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In order to solve the backward electron transfer problem, 9 kinds of rhenium bipyridyl photosensitive dyes with different electron donating groups on the p or m-position of the pyridine rings, 2 kinds of rhenium bipyridyl and 2 kinds of ruthenium tris-bipyridyl photosensitive dyes with two tyrosine ethyl ester groups on the bipyridyl rings were designed and synthesized.

本文针对该类太阳能电池中存在的电子回传问题,设计合成了在吡啶配体的间位和对位带有不同供电基团的9种铼联吡啶光敏染料,在联吡啶配体上带有两个酪氨酸基团的2种铼联吡啶和2种钌三联吡啶光敏染料。

Parameters based on chemical shift indicate that methyl is a substituent with electron-withdrawing inductive effect and poor electron-donating conjugative effect. Perhaps its conjugative effect is on critical point. Methyl is electron-withdrawing for benzene relative to H. Otherwise, methyl has strong p-position and weak o-position orientation effect.

化学位移值表示的诱导效应参数表明甲基具有吸电子诱导效应,经校正后的化学位移值表示的共轭效应参数表明甲基具有微弱的给电子共轭效应,甚至其共轭效应有可能正处于给电子和吸电子的临界状态,总之相对于氢原子,甲基具有吸电子效应。

As compared to isop, the coexistence of electron-donating -OH,-C(CH_3_3 or electron-withdrawing groups (-NO_2) groups in the dicarboxylate derivatives has a significant effect on the molecular self-assembly.

同间苯二甲酸相比较,含有取代基的5-羟基间苯二甲酸、5-硝基间苯二甲酸和5-叔丁基间苯二甲酸在一定程度上影响着配位聚合物的自组装。

Only if the system is built and works well, may women give out eggs dignifiedly, whatever by "donating" or the so-called "selling".

只要这样的体系建立起来并运作完好,妇女们都能堂堂正正地献出卵子,无论是&捐&还是&卖&。

A-Methylnaphthalene contains a methyl group, which is a strong donor group, so the reaction of a-methylnaphthalene with C14 AOS acid had a higher conversion of aromatic than did the reaction of benzene with C14 AOS acid. After alkylaryl sulfonic acid is formed, it will continue to react with another AOS acid to rapidly produce dialkylaryl disulfonic acids owing to the electron- donating effect of the long alkyl chain in the alkylaryl sulfonic acid molecule.

a-Methylnaphthalene包含一个甲基集团,这是一个强大的捐赠团体,所以 a-methylnaphthalene反应出了与C14酸更高的转换的反应比苯与C14活性氧酸。alkylaryl磺酸为后形成,它将继续与另一出酸 dialkylaryl disulfonic迅速产生的电子-酸捐赠的长期效果在alkylaryl烃链磺酸分子。

To produce forensically clean target media or to sanitize media before re-use in a different environment of before donating.

X-Ways Security 提供的数据粉碎技术本身已经包含在WinHex 软件中,为了达到专业、简单、易用目的而推出,支持语言有:。

Electron donating substituent CH〓, OCH〓 and 4, 5-benzo make λ〓 red shift, electron with -drawing substituent F, Cl and CF〓 make λ〓 hypsochromic shift; b The W〓 is bigger than relative symmetrical carbocyanines, and the ratio of 0-1' and 0-0' transition intensity increase with the increase of σ〓; c The absorption and the fluorescence spectra are mirror image, and the λ〓 have a good linear relationship; d The Stokes shift △λ〓 and the Hammett σ〓 constant have a good linear relationship.

研究了染料的光物理性质,①苯环上取代基影响染料的λ〓和摩尔消光系数,相对于H,给电子取代基CH〓、OCH〓、4,5-benzo使λ〓红移,摩尔消光系数减小,吸电子取代基F、Cl、CF〓使λ〓蓝移,摩尔消光系数减小;②化合物吸收峰的半峰宽较相应的对称染料的大,且振动肩部与最大吸收峰的强度比随σ〓增大而增大;③吸收光谱与荧光光谱呈镜像关系,且λ〓与λ〓呈良好的线性关系;④化合物的Stokes位移△λ〓与取代基的Hammett σ〓常数呈线性关系。

It was also found that the electron-donating groups in the 5-position of indoline moiety could stabilize the colored forms and then low the thermal decay date.

吲哚啉环上5位的取代基对螺噁嗪热消色过程也有影响。5位的给电子基团能稳定开环体,热消色速率降低,寿命延长。

ATRP initiation systems consist of organic chloride initiators (RCl, RBr or aryl sulfonyl chloride, etc.), transition-metal catalysts in lower oxidation state Cu(I, Fe, Ru, Ni, etc. and organic electronic-donating ligands (2,2'-bipyridine―bipy or bpy, PPh3, multidentate ligand compound 1,1,4,7,7-pentamethyldiethylenetriamine, etc.).

普通ATRP引发体系包括引发剂主要为氯或溴化物,芳基磺酰氯;低价过渡金属卤化物如Cu, Fe,Ru,Ni等;有机配体如2,2'-联吡啶,PPh3,脂肪族多元胺等。

If it's true, we will stop donating via Canadian Rad Cross.

如果这个政策确有其事,我们将停止通过加拿大红十字会捐款。

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There are different types of personal loans available.

有许多不同类型的个人贷款优惠。

The above mentioned teaching model of spiral rising can be used to avoid rigidness in teaching.

上述螺旋式上升的教学模式,可以避免教学形成模式後的僵化现象。

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