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十八酸

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Water,c12-20 acid peg-8 ester,caprylic/capric triglyceride,proplylene glycol,ppg-15 stearyl ether,chondrus crispus,iris germanica(orris extract/cells),centaurea cyanus,macadamia ternifolia,buxus chinensis,triethanolamine,potassium cetyl phosphate,butyrospermum parkii,c12-13 alkyl lactate,carbomer,phenoxyethanol,methylparaben,imidazolidinyl urea,glyceryl hydroxystearin,tocopheryl acetate.retinyl palmitate,sodium hyaluronate,biosaccharide gum-1,propylparaben,disodium edta,ethylparaben,pentadecalactone,hydroxystearic acid,tetradecyloctadecanoic acid,tetradecyleicosanoic acid,hexadecyleicosanoic acid,butylparaben,isobutylparaben,chlorhexidine digluconate,tocopherol,lecithin,ascorbyl palmitate,glyceryl stearate,glyceryl oleate,BHT,citric acid.

水,C12-20 酸 PEG-8酯,辛酸/癸酸三酸甘油酯,丙二醇,PPG-15 硬脂基醚,卡拉胶萃取,德国鸢尾花提取物/细胞,矢车菊提取物,澳洲坚果油,荷荷巴油,三乙醇胺,十六烷基磷酸钾,牛油果,c12-13烷醇乳酸酯,卡波姆,苯氧乙醇,羟苯甲酯,尿素醛,甘油羟基硬脂酸酯,醋酸盐维他命E,维他命A酯,透明质酸钠,多醣物质,羟苯丙酯,乙酸乙二胺二钠,羟苯乙酯,环十五内酯,羟基硬脂酸,十四烷基十八烷酸,十四烷基二十烷酸,十六烷基二十烷酸,羟苯丁酯,对羟基苯甲酸异丁酯,洗必泰葡萄糖酸盐,维生素E,卵磷脂,抗坏血酸棕榈酸酯,甘油硬脂酸,甘油油酸酯,BHT,柠檬酸。水:几乎所有护肤品成分第一位都是水。辛酸/癸酸三酸甘油酯:润滑剂、扩散剂,棕榈油/椰子油衍生物

Using peptide hydrolysis combined with amino acid analysis, sugar alcohol acetylation combining with GC/MS, fattic acid methyl esterization combining with GC/MS and other technical means it was identify carbohydrate in the bioemulsifier mainly was D-mannose, and main amino acids were glutamic acid, aspartic acid, alanine, and main fattic acids that composed lipid was hexadecanoic acid, octadecenoic acid, and octadecanoic acid.

利用肽水解结合氨基酸分析、糖醇乙酰化结合GC-MS、脂肪酸甲脂化结合GC-MS等技术手段鉴定乳化剂中糖主要为D-甘露糖;主要氨基酸为谷氨酸、天冬氨酸、丙氨酸;构成脂的主要脂肪酸为十六烷酸、十八烯酸和十八烷酸。

SM6 and SM7 of uncrystal were analyzed through GC-MS, the results showedthat SM6 main contained unsaturated fatty aldehyde with fragrance, i.e.-2,4-decadienal(58%), tetradecanoic acid (55.78%), 2-decenal(50%), Phthalic acid isobutylundecyl ester(47%), 2, 4-Decadienal(41%), 2-Undecenal (31%), 2-Methyl-Z,Z-3, 13-octadecadi-enol(18.84%), and SM7 contained saturation alkanes, i.e. 1, 2-Benzenedicarboxylic acid, butyl cyclohexyl ester(23.90%), Triacontane(22.63%),Nonacosane(21.04%), Heptadecane(18.84%), Octacosane(13.58%). Toxicological experiments were done to insure the pigment safety.

并对紫红丝膜菌色素非晶体部分的黄色油状物SM6和紫色粉末物SM7作了GC-MS分析,结果显示SM6中主要为具有香气成分的不饱和脂肪醛,其中含量较高的依次为:-2,4-癸二烯醛(58%)、十四烷酸(55.78%)、2-癸烯醛(50%)、邻苯二甲酸异丁基十一烷酯(47%)、2,4-癸二烯(41%)、2-十一碳烯醛(31%)、2-甲基-Z,Z-3,13-十八碳二烯酸(18.45%)等;SM7中主要为饱和直链烷烃,其中含量较高的依次为:1,2-苯二羧酸丁基环己酯(23.90%)、三十烷(22.63%)、二十九烷(21.04%)、十七烷(18.84%)、二十八烷(13.58%)。

The result indicated that the cellular fatty acid compositions of Salmonella, Escherichia coli, Vibrio and Shigella all contain tetradecanoic acid, hexadecanoic acid and octadecenoic acid, the total content is around 90%, in which the hexadecanoic acid is the most, above 40%, next is the octadecenoic acid, around 30%.

结果表明:沙门氏菌属、埃希氏菌属、弧菌属和志贺氏菌属全细胞脂肪酸组分都含有十四烷酸、十六烷酸和十八碳烯酸,这三种脂肪酸占总脂肪酸含量的90%左右,含量最高的是十六烷酸,含量在40%以上,其次是十八碳烯酸,含量在30%左右。

The nautre of ester bond and sedimentary medium condition control the distribution pattern of organic acid ester in strong reductional environment and water-washed oxidized crude oils. The former features higher contents both of 9, 11-Octadecadienoic acid, methyl ester and Hexadecanoic acid, showing the non-reversible hydrolysis reaction of ester bond in condition of basicity; the later features higher contents of Hexadecanoic acid and Octadeanoic acid, and lower contents of nonsaturated and side-chain acid ester, indicating the reversible hydrolysis reaction of ester bond in acid condition.

酯键的化学性质和沉积环境中介质条件,决定了强还原咸水盐湖相和淡水湖沼相经水洗氧化次生变化的原油有机酸酯的分布特征,前者9,11-十八二烯酸甲酯与正十六烷酸为主,反映酯键在碱性条件的不可逆水解过程,后者以正十六烷酸和正十八烷酸为主,烯酸和支链酸很少,反映酯键的酸性条件的可逆性水解,烯酸经氧化向正十八烷酸,正十六烷酸转化。

With intermediates 1,ω-hexadecanediol and ω-bromo pentadecanol as starting materials,ω-bromo hexadecanoic acid and ω-bromo octadecanoic acid were prepared in four and seven steps of reactions separately.

分别以1,ω-十五烷二酸和1,ω-十六烷二酸为原料,各经过四步有机反应,制备了ω-碘代十六烷酸及含十四、十五、十六碳原子的ω-溴代直链脂肪酸;再以中间产物15-溴代十五烷醇、1,ω-十六烷二醇为原料,各经过四步、七步有机反应,制备了ω-溴代十六烷酸及ω-溴代十八烷酸。

Results13 compounds were identified, which accounted for 100 % of the essential oil of the skins of stem. The major compositions were n-Hexadecanoic acid (46.13%); Octadecanoic acid (15.44%),-9-Octadecenoic acid (13.73%), and-9,12-Octadecadienoic acid (7.79%).

结果通过计算机检索、图谱分析法鉴定出13种化合物,占总油量的100%,其主要成分为正十六烷酸(46.13 %)、十八烯酸(15.44 %)、-9-十八烯酸(13.73 %)及-9,12-十八碳二烯酸(7.79 %)。

Our study show that 9, 11-Octadecadienoic acid, methyl ester is the highest content of organic acid ester components in non-hydrocarbon fraction, higher content of 6-Octadecenoic acid, methyl ester reflects mainly terristrial source input, higher content of pentadecane acid, 14-methyl, methyl ester or Heptadeeanoic acid, 16-methyl, methyl ester shows mainly aquatic source input.

原油和岩石抽提物非烃中有机酸酯类化合物的有机地球化学研究报道很少,系统研究发现非烃有机酸酯中9,11-十八二烯酸甲酯含量最高,而次高峰的丰度可用作生源判识,陆源母质输入多的样品次高峰为6-十八单烯酸甲酯,水生母质供给多者次高峰为14-甲基十五烷酸甲酯或16-甲基十七烷酸甲酯。

Third, volatilizable parts from Hainan Rauvolfia were obtained through water vapor distillation. They were analyzed by GC/MS. The resuts showed that about 10 compounds in the root essential oil were extracted and 9 of them were identified. Fatty acids and phenol ramification are the main types of the compounds.

用水蒸气蒸馏法获得了萝芙木中的易挥发组分,对其进行了GC/MS分析,分析结果表明,萝芙木根挥发油分离出10个峰,鉴定出9种化合物,其主要成分为9-十八烷酸、十六酸,棕榈酸、9,12-十八烷二酸、1H-酚[2,1-b] 喃-1-酮,分别占挥发油总量的25.66%、19.34%、18.12%、17.23%,四者占其总量的80.35%。

Third, volatilizable parts from Hainan Rauvolfia were obtained through water vapor distillation. They were analyzed by GC/MS. The resuts showed that about 10 compounds in the root essential oil were extracted and 9 of them were identified. Fatty acids and phenol ramification are the main types of the compounds.

用水蒸气蒸馏法获得了萝芙木中的易挥发组分,对其进行了GC/MS分析,分析结果表明,萝芙木根挥发油分离出10个峰,鉴定出9种化合物,其主要成分为9-十八烷酸、十六酸,棕榈酸、9,12-十八烷二酸、1H-萘酚[2,1-b]吡喃-1-酮,分别占挥发油总量的25.66%、19.34%、18.12%、17.23%,四者占其总量的80.35%。

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