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On the 3 rd day after operation, compared with group C, the latency period and swimming distance of group O, group Hup extended further, while compared with group O,the latency period and swimming distance of group Hup shortened (P.05);Compared with group C, the extending degree of the latency period and swimming distance of group O decreased on the 7 th day after operation.

结果 术后1 d进行水迷宫测试,与C组比较,A组、O组潜伏期和游泳距离均延长(P.05);术后3 d,与C组比较,O组、Hup组潜伏期和游泳距离进一步延长,而Hup组与O组比较,潜伏期和游泳距离均缩短(P.05);术后7 d,O组与C组比较,潜伏期和游泳距离延长程度缩小。

In addition, the changes of molecular geometry, atomic natural charge and IR spectra of the reaction system during the crucial step of O to attack H showed that the rupture of C—H bond and the formation of O—H bond were concerted stepwise. Obvious changes of atomic natural charge happened to atoms C(1), H(11), O(28), O(29) and N(27). The bond lengths and bond angles related to these atoms were also varied greatly.

NO2中O进攻1-H决速反应过程中,分子几何、原子自然电荷及IR光谱变化表明, C—H键的断裂和N—H键的形成是一个协同过程;参与新键形成和旧键断裂原子C(1), H(11), O(28), O(29)和N(27)的原子自然电荷及与其相关的键长、键角有明显的变化。

The paper about the studies on alteration-deformation rock mineralogy and geochemistry indicates from unaltered phyllite to ultramylonite, SiO〓, CaO increase, Al〓O〓, TiO〓, TFe, MgO, K〓O decrease, P〓O〓 and MnO〓 almost remains constant, with the deformation degree increase.

蚀变变形岩石学及地球化学研究表明,由未蚀变的千枚岩经糜棱岩到超糜棱岩,随着变形程度的提高,SiO〓、Na〓O含量逐渐增加,Al〓O〓、TiO〓、TFe、MgO、K〓O逐渐减少,而P〓O〓、MnO〓基本保持不变,岩石的密度也逐渐降低。

Nd AC/O〓 process generated nonanal, alcohols and dimethyl phthalate. In TiO〓/UV/O〓 process, all raw organic compounds decreased or disappeared, and azulene, triacontane and 1, 3-cyclohexanediamine were generated.

C/O〓氧化出水中分子量为1000-3000的有机物所占比例均小于O〓和TiO〓/UV/O〓氧化出水;其它分子量范围的有机物去除,TiO〓/UV/O〓氧化过程要显著高于AC/O〓氧化过程。

Iron deposit is concerned with spilite keratophyre, rich in Fe, Na〓O, Alternative types are similar-skarnization, Iron deposit is of aeromagnetic anomaly. Indexes of Cu, Pb-Zn deposits are contemporaneous fault, ore-bearing bed, volcanic rock with high potassium, volcanic structure, a serious of alternative in ore-bearing bed and under ore-bearing bed, high content of Pb, Zn, Ag, Cu, Cd, Ba, As, CaO, Fe, Mn, low Na〓O, Al〓O〓 in mineralizing body.

铅锌矿形成大矿富矿指标:①NW、NE向同生断裂;②有利含矿层位D〓k〓〓;③酸性富钾火山岩;④火山机构发育;⑤有利于矿质聚集的火山洼地;⑥发育与流体活动有关的矿下层、矿层、蚀变岩筒蚀变;⑦块状、浸染状铅锌黄铁磁黄铁矿石;⑧原生晕中Pb、Zn、Ag、Cd、Ba、Cu、As元素组合,CaO、TFe、Mn富集,Na〓O、Al〓O〓亏损,其下部位富K〓O或Na〓O。

We have investigated on the chemical constituents of Nepeta partite collected from Gansu Zhuanglang, and twenty eight compounds were isolated from the methanol extraction of this species by chromatography techniques. Twenty five compounds were identified by means of chemical and spectra methods IR, FABMS, EI-MS,〓, DEPT, and 2D NMR), among which four compounds were new as isopimar-15-en-3β, 8β, 20-triol; phenylethanal-3-O-(2'-glycerin)-5-O-β-D-glucopyranoside; 3-O-linolenoylglyceryl-6'-O-(α-D-galactopyranosyl)-β-D-galactopyranoside; ethyl rosemarinate.

我们对采自甘肃庄浪的康藏荆芥进行了化学成分的研究,利用层析手段从该植物的甲醇浸膏中分离出二十八个化合物,经化学方法和波谱技术(红外,质谱,一维和二维核磁共振谱)鉴定了二十五个化合物的结构,其中四个为新的化合物,它们分别是:异海松-15-烯-3β,8β,20-三醇;苯乙醇-3-O-(2'-甘油基)-5-O-β-D-吡喃葡萄糖甙;3-O-亚麻酰基甘油-6'-0--β-D-吡喃半乳糖甙;迷迭香酸乙酯。

The magnetite with a mean diameter of 8nm was prepared by chemical coprecipitation methods. By the addition of nonionized oleic acid to the suspension of magnetite in solution during precipitation, the magnetite nanoparticles were coated with a double surfactant layer. A gel-like precipitated precursor is then formed because of the hydrophobic interaction among those coated units. By transferring of this precursor to an organic solvent, the surfactant double layer on Fe〓O〓 nanoparticles reduces to one; however, it still remains as a double layer by transferring to an alkaline aqueous solution. Both these cases give in stable colloids of superparamagnetic Fe〓O〓 nanoparticles.

从解决无机磁性Fe〓O〓颗粒与有机烯类单体的相容性入手,采用化学共沉淀法,制备了平均直径为8nm的超顺磁性Fe〓O〓颗粒,在制备过程中以非离子形式引入油酸,在Fe〓O〓颗粒表面形成一个具有双层结构的疏水外壳,并通过疏水相互作用凝聚成磁性Fe〓O〓凝胶,能够以单分子层结构形式溶解在非极性溶剂中,也能够以双分子层结构形式溶解在碱性水溶液中,形成稳定的超顺磁性Fe〓O〓溶胶。

In the hydroxylation of phenol with H〓O〓 in the presence of Ti-ZSM-5, water is best solvent. It produces catechol and hydroquinone simultaneously, and catechol/hydroquinone ratio is approximately 0.85. The results show H〓O〓 utilization ratio increase 14%, when nonoxidizable weak acid HAc is added into the reaction system. Under the conditions of Ti-ZSM-5 as catalyst, phenol/H〓O〓 ratio being 10, a little HAc, temperature 75℃, reaction time 6h, H〓O〓 utilization ratio reaches 74. 6mo1% in the reaction.

对Ti-ZSM-5催化苯酚羟基化的研究结果表明,水是最好的溶剂,羟基化有邻、对苯二酚两种产物,并且邻苯二酚/对苯二酚摩尔比可维持在~0.85左右;向反应体系中加入非氧化性弱酸性助剂HAc时,H〓O〓有效利用率较未加入助剂时可提高14mol%;当催化剂用量为8g/100g苯酚、苯酚/H〓O〓比为10、反应温度75℃、添加少量HAc的条件下,反应6h后,H〓O〓有效利用率可达74.6mol%。

Their half lives were 27.29 and 69.16 days respectively. Monocrotophos degraded into both methanol extractable and unextractable residues in the submerged soil.The analysis of 14C-methanol extractable. residue by TLC and ARG indicated that degraded products of monocrotophos were triether phosphate,;N-de-methyl Azodrin, O, O-dimethyl-vinyl-phosphatc,O-demethyl Azodrin,and O, C-demethyl Azodrin.The principal degraded extratable product of monocrotophos was triether phosphate, which incresed from 5% of the parent solution of monocrotophos to a range of 28-83%, furthermore and its degradation process was much faster in the unterilized soil than in the sterilized soil.

久效磷在淹水土壤中降解为甲醇可抽提态和不可抽提态残留物,对甲醇可抽提态残留物经TLC和红外光谱分析表明,其降解物为磷酸三酯、N-去甲基久效磷、O,O-二甲基乙烯基磷酸酯,0-去甲基久效磷,以及O,C-去甲基久效磷,但主要为磷酸三酯,其含量由母液中的5%增加到28—83%,这种降解过程,在未灭菌土壤中比在灭菌土壤中快。

It is found that the occupancies of three crystallographic distinct O sites O(1), O(2) and O(3) are 100%, 91.7% and 25%, respectively, consistent with experiments. Each Mo cation is surrounded by four or five O-ions.

研究首次发现结构中Mo有MoO4和MoO5 2种形式的多面体,并且O(1)、O(2)和0(3)3 种氧位置的占有率分别为100%、91.7%和25%,与实验相符。

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