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A group of pyrylium salts with different substituents has been synthesized in this work. Their fluorescence life time, quantum yield and quenching constant by BVE have also been measured. It was found that a strong interaction was observed between BVE and pyrylium salt which contains an electron-withdrawing group, and contrary, the introduction of electron-repulsive groups to the pyrylium salt will decrease this effect. It indicated that these reactions possess the characteristic of electron transfer.

本工作合成了一组带不同取代基的氧鎓盐化合物,并对它们的荧光寿命、荧光量子产率以及用丁基乙烯基醚进行猝灭的荧光猝灭常数进行了测定,发现带拉电子基的氧鎓盐化合物和BVE间存在着较强的相互作用,相反,推电子基的引入则减弱了这种影响,表明反应具有电子转移性质。

Halogenated aromatic compounds with great q〓(the most negative net atomic charges on an atom of the molecule), ENC (electron-nuclear attraction energy of the one-center term for the carbon atoms of the weakest carbon-halogen bond), qc (thenet atomic charges on the carbon atom of the weakest carbon-halogen bond) and E〓 tend to be reductively dehalogenated slow, while halogenated aromatic compounds with high values of △E (the difference of front-line orbital energy), EEC (electron-electron repulsion energy of the one-center term for the carbon atoms of the weakest carbon-halogen bond), Mw, q〓 and α tend to be reductively dehalogenated fast.

卤代芳烃化合物的整个分子的最负的原子净电荷,键序最小的碳卤键中碳原子的单中心项电子-核吸引能,该碳-卤键上碳原子的净电荷和E〓与该卤代芳烃化合物还原脱卤的速率常数负相关;而前线轨道间隙能,键序最小的碳卤键中碳原子的单中心项电子-电子推斥能,Mw,q〓和α与该卤代芳烃化合物还原脱卤的速率常数正相关。

The process of DC discharge in O2/N2 mixtures with the different N2 concentration has been simulated. The dependences of number of collisions with the E/N and the energy of electron are given. It is analyzed stressfully that the process of electron-molecule collision with the E/N and the energy of electron in air at atmospheric pressure.

对于O_2/N_2混合气体,模拟了不同配比条件下直流放电过程,得出了发生碰撞的粒子数随E/N、电子能量的变化;着重分析了空气中激发、电离、分解及分解电离碰撞的粒子数随E/N的变化,给出了电子漂移速度和平均电子能量随E/N的变化。

Materials and methods: The method of the electron grid therapy is to place a cerrobend grid on the end of an electron cone. Film dosimetry was used to measure the relative surface optical density and depth profile of grided electron beam with energies of 6 to 14 MeV.

材料与方法:使用底片测量术的方法,观察当15×15cm^2铅合金网眼板上的网眼孔径大小(d=0.45, 1.0, 1.5 cm)、网眼之间的间隔宽度(s=0.4, 0.2cm)不同时,以不同能量的电子射束(6、8、10、12、14 MeV)照射剂量50 M.U。,对底片的相对表面平均光密度及深度等光密度曲线分布情形所引起的变化。

In this paper several technologies, such as Fourier transform infrared spectroscopy, elemental analyzer, wide angle X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy and high resolution transmission electron microscopy were used to systemically investigate the evolution of crystal structure, chemical structure, microstructure and properties of wet-spinning and dry-jet wet-spinning PAN precursor fibers during proxidation and carbonization process, analysis the structural change of carbon fibers during graphitization, and discuss the correlation between the structure and properties.

本文采用傅里叶变换红外光谱、元素分析仪、X射线衍射仪、场发射扫描电镜、透射电镜以及高分辨透射电镜等测试技术,分别系统研究了湿纺原丝和干喷湿纺原丝在预氧化和碳化过程中纤维晶体结构、化学结构、微观结构和力学性能的演变规律,分析了碳纤维在石墨化过程中的结构转变,并对碳纤维结构与性能的相关性问题作了探讨。

By analyzing the electron emission waveforms, the natural parameters of the ferroelectric electron emission and the theory of the electron emission have been generalized.

其中,对BT、BNBT两种环保无铅铁电材料电子发射性能的详细研究,并公开报道了其最大发射电流密度分别为30A/cm~2、20A/cm~2,这在国际上尚属首次。

The problem in using titanium dioxide as a photocatalyst is recombination of electron and hole. One strategy for inhibiting theirs recombination is to add other electron accepters to the reaction. It can reduce the electron/hole recombination and then produce more ·OH on the surface of titanium dioxide, from which increased the degradation rate of the pesticide.

二氧化钛作为光催化剂进行光催化降解的问题在于电子—空穴对的重新复合,抑制其重新复合的一种办法是加入其他的电子接受体,减少电子—空穴对的复合,从而使光催化剂TiO2表面产生更多的·OH自由基,加强农药的光催化降解。

However after chemical fixation, basement membranes showed 2 main layers: the electron-lucent "lamina lucida" and the electron-dense "lamina densa"; T tubules were flat; there existed only some electron dense particles in terminal cisternae, the feet process projected from membranes of terminal cisternae toward T tubules.

化学固定后,缝匠肌基膜由两层组成:一层电子密度低,另一层电子密度高;横小管为扁平状或哑铃状;终池内仅有一些散在的电子密度高的颗粒,终池膜上有几个脚状突起伸向横小管。

Then the secondary electron emission yield of MgO film were measurement on the dynode structures. We successfully demonstrated that primary electron energy effect the curve of SEE yield according to previous study. We found that the magnitude of the secondary electron em....

驱动的原理是以集热板吸收太阳热能,透过热管快速传递热量的特性将收集到的热能快速而高效的传递到远端的散热鳍片,鳍片温度上升高后,以自然对流的方式驱动鳍片周遭的空气上升,进而使建筑物内的空气来递补,。。。。

In classicaIn classical hydrogen atom model an electron is circling around the nucleus like Earth revolving around the sun, except that the force between the l hydrogen atom model an electron is circling around the nucleus like Earth revolving around the sun, except that the force between the two electron

在经典的氢原子模型里,电子绕着原子核作圆周运动,在经典的氢原子模型里,电子绕著原子核作圆周运动,就象地球绕太阳运动一样就就像像地球绕太阳运动一样地球绕太阳运动一样,,只只是前者的是前者的而其引力来自电场。

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