查询词典 valence shell

We found out one kind of new orange-red long afterglow material La2O2S: Eu3+, Mg, Zr.2 In the phosphor Gd2O2S, Mg, Ti which was prepared by high-temperature solid-state method, the orange afterglow phenomenon can be seen after illuminated with UV light.3 Using the high-temperature solid-state method, Gadolinium oxysulfide phosphors doped with rare earth ions were synthesized. We can observe the red or orange phosphorescence in Gd2O2S doped with Eu3+, Sm3+, Tm3+, Yb3+, Dy3+, Er3+, Nd3+or Ho3+. This is a new result of the long afterglow phosphors research.4 Using the microwave radiation method, the new Sm3+ doped gadolinium oxysulfide phosphor, which has the orange-red long afterglow emission after illuminated with UV light or visible light, was synthesized for the first time.5 In fluorescent materials YOX doped with europium ions, the long afterglow phenomenon wasnt observed but the blue luminescence of Eu2+ and red luminescence of Eu3+ are simultaneously examined. This is a new result of the valence stability and change of Eu2+ in yttrium oxyhalide .We systematically studied the effects of the host, addition agents and reaction atmosphere on the valence change and fluorescence property of europium ions.

经过系统的研究总结得到以下的结论与成果： 1采用高温固相反应法合成了一系列稀土离子掺杂的硫氧化镧发光粉，发现了该体系中Eu~(3+)的长余辉发光，从而得到一种迄今未见文献报道的红色长余辉发光材料：La_2O_2S：Eu~(3+)，Mg，Zr； 2在Gd_2O_2S，Mg，Ti磷光粉中观察到橙色的长余辉发光现象； 3采用高温固相反应法合成了一系列稀土离子掺杂的硫氧化钆磷光粉，在掺杂Eu~(3+)、Sm~(3+)、Tm~(3+)、Yb~(3+)、Dy~(3+)、Er~(3+)、Nd~(3+)、Ho~(3+)的Gd_2O_2S中观察到红色和橙色长余辉发光； 4首次采用微波法合成了Gd_2O_2S：Sm~(3+)，Mg，Ti磷光粉，该磷光粉经紫外或可见光激发后呈现明显的橙红色长余辉发光； 5在YOX中同时观察到Eu~(2+)和Eu~(3+)的发射，系统研究了基质、添加剂及反应气氛对Eu价态和发光的影响。

The colors of barrel plating are :triatomic chromiumblue/white/colorful/black zinc, chromium with a valence of sixblue/white/colorful/black zinc, pure copper, bright nickel, chemical nickel ,black nickel ,bronze, chromium and so on; the colors of the rack plating are : triatomic chromiumblue/white/colorful/black zinc, chromium with a valence of sixblue/white/colorful/black zinc, pure copper, bright nickel, chemical nickel ,black nickel ,bronze, chromium and so on.

随着市场发展需要，公司电镀生产线迁入博罗县石湾镇，投资设立金城五金电镀厂，总面积 9000平方米，专业加工电镀各种螺丝、五金件，设备齐全，实力雄厚，滚镀的颜色有：三价铬兰/白/彩/黑锌、六价铬兰/白/彩/黑锌、红铜、亮镍、化学镍、枪黑镍、青铜、青古铜、铬等不同颜色，挂镀的颜色有：三价铬兰/白/彩/黑锌、六价铬兰/白/彩/黑锌、红铜、亮镍、化学镍、枪黑镍、青铜、青古铜、铬等颜色，镀种齐全，月生产能力可达 800 余吨。

Inhibition efficiency of these inh ibitors decrease with the increase of free valence of N atom; Otherwise inhibiti on efficiency increase with the increase of summation of free valence in pyridin e ring .

这些缓蚀剂随着N原子自由价的增大，缓蚀效率降低；而随着吡啶环自由价之和的增加，缓蚀效率提高。

When examining the relative positions of the valence band and the conduction bands in Table 2, it is evident that it is in fact thermodynamically feasible for the generated electrons in titanium dioxide to be transferred to the lower lying conduction band of any the iron oxides phases present, while the photogenerated holes may also be transferred to the upper lying valence bands of the iron oxides.

当检查原子价的比较位置的时候表 2 的乐团和传导乐团，它是显然的那它事实上热力学能实行对钛二氧化物的被产生的电子被转移对比较低的横躺传导乐团任何的那氧化铁时期呈现，当 photogenerated的时候洞也可能被转移到上面的横躺原子价氧化铁的乐团。

One is low valence vanadium oxide thin films were deposited by direct current facing target magnetron sputtering firstly, and then thermal oxidated; the other is high valence vanadium oxide thin films were deposited by ion beam sputtering, then thermal deoxidated. Vanadium oxide thin films with phase transition were obtained at the lower thermal process temperature 300℃, which is compatible with MEMS technologys. The composition of VO_x thin film fabricated by first method includes mainly VO_2, V2O3 and VO_, the TCR is -2.25%/K, the TCR gradually increases with phase transition temperature decreases. The composition of VO_x thin film fabricated by the second method includes mainly VO_2, V2O5 and V2O3 , and the resulting VO_x thin filmTCR is -3.0%/K. The TCR of phase transition vanadium oxide thin films made by second method is higher than that made by first method for the existance of V2O5 in thin films.

分别采用直流对靶磁控溅射制备低价态氧化钒薄膜再附加热氧化处理的方式，和射频离子束溅射制备高价氧化钒薄膜附加热还原处理的方式获得了具有相变特性的氧化钒薄膜，第一种方式获得相变特性氧化钒薄膜的热处理温度最低为300℃，克服了以往高温条件下热处理不能与MEMS工艺兼容的缺点；相变特性氧化钒薄膜的组分以VO_2为主，含有V2O3和VO_，室温TCR为-2.25%/K；室温电阻温度系数随相变温度的降低逐渐升高；采用第二种方式获得的相变氧化钒薄膜的组分以VO_2为主，含有V2O5和V2O3，室温TCR可达-3.0%/K；分析发现，具有相变特性的氧化钒薄膜中含有V2O5时，室温电阻温度系数明显增大。

High temperature is favorable to the formation of low valence state-As minerals and to the addition of As into pyrite crystal lattice, thus is favorable for the formation of P type of pyrite. However, at low temperature, high valence As minerals are easily formed and this case is not suitable for As to add into the pyrite crystal lattice to substitute S, thus the low temperature is beneficial to the formation of N type of pyrite.

As在白然界中的赋存状态与温度的关系表明：高温有利于形成低价态的As矿物，也有利于As呈低价态进入黄铁矿晶格中替代S而形成P型导电；低温则有利于形成高价态As的独立矿物，不利于As呈低价态进入黄铁矿晶格中替代S。，因而有利于形成N型导电。

The formal potentials in cyclic voltammograms of these 3+ valence complexes are followed: Co〓-TPPS (-0.08V )＞Fe〓TPPS (-0.14V)＞Mn〓-TPPS (-0.23V). The electrochemical reaction of Mn〓-TPPS is reversible, and both of Co〓-TPPS and Fe〓-TPPS are quasi-reversible. The standard heterogeneous rate constants of Co〓-TPPS and Fe〓-TPPS were determined to be 1. 4×10〓cm/s and 1.4×10〓cm/s respectively. The rates of electrode reaction are as followed: Mn〓-TPPS＞Co〓-TPPS＞Fe〓-TPPS, e.i. Mn〓-TPPS is the most easily oxidized by the dissolved oxygen, and Fe〓-TPPS is oxidized slower than Co〓-TPPS. Ni〓-TPPS can not be oxidized. It is considered that oxygen plays an important role in the valence change of central metal atom and the rate of electron transfer in some metalloporphyrins.

三价金属卟啉络合物在循环伏安图上可得到三价到二价的还原和氧化响应，电极电位从大到小排列为：Co〓-TPPS(-0.08V)＞Fe〓-TPPS(-0.14V)＞Mn〓-TPPS(-0.23V)，电极反应可逆性也不相同，Mn〓-TPPS是可逆过程，Co〓-TPPS、Fe〓-TPPS是准可逆过程，实验测得Co〓-TPPS的标准电极反应速率常数ks＝1.4×10〓cm/s，Fe〓-TPPS的ks＝1.4×10〓cm/s，电极反应的速率从大到小为：Mn〓-TPPS＞Co〓-TPPS＞Fe〓-TPPS，即Mn〓-TPPS最容易被溶解氧所氧化，Fe〓-TPPS被氧化的速度最慢，Ni〓-TMPyP不能被氧化，因此我们认为溶解氧对金属卟啉中心离子的价态和电子转移速率起着重要作用。

The affecting factors of ammonification on natural lignin materials, which include shell of sunflower seed, shell of walnut seed and shell of apricot seed, were studied.

研究了天然木质素瓜子壳、核桃壳、杏核壳三种原料化学加氨的影响因素。

Research on techniques for the synthesis of ACR impact modifier with core-shell structure;2. Preparation of polymer-tungsten-silica composite microspheres with multi-layer core-shell structures;3. Organosilicon-acrylate micro emulsion with core-shell structure was synthesized with OP-10,JFC and amyl alcohol nonionic compounded emulsifier by means of seeded emulsion polymerization.

运用种子乳液聚合工艺以OP-10/JFC/戊醇非离子复合乳化剂合成了具有核-壳结构的有机硅-丙烯酸酯微乳液，研究了复合乳化剂类型、丙烯酸酯单体、有机硅单体加入方式和含量、pH值、硫醇对微乳液聚合过程中稳定性和光泽度的影响，通过差示扫描量热仪和透射电镜对微乳液的结构进行了表征。

The basic approach of protecting people from being hurt or killed in an accident is to improve crashworthiness of vehicles. This paper starts with discussing theories and methods for vehicle passive safety design, which included experiential methods, analytic methods, multi-body dynamics methods, crash test methods and the finite element method. Emphasis will be paid to the basic FEM theories and algorithms of impact problems. Topics discussed include the governing equation, element discretization, hourglass control, time integration, material model, shell element algorithms and contact-impact algorithms. For more reliable simulation results, this paper then conducts study on how to accurately get material model parameters by combining the FEM method with experimental method, and develops relevant material test machine and parameter calculating software. Based on that, basic typical impact simulation and test validation study are conducted. On the basis of the above work, the paper studies the thin-shell structures'crashworthiness, which was affected by the following factors: spot-weld features, shell thickness, cross-section and pre-deformation. As to vehicle parts'crashworthiness, the paper conducts simulation study of designing energy-absorbing steering system and adaptive airbag system. A practical energy-absorbing steering wheel is designed as an example. In further depth research, the paper suggests several inverse quantificational methods for vehicle crashworthiness design based on the ideal crash characteristics. The above theories and methods are applied with good results through several practical vehicles' crashworthiness design and improvement.

文中对汽车碰撞安全性的设计理论和方法进行了归类和总结，其中包括经验法、解析法、多刚体动力学法、试验法以及有限元方法等；重点介绍了碰撞有限元法的基本理论和有关算法，涉及到有限元求解控制方程、单元离散、沙漏模态控制、时间积分、材料模型和应力修正、薄壳单元算法以及接触碰撞界面算法等，探讨了有限元计算中的材料模型参数获取技术，开发了相应的材料试验装置及材料模型参数反求软件，在此基础上进行了基本的碰撞仿真算例和试验对比研究；文中通过应用有限元方法研究了薄壁构件的碰撞吸能特性，指出了设计薄壁吸能构件时需要考虑的几个主要影响因素，即焊点、壁厚、横截面和预变形等；在关于车辆部件的碰撞安全性能设计中进行了吸能转向机构和自适应安全气囊的仿真研究，提出了吸能转向机构和自适应安全气囊的仿真研究方法；文中最后探讨了整车碰撞性能的设计与改进方法，提出了以理想碰撞特性为目标，采用分段加速度或者根据碰撞时间进行设计的反推设计法、部件吸能仿真优化设计法等量化设计方法，并通过综合应用文中所讨论的相关技术进行了整车碰撞性能的设计与改进实例研究，所选定的车型是大众化的普通轿车和碰撞安全性基础较差的微型面包车，研究结果表明，本文所提出的设计与改进方法是适用而有效的，具有重要的工程实用意义和价值。

There are different types of personal loans available.

有许多不同类型的个人贷款优惠。

The above mentioned teaching model of spiral rising can be used to avoid rigidness in teaching.

上述螺旋式上升的教学模式，可以避免教学形成模式後的僵化现象。