查询词典 substitution group

Finally, we compare o-dimethoxybenzene with other benzene derivatives to discuss the influence of vicinal substitution effect and substituent group effect on the electronic transition, ionization energy and molecule vibration.

最后将把结果与其他苯衍生物的结果相互比较，而进一步得到取代基效应和邻近效应对电子跃迁、游离能及分子振动的影响。

Many participation enterprises have demonstrated the independent research and development technology: The Guangdong Mengnalisha ceramics Limited company's most new high science and technology ceramics product ---"the PP board", its thickness only has 5.5 millimeters, had passed on the integrated construction ceramic all functions, but its needed materials were merely the traditional ceramics 1/3, thus has saved raw material amount used greatly, reduced the packing transportation cost; Beijing passes permanently innovates wooden models the technological progress Limited company independent research and development the lumber substitution product match woodware, has the waterproof moisture-proof anticorrosion, the intensity to be high, the turnover number of times many, can recycle, characteristics and so on environmental protection, security; Dalian iceberg group take the technology and the talented person as a backing, makes light highly effective, safe reliable Leng Re, the ecology, the energy conservation, the environmental protection new product with all one's strength, is also the exhibition luminescent spot.

很多参展企业展示了自主研发的技术：广东蒙娜丽莎陶瓷有限公司的最新高科技陶瓷产品———"PP板"，其厚度仅有5.5毫米，具备了传统建陶的所有功能，但其用料仅仅是传统陶瓷的1/3，从而大大节省了原料用量，减少了包装运输成本；北京恒通创新木塑科技发展有限公司自主研发的木材替代产品赛木制品，具有防水防潮防腐、强度高、周转次数多、能回收、环保、安全等特性；大连冰山集团以技术和人才为依托，全力打造的轻型高效、安全可靠的冷热、生态、节能、环保新产品，也是展会亮点。

Computationalresults indicate that the no-planar trans-benzanilide is the most stable structure. The spectra indicate that the Franck Condon region photodissociation dynamics have multidimensional character withnine activemodes. The intensity of υ24 mode in methanol is much stronger than that in acetonitrile. Compared with fatty amides and benzamide, phenyl substitution for H atom on-NH2 group makes C=O solvent effects disappear.

结果表明，苯甲酰苯胺的非平面反式结构为最稳定结构；在Frank-Condon区域内，苯甲酰苯胺主要由9个活性振动模组成；其中ν24（苯环上C＝C不对称伸缩振动和CCH的面内弯曲振动，NH面内弯曲振动）振动模在甲醇溶剂中的强度远远大于其在乙腈的强度；与脂肪酰胺类化合物和苯甲酰胺的研究结果比较发现，苯基取代－NH2上的H原子使得C＝O不再具有明显的溶剂效应。

In this thesis, investigations focused on heteropoly acids-catalyzed C-C and C-N bond formation reactions and the synthesis of xanthenediones and acridinediones under thermal conditions are described.1.12-Phosphotungstic acid has been used as an efficient,eco-friendly,and air- and moisture-stable catalyst to promote the direct dehydrative substitution of the hydroxy group of benzylic and allylic alcohols with variousβ-dicarbonyl compounds.

本篇论文主要描述了杂多酸催化下的C-C和C-N键的生成，以及无溶剂直接加热下合成十氢氧杂蒽二酮和9-芳基十氢吖啶二酮。主要内容如下：1。在磷钨酸催化下，1，3-二羰基化合物与醇能够顺利偶合，脱除一分子的水，生成烷基化的1，3-二羰基化合物。反应在甲苯中进行时，二芳基甲醇能与各类1，3-二羰基化合物反应，成率很高；但对于1-苯乙醇，只能得到很低的产率。

Starting from 3, 5-dihydroxybenzoic acid, a total of 16 kinds of salicylicaldehyde derivatives have been synthesized by the esterification, substitution, reduction, formylation, condensation, brominate, functional group protection and deprotection reactions, of which 11 have not been reported yet. Enatiomerically pure 2-amino-2'-hydroxy-1, 1'-binaphthyl has been easily obtained from its racemic mixture by the eantioselective formation of inclusion crystals with N-benzylcinchoninium chloride.

树枝状大分子希夫碱三齿手性配体的设计与合成从3，5-二羟基苯甲酸出发，通过酯化、取代、还原、甲酰化、缩合、官能团的保护与去保护等反应合成了四个系列16种水杨醛衍生物，其中11中是未见文献报道的新化合物。

The proposition of reaction pathway suggested that the initial degradation of pyridaben proceed via C-S bond cleavage between phenyl ring and heterocyclic group, and then promote a serious of reactions such as substitution, oxidation and dealkylation.

反应路线推导表明降解哒螨酮首先是在苯环与杂环之间C-S键处断裂为两个部分，接着发生取代、氧化，去烷基等系列反应。

In conclusion, a catechol moiety is presumably to be essential for its activity and substitution of the p-hydroxybenzyl group at C-1 position with correct stereochemistry in the isoquinoline molecule makes a great contribution to the activation of beta adrenergic receptors.

本实验初步结果发现，对於去甲基乌药碱分子之药效，catechol基是必备无疑；而异喹啉环的碳－1位置上取代的p-hydroxybenzyl基对於药效有非常大的影响；至於其立体化学的配位是有立体选择性的。

The polycondensation of the benzoguanamine and pyromellitic Dianhydride was carried out under microwave irradiation, and the resulted polyamic acid was grafted with TDI-para position substitution aniline derivatives. Thus graft polymers with different electronic effect of the end group in side chain were obtained.

将微波辐射合成的苯代三聚氰胺-均苯四酸二酐体系的PAA与TDI-对位取代苯胺衍生物反应，通过改变TDI－对位取代苯胺衍生物的对位取代基来合成具有不同电子效应的侧链端基的接枝聚合物。

A single crystal complex [Ni2(H2O)2]2DMSO(Hqina=quinaldinic acid, DMSO=dimethyl sulfoxide) was synthesized at room temperature by the solvent substitution method, which belongs to monoclinic system with space group C2/m.

在常温下，通过溶剂置换法制备了[Ni2(H2O)2]2DMSO单晶，其中qina为喹哪啶酸根，DMSO为二甲亚砜。

It is reviewed that sulfamic acid can be utilized as a green catalyst in many important organic reactions such as esterification and transesterification,group protection,imino-Diels-Alder,rearrangement,substitution and condensation.

综述了近年来氨基磺酸作为一种绿色催化剂在有机合成中的应用，主要包括酯化与酯交换、基团保护、氮杂Diels-Alder、重排、取代及缩合等反应。

Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克，果实色泽鲜艳，汁多味浓，甜酸适口，离核仁甜，清末时就驰名陕、甘两省，清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异：红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感，ED90值分别为47.65、71.67和29.17g/hm2；春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感，ED90值分别为96.91、114.20g/hm2；而番茄不敏感。