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丁酮

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Experimental process: jing and 3- methyl -2- methyl ethyl ketonesynthesizes by the benzene zong; Again the glacial acetic acidcatalysis produces 2, 3, 3 - trimethyl - 3H - yinduo; Again has thealkylate response production yinduo iodide after the methyl iodide;The iodide takes off molecular HI under NaOH to become freejier thealkali; Adds 5 - nitryls salicylic aldehydes in the ethyl alcohol forthe solvent under if to respond finally produces 6 '- the nitryl yinduolin spiral benzene and pinan; Through the infrared spectrum andthe ultimate analysis irrevocably proved its structure, and studiedthe annulus with to open the annulus the light to send changes colorthe performance, explained in different solvent medium ultravioletabsorption spectrometry solvent effect, and the comparisondiscoloration the response speed number difference, finally mixed itadds to the methyl methacrylate, the peroxidation benzoin formyl in the plexiglass, tested 6 '- the nitryl yinduolin spiralbenzene and pinan in the glass fatigue resistance, thethermostability.

实验过程:由苯肼和3-甲基-2-丁酮合成腙;再冰醋酸催化生成2 ,3 ,3—三甲基—3H—吲哚;再经过碘甲烷发生烷基化反应生成吲哚碘化物;碘化物在NaOH下脱去一分子HI成为费歇尔碱;在乙醇为溶剂下加5-硝基水杨醛与其反应最后生成6'—硝基吲哚啉螺苯并吡喃;通过红外光谱和元素分析确证其结构,并研究了环体与开环体的光致变色性能,解释了在不同溶剂介质中紫外吸收光谱的溶剂效应,并比较褪色反应速率数的差异,最后将其掺加到甲基丙烯酸甲酯,过氧化二苯甲酰有机玻璃中,测试6'—硝基吲哚啉螺苯并吡喃在玻璃中的抗疲劳性、热稳定性。

The activity of pyruvate formate-lyase and pyruvate dehydrogenase accounts for the observed production of formate, acetate, ethanol and acetoin. In 1978, Hillman isolated one of the mutants of Streptococcus mutans which lack the enzyme activity of dehydrogenase.

当外源性糖丰富的时候,果糖-1,6-二磷酸增加,使LDH活化,90%以上的葡萄糖被转化为乳酸;外源性糖供应不足时,通过丙酮酸甲酸裂解酶和丙酮酸脱氢酶作用产生甲酸、乙酸、3-羟基丁酮和乙醇。

Organic substances (diethylene glycol, glycol methyl ether and methyl ethyl ketone) were used as nonsolvent additives and N-methyl-2-pyrrolidone used as a solvent in membrane preparation. The effects of PPESK concentration, the type of additives and the NSA concentration in casting solution on the morphology and performance of the PPESK hollow fiber ultrafiltration membrane were systematically investigated.

以PPESK为膜材料,NMP为溶剂,水为凝胶剂,选用乙二醇甲醚、一缩二乙二醇和丁酮为非溶剂添加剂,系统研究了聚合物浓度、添加剂种类和含量对PPESK中空纤维超滤膜结构和性能的影响,制备了一系列具有不同孔径和通量的中空纤维超滤膜。

The phase separation behavior of different nonsolvent additives (methyl ethyl ketone, glycol methyl ether and diethylene glycol) on PPESK casting solution was studied at 20℃according the linerized cloud point correlation.

结合线性浊点关系,根据浊点滴定试验,通过三元相图研究了20℃下非溶剂添加剂(丁酮,乙二醇甲醚,一缩二乙二醇)对PPESK铸膜液体系的相分离行为。

When the catalyst was triethylamine, the water produced in condensation of isopropanolamine or ethanolamine and butanone was removed with benzene by water segregator, then the dichloroacetyl chloride was dropped.

利用异丙醇胺、乙醇胺、丁酮和二氯乙酰氯为原料,分别合成了两种除草剂安全剂Ⅰ∶3-二氯乙酰基-2,5-二甲基-2-乙基-1,3-噁唑烷和Ⅱ∶3-二氯乙酰基-2-甲基-2-乙基-1,3-噁唑烷。

Sodium(3 S,4S)-3-amino-4--2-ox-Oazetidine-1 -sulfonate is its key intermediate, a chiral zwitterion.

手性内盐(3S,4S)-3-氨基-4-氨甲酰氧甲基-2-氧代氮杂环丁酮-1-磺酸钠是卡芦莫南的关键中间体。

Then fed-batch fermentation was performed with glucose feeding. The yield of acetoin achieved at 20 g/L in fed-batch fermentation with glucose feeding.

在优化的发酵条件下,采用分批补糖的工艺,摇瓶发酵产量可稳定在20g/L以上,为3-羟基-2-丁酮的工业化生产提供了一定的基础。

It shown that PDC does not only catalyze the production of acetaldehyde (PDC's main activity), but also catalyzes an aldoltype condensation reaction in which the hydroxyethyl-ThDP intermediate of enzyme is condensed with a second acetaldehyde to form acetoin.

在研究中发现PDC不仅能催化产生乙醛,还具有醛连接酶的活性。即将二个乙醛分子缩合成3-羟基丁酮,尽管这个活性比产生乙醛的活性低得多。

LacZ gene was fused with the promoter of the acoR gene and bkdR gene, and two recombined genes were expressed in sigL mutant strain and HD-73 wild strain sequentially.

分别将调控aco操纵子(编码3-羟基丁酮脱氢酶系统)的转录调节基因acoR和调控bkd操纵子(编码催化支链脂肪酸合成的酶系统)的转录调节基因bkdR的启动子与lacZ基因融合,并转入出发菌株和sigL突变体中,测定b-半乳糖苷酶的活性。

Results Six compounds were isolated from the ethanol extracts of Acrostichum aureurm,and their structures were elucidated as ponasterone A(1),pterosterone(2),kaempferol(3),quercetin(4),4-(3,4-dihydroxyphenyl)-2-butanone(5),and daucosterol(6),respectively.

结果从卤蕨乙醇提取物中分离得到6个化合物,分别鉴定为ponasterone A(1)、pterosterone(2)、山奈酚(3)、槲皮素(4)、4-(3,4-二羟基苯基)-2-丁酮(5)、胡萝卜苷(6)。结论6个化合物均为首次从该植物中分离得到。

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Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克,果实色泽鲜艳,汁多味浓,甜酸适口,离核仁甜,清末时就驰名陕、甘两省,清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异:红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感,ED90值分别为47.65、71.67和29.17g/hm2;春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感,ED90值分别为96.91、114.20g/hm2;而番茄不敏感。

However, I have an idea.

不过,我有个主意。