查询词典 silica

In this study, the amino propyl trimethoxy silane was used for the surface modification of silica, and the modified silica was adsorbed to surface of clay/silica (SiO2 : Clay = 4:1 and 2:1) and the clay/silica was adsorbed by the surfactant. Also, we used Dimethyldistearylammonium chloride and Dodecyltriphenylphosphonium surfactant to modify clay/silica. Then we prepared the Epoxy/clay/silica nanocomposites and Epoxy/clay/silica/DOPO composites.

中文摘要本研究利用胺基矽氧烷改质二氧化矽，并将改质二氧化矽吸附於蒙脱土上(SiO2 ： Clay = 4：1与2：1)再分别以Dimethyldistearylammonium chloride 与Dodecyltriphenylphosphonium界面活性剂改质蒙脱土/二氧化矽并与环氧树脂制备成复材，并且再另外加入含磷阻燃剂 9，10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide与环氧树脂制备成复材。

Study on silica fume at the Scandinavian countries, in spite of the 20th century, the 50's people have a better understanding of the role of silica fume and a preliminary study, but applied to actual projects from the beginning of 70's, first of all, Norway and Sweden and other countries in the port terminals, the North Sea oil fields and underground parts of mines in the silica fume concrete, in 1982, Norway in V Bashang Minoves formally adopted the silica fume concrete dam, the 20th century, the early 80s established in Quebec, Canada silica fume concrete, and large volume of silica fume concrete to carry out pilot studies, mixing high-grade 10,000 cubic meters of concrete, the United States in 1983 a patch of concrete with silica fumekatcha River Dam stilling basin well.

研究硅粉在斯堪的纳维亚国家，尽管在20世纪50年代的人有更深入的了解方面所起的作用和硅粉的初步研究，但应用到实际项目从一开始的70年代，首先，挪威与瑞典和其他国家的港口码头，北海油田和地下部分地雷硅粉混凝土，在1982年，挪威钒坝上米诺维斯正式通过硅粉混凝土坝， 20世纪80年代初成立在加拿大魁北克硅粉混凝土，以及大量的硅粉混凝土进行试验研究，混合高档一点○万立方米具体，美国在1983年一块混凝土二氧化硅fumekatcha江水库消力池以及。

Three part of research works had been carried out in the dissertation. The first part: a kind of multidentate amine modified silica gel was synthesized through the following steps:(1) introduce the amino groups onto the surface of silica-gel by the treatment of surface silanol groups withγ-aminopropyl trimethoxy silane;(2) michael addition of excess trihydroxymethyl propyl triacrylate to amino groups on the silica gel surface;(3) amidation of the unreacted double bonds of TMPTA on the surface of TMPTA modified silica gel with diethylenetriamine;(4) the multidentate amine modified silica gel was finally obtained by the reaction of amino groups on the surface of DETA modified silica gel with double bond of butyl acrylate.

本论文进行了三部分研究工作，第一部分：通过多步反应对硅胶进行改性合成了一种多齿胺改性硅胶配体，合成过程如下：1通过γ-氨丙基三甲氧基硅烷与硅胶表面的硅羟基反应，使硅胶表面带有氨基；2利用硅胶表面氨基与过量的三羟甲基丙烷三丙烯酸酯发生Michael加成反应；3利用二乙烯三胺与TMPTA改性硅胶表面未反应的双键发生反应使硅胶表面氨基化；4最后用丙烯酸正丁酯与DETA改性硅胶表面氨基充分反应成功合多齿胺改性硅胶配体。

The main object of this research is to investigate synthesis of Cu23Cl Cu and CuO nanoparticles through electrospinning and heat-treated method The research is mainly focused on preparative parameter and the change of heat-treated temperature to form the nanoparticles inlaid in silicon fibers the shape and color change are dicussed First of all to prepare the Polyvinyl butyral and silica dioxide complex nanofiber by electrospinning and then to investigate different heat-treated temperature and reactive time to being an influence on the products The results detected by SEM XRD TEM EDS FTIR combined sol-gel process and electrospinning can prepare Polyvinyl butyral and silica complex nanofiber The experimental result is found when heat-treated temperature is 100~4750C it can produce Cu23Cl nanoparticles; Above 4750C~ 4900C it can produce Cu nanoparticles; Above 450~7000C it can produce CuO nanoparticles And the viscosity is lain between 20~40cp and the sol-gel process time is 3hr it can produce the thinner fibers The average diameter of the fibers are 107 88±21 01nm;Due to the nanoparticles inlaid in the silica fibers the thinner fibers can be inlaid the smaller nanoparticles so this is the result that the experiment is expected To calcine the complex fibers is to produce surface silica fibers contain Cu23Cl Cu and CuO nanoparticles due to surface plasma resonance it make the color of the fibers become yellowish green from light white green turn into the red nuclear finally As the experimental result to utilize sol-gel process combine electrospinning can produce porous silica fibers contain Cu23Cl Cu and CuO nanoparticles

本研究旨在探讨「利用放电纺丝和热处理法来合成Cu23Cl、Cu和CuO奈米粒」之研究，实验著重在制备参数与热处理温度变化对所形成的奈米粒镶嵌在二氧化矽纤维中的形态与颜色变化探讨。首先，利用放电纺丝法制备出聚乙烯醇缩丁醛及二氧化矽之奈米纤维，比较不同的热处理温度与反应时间的改变对产物生成产生影响，进而研究不同热处理温度和时间对生成奈米粒的影响。产物经由SEM、XRD、TEM、EDS和FTIR等仪器分析结果显示，结合溶胶-凝胶法(sol-gel process)和放电纺丝法可产生聚乙烯醇缩丁醛及二氧化矽复合奈米纤维。实验结果发现，若热处理温度在100~4750C下可得到Cu23Cl奈米粒，475~4900C 可得Cu奈米粒，450~7000C以上可得 CuO奈米粒。而黏度介於20~40cp间和溶胶-凝胶时间为3hr时，可产生直径比较细的纤维，纤维直径为107 88±21 01nm；且由於奈米金属颗粒镶嵌在二氧化矽纤维中，直径比较细的纤维，可以得到比较小的奈米金属颗粒，这与实验预期相符。而锻烧此复合物产生多孔的二氧化矽纤维并包含Cu23Cl、Cu和CuO奈米微粒时，由於表面电浆子共震关系，而使纤维颜色由淡白黄绿色变成黄绿色，再变红褐色。由实验结果得知，利用溶胶-凝胶法(sol-gel process)结合放电纺丝法和不同热处理温度，可产生Cu23Cl、Cu和CuO奈米粒镶嵌在二氧化矽纤维。

One route was that the amino-groups on the silica gel were transformed to tertiary amines by Eschweiler-clarke reaction that amine-groups react with formaldehyde and methanoic acid to prepare tertiary amines; the silica gel intermediates with tertiary amine groups reacted with chorohydrocarbons to prepare insoluble silica gel quaternary ammonium salt bactericides. Another route was that the amino-groups on the silica gel reacted with excessive chlorohexadecane; the preparing intermediates were quaternized with iodomethane to obtain insoluble silica gel quaternary ammonium salt bactericides.

一条路线是根据埃施韦勒-克拉克(Eschweiler-clarke)胺甲基化反应，进行胺基叔胺化反应，制成带有叔胺官能团的硅胶中间体，此中间体上的叔胺与卤代烷反应生成杀菌活性官能团季铵盐，制成硅胶类水不溶性季铵盐杀菌剂；另一条路线是带有胺反应活性中心的硅胶与过量正氯代十六烷反应，得到的中间体再用碘甲烷季铵化，得到最终产品——水不溶性季铵盐杀菌剂。

The nano-silica partrcles are organic-modified by E-MA-GMA elastomer through direct solvent process,the organic-modify process mechanism was studied,and the dispersing of modified nano-silica particles in tetrachloroethane solvent and PBT were investigated.FIRT,TEM,SEM results indicated that the epoxy group of E-MA-GMA could react with the hydroxyl groups of silica surface,helped to reduce the interactions of nano-silica particles particles and improve the dispersion of nano-silica on PBT and the interfacia...

surface modification ；溶液法利用功能化弹性体E-MA-GMA对纳米二氧化硅进行表面有机化修饰改性，分析了表面改性过程机理，同时考察了改性后纳米二氧化硅在四氯乙烷溶剂和PBT基体中的分散情况；FIRT、TEM、SEM测试结果表明，E-MA-GMA的环氧基团与纳米SiO_2的—OH基团发生反应，降低纳米二氧化硅粒子间的相互作用力，改善了纳米二氧化硅在PBT基体中的分散，提高复合材料的相容性。

In order to install the electrothermic Board, silica gel used for blocking the release version of silica gel used for blocking the General selection of grass-roots level to 1-3 mm in thickness of the aluminum plate. Silica gel layer from the aluminum plate between the bond strength directly linked to silica gel used for blocking the version of the service life, if the silican layer from the aluminum plate between the bond strength is not high enough, the high temperature and high pressure easy to crack.

当然，在本质操纵洋上述几个参数的设定不是白云苍狗的，而给根据本质处事洋的需给举行拔取和设定，如铜、锌版不同，平均的烫印压辛、较矮的烫印温量和较缓的烫印速率会爆发更抱负的烫印成果，因为平均的烫印压辛使电化铝的黏结性更好，较矮的烫印温量使电化铝的光华量更矮，而较缓的烫印速率是为了适答较矮的烫印温量。

According to different technological requirements of battery component, B series automatic laminating machines can set different technological parameters, boast reasonable and compact structural design, as well as the design of stable continuous feeding and discharge mechanism; PLC automatic control, high-definition touch screen display, humanistic intelligence control system; urgent, emergent and accurate alarm system is able to deal with unexpected states of the equipment, to ensure that the equipment is safe and reliable and the components are not damaged; oil heating style and thickened hot plate make the temperature more equal and even; unique tightening structure of silica gel plate further smoothes the tightening of silica gel plate, prevents the frilling of silica gel plate, and makes the replacement of silica gel plate quicker and more convenient.

B系列全自动层压机可根据电池组件不同的工艺要求，设置不同的工艺参数，合理紧凑的结构设计，稳定的连续式出入料机构设计；PLC自动控制，高清晰触摸屏显示器，拥有人性化智能控制系统，设置紧急、应急及准确的报警系统以应对设备突发情况，保证设备安全可靠，使组件不受损伤；采用油加热方式，加厚热板，温度更均匀；独特的硅胶板张紧机构设计，使硅胶板的张紧更平整，杜绝硅胶板的起褶现象，硅胶板更换更方便快捷。

Fumed-silica surfaces were modified with resorcinol and hexamethylenetetramine complex, and NR/M-silica nanocomposites were prepared in mixing and curing process. Structure and properties of NR/M-silica nanocomposites were investigated by mechanical testing ,cross-linking density determination, transmission electron microscopy, differential scanning calorimetry, fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The results showed that M-silica have obvious reinforcement effect on NR vulcanizate.

用间苯二酚与六亚甲基四胺络合物对气相法白炭黑进行表面改性，通过混炼和硫化制备了天然橡胶/改性气相法白炭黑（NR/M-silica）纳米复合材料，并通过力学性能测试、交联密度测定、透射电镜、差示扫描量热法、红外光谱和X射线光电子能谱等手段研究了纳米复合材料的结构和性能。

The results showed that the aluminum plates had a much better effect than zinc plates in identifying crystalline free silica. The all open-faced samples had good uniformity in the filter no matter how many middles were used, but not so good for the closed-faced sampling. The calibration curve had a good correlation coefficient (r=0.995). Due to different industrial operating patterns, the distribution of crystalline free silica concentration varied by the industrial environment. The dust consisted of 10- 30% of crystalline free silica in all samples obtained from the foundry environments. The crystalline free silica was accounted for less than 10% in the respirable dusts.

结果显示，因为铝板对於结晶型游离二氧化矽具有较良好的补正系数，因此做为本研究的基底标准吸收校正的校正元素；SKC铝制旋风分离器搭配开匣式滤纸匣於一阶中环、二阶中环、三阶中环均有良好之均匀度，反之，搭配闭匣式滤纸匣其均匀度均不佳；分析检量线具有良好线性关系(r=0.995)，因作业型态不同，作业环境会有不同的浓度分布，综观作业环境中可呼吸性结晶型游离二氧化矽之含量均小於10%以下，总粉尘结晶型游离二氧化矽之含量约为10 – 30%之中。

Based on the construction of international financial centre, we have pushed forward the explorations in the integration of cultural industries with financial services.

2010年及整个"十二五"期间，上海文化产业面临更有利的发展时机、更坚实的发展基础和更完善的发展环境。

The koala is an animal with a large bag in its body.

树袋熊用它的身体的一个大的袋子是一只动物。