加成化合物

The tin atom of the title molecule exists in a distorted- trigonal- bipyramidal geometry, defined by three carbon,one iodineand one oxygen atoms leading to a five - membered chelate ring. The x- ray analysis show tha...

标题化合物分子中的锡原子被配体的三个碳、一个碘和一个氧原子配位；配位原子是畸变的三角双锥构型；标题化合物具有与卤素发生取代反应而不发生加成反应的性质。

The test results indicate that the zincate catalyst systems can accelerate these reactions high-effectively, so its selectivity is up to 100% and TOF is 5472h -1, and the activity and the selectivity of the catalyst are kept in six times, and the catalyst system can be availab.

研究了离子液体助催化的各种无机盐催化剂体系用于二氧化碳和环氧化合物通过环加成反应制备环状碳酸酯，结果表明锌盐催化剂体系能够非常高效地催化该反应，最高得到了 5 472h- 1的催化转化频率和 10 0 %的选择性，催化剂使用六次以后没有发现催化活性和选择性的下降，并且该催化剂体系能够适用于各种结构的环氧化合物。

Chiral compounds Ⅰ for the first time was applied to allylation of acylhydrazones with allyltrichlorosilane and the results showed that the compound Ⅰ can contribute to the occurrence of the reaction.

首次将手性化合物Ⅰ应用于烯丙基三氯硅烷和酰腙的烯丙基化加成反应中，结果表明化合物Ⅰ能够促进该反应的发生。

The reaction products between disubstituted phosphinosilane and alkynes were those eliminating SiMe3 after addition rather than those via normal addition.

二取代膦基硅烷和炔类化合物之间的反应不是一般的加成产物，而是加成后SiMe3被H消去的产物。

In Granards' reactionof fluorinated β-ketophosphonium salts we found differentGranard reagents give different reaction mechanisms andPhMgBr realized the enolate reaction of fluorinatedβ-keto-phosphonium salts.

在研究含氟β-酮基鏻盐的β位亲核加成反应中，我们利用含氟α-烷氧基-β-酮基鏻盐与有机锂试剂的亲核加成反应一锅法高度立体选择性地合成了E式或Z式三氟甲基的烯醚类化合物。

Olefine, electrophilic or nucleophilic substitution of arenes, nucleophilic addition of carbonyl compounds stereochemistry in elimination reaction of double bond forming and the choosing of oxidants and reducing agents in redox system.

在化学反应方面重点是烯烃的亲电加成，芳香烃的亲电，亲核取代，羰基化合物的亲核加成，消除反应的双键定位和立体化学，氧化，还原反应中氧化还原剂的选择。

That 1,4-addition reactions of Grignard agent made from 1-bromo-3-triphenylmethoxyl-1-octene and organozinc agent made from 1-iodo-3-trimethysiloxy-1-octene with 2-(6-methoxylcarbonylhexyl)-4-(2- tetrahydro-pyranyloxy)-2-cyclopentenone both gave prostaglandin 〓 methyl ester statethat prostaglandin E compounds can be prepared by 1,4-addition reaction oforganozinc agent.

最后，研究了溴化-3-三苯甲氧基-1-辛烯基镁和碘化-3-三甲硅氧基-1-辛烯基锌与2-(6-甲氧羰己基)-4-(2-四氢吡喃氧基)-2-环戊烯酮通过1，4-加成反应合成〓甲酯的方法，结果表明，用有机锌试剂通过1，4-加成反应来合成PGE类化合物是可行的。

We have presented a practical method for the preparation of propargylic alcohols from terminal alkynes and carbonyl compounds promoted by KOH in the presence of 18-crown-6,and subsequent efficient cyclizations of propargylic alcohols with 2-naphthol catalyzed by InCl_3·4H_2O under the solvent-free ball-milling conditions.Ball milling exhibits its superiority over the reported methods in the preparation of propargylic alcohols and naphthopyran derivatives.

采用机械研磨方法进行了连续的两步固相化学反应的研究：首先，在氢氧化钾和18-冠-6的作用下，端基炔和羰基化合物在机械研磨条件下反应可以高效地生成相应的炔醇化合物；其次，在四水合三氯化铟的催化作用下，生成的炔醇化合物和2-萘酚在机械研磨条件下环加成生成相应的萘并吡喃产物。

To optimize the reaction condition for the purpose of target compounds synthesis, the advance of 1,3-dipolar cycloaddition and click chemistry is reviewed. The conditions of the reaction between azides or nitrile oxides and terminal alkynes were optimized experimentally and the best operation condition was established.

论文综述了偶极环加成反应和点击化学的进展，特别对Cu催化的腈氧化物或叠氮化物与端炔化合物之间的1，3-偶极环加成反应进行了理论分析与实验研究对反应条件进行了优化，确立了实验室中进行反应的最佳操作条件。

Alkylbenzene, normal alkanes and alkylcyclohexane on the pyrolysates of P. Boryanum at 300℃ had uniform distribution and the relative content of them was similar, indicating that they originated from same precursors. Fatty acids, alcohol and ketone in algal cell are the possible precursors. For example, the precursor of relatively abundant C〓 alkylbenzene and alkylbenzene with C〓 side chain perhaps related with palmitic acid. N-alkylnaphthalene in pyrolysates at 300℃ probably derived from alkylation of cleavage products of aromatic steranes and terpanes.

在盘星藻300℃热解产物中，烷基苯、正烷烃和烷基环己烷碳数分布一致、各化合物的相对含量接近，表明它们有相同的来源，藻类体内的脂肪酸、醇和酮及细胞壁等物质可能是其母质，相对含量较高的碳数为16及侧链碳数为16的烷基苯类化合物，其前身物可能与软脂酸有关。300℃热解产物中的正烷基萘类化合物，可能由芳香甾、萜类的降解产物与直链烃类加成烷基化而形成。

Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克，果实色泽鲜艳，汁多味浓，甜酸适口，离核仁甜，清末时就驰名陕、甘两省，清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异：红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感，ED90值分别为47.65、71.67和29.17g/hm2；春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感，ED90值分别为96.91、114.20g/hm2；而番茄不敏感。