprolactone-co-DL-lactide)-sulfamerazine oligomers，OSM1-PCLA-PEG-PCLA-OSM1作为缓控释给药系统的载体提供依据。

This article reports a new kind of copolymer, non polar polar terpolymer : poly(styrene-butadiene-methyl methacrylate ) P(S-b-B-b-MMA prepared by anionic polymerization with n BuLi as initiator, 1,1 diphenylethylene as capping agent and lithium 2-(-methoxyethoxy) ethoxide as complex agent.

以正丁基锂为引发剂， 1 ，1-二苯基乙烯为戴帽剂， 2-(2-甲氧基乙氧基)乙氧基锂为络合剂，在环己烷、四氢呋喃混合溶剂中，采用阴离子聚合法，于－70℃～－40℃合成了非极性-极性的三嵌段共聚物聚苯乙烯-聚丁二烯-聚甲基丙烯酸甲酯，并借用GPC、1H-NMR、DSC、TEM、IR等仪器对共聚物进行了表征。

Moreover, the A-B-A triblock copolymer solution in a selective solvent, which is good for the block B, was explored. It was observed that the flowerlike micelles were formed, in which the central block B took on a loop conformation and the two end A blocks became a part of the micellar core. It was found that some of the soluble middle B blocks served as extended bridges between the small clusters by the poorly solvated end A blocks.

在A-B-A三嵌段共聚物溶液体系中，溶剂是链段B的良溶剂，是链段A的不良溶剂，此时我们得到了花型结构的胶束，其中花心是由链段A聚集而成，花瓣是由链段B形成的，而且在体系中也发现了有些胶束间存在着桥，并且在浓度很高时，体系出现了凝胶现象。

The researchers found that, when they added block co-polymers to a lithographically patterned surface, the co-polymers assembled themselves into the designated regular array.

研究者发现，当他们将嵌段共聚物加到光刻晶格表面上时，共聚物会自己形成指定的规则排列。

Continuous growth of dendrons from G1.5 to G4 at the both ends of PSt chains was carried out by the iterative Michael addition reactions with excess PZ and following TT. Structures of the triblock polymers were characterized by GPC and ~1H NMR spectra.

随后，聚合物链末端反复用过量的哌嗪和TT进行迈克尔加成反应，使树枝状聚酰胺胺嵌段不断增长，得到G1.5到G4的嵌段共聚物。

August 19, 2008 - Invensys Process Systems signed a five-year, more-than-$20 million contract to provide comprehensive industrial automation services and solutions to Kraton Polymers, a copolymers industry pioneer and a leading producer of styrenic block copolymers with facilities in the United States, Germany, France, The Netherlands, Brazil, China and Japan.

8月19日消息——英维思过程系统公司签订了一份为期五年、价值超过2000美元的合同，为Kraton Polymers公司提供全面的工业自动化服务和解决方案，Kraton Polymers公司是共聚物工业的先驱，是苯乙烯类嵌段共聚物的领先生产商，在美国、德国、法国、荷兰、巴西、中国和日本都有工厂。

August 19, 2008 - Invensys Process Systems signed a five-year, more-than-$20 million contract to provide comprehensive industrial automation services and solutions to Kraton Polymers, a copolymers industry pioneer and a leading producer of styrenic block copolymers with facilities in the United States, Germany, France, The Netherlands, Brazil, China and Japan.

8月19日消息——英维思过程系统公司签订了一份为期五年、价值超过2000万美元的合同，为Kraton Polymers公司提供全面的工业自动化服务和解决方案，Kraton Polymers公司是共聚物工业的先驱，是苯乙烯类嵌段共聚物的领先生产商，在美国、德国、法国、荷兰、巴西、中国和日本都有工厂。

In the dissertation, a new stabilization method, equal-density method was adopted to prepare modified asphalts with storage stability at high temperature. In this method, a compound was prepared by premixing polymer and filler, and the compound was mixed with asphalt to prepare Polymer-Modified Asphalt by changing the ratio of polymer and filler. The asphalts with good storage stability were formed with the addition of filler, by regulating the density difference between polymer and asphalt. With identifying the effect of composition factor and the technique conditions on mechanical properties of polymer/filler compound and the molecular distribution of the polymer, identifying the effect of composition factor and the technique conditions on the properties and structure of polymer/filler modified asphalt, Styrene-Butadiene-Styrene copolymer, Low Density PolyEthylene, Styrene-Ethylene-Butadiene-Styrene block copolymer modified asphalts with good storage stability and performance were prepared. Rheological method, gel content analysis and swelling measurement were adopted to elucidate the interaction between the polymer and filler. Filler reduced the difference between the polymer and asphalt with the premixing technique, which led to the improvement of the storage stability of the modified asphalts. The thermo-oxidative aging process of base asphalt and PMA were studied and the effect of antioxidant additives on the base asphalt and PMA were analyzed.

本论文采用等密度方法，即预先混合聚合物与填料制备复合物，复合物在沥青中会吸收油份而溶胀，改变填料的用量从而调节聚合物与沥青的密度差异的方法，制备出高温贮存稳定的改性沥青，并研究了工艺条件和配方因素对聚合物/填料复合物力学和聚合物分子量分布的影响，系统考察了工艺条件和配方因素对聚合物/填料改性沥青性能与形态结构的影响，研制出性能优良、高温贮存稳定的苯乙烯-丁二烯-苯乙烯三嵌段共聚物、氢化SBS、低密度聚乙烯改性沥青，并通过流变学分析方法及凝胶和溶胀测试探讨了聚合物与填料的相互作用，指出经过预混工艺填料改变了聚合物与沥青的密度差异，以此说明聚合物/填料改性沥青高温贮存稳定的原因；研究了基质沥青和聚合物改性沥青热氧老化过程，并分析了抗氧剂对基质沥青及聚合物改性沥青的影响，探讨了抗氧剂提高沥青耐老化性能的原因。

Surface phase separation behavior of these multiblock copolymer coatings was studied by atomic force microscopy with ultra-light tapping mode.

利用轻敲模式原子力显微镜观察了嵌段共聚物的表明形貌，研究了退火、共聚物组成以及PEG分子量和不同的官能团对涂层表面微相分离行为的影响，同时对微相分离行为的形成机理也作了相应的探讨。

Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克，果实色泽鲜艳，汁多味浓，甜酸适口，离核仁甜，清末时就驰名陕、甘两省，清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异：红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感，ED90值分别为47.65、71.67和29.17g/hm2；春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感，ED90值分别为96.91、114.20g/hm2；而番茄不敏感。