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To understand the thermodynamic process of the transesterification, the thermodynamic properties (△r H o,△r S o,△r G o, K p ) of the reaction for production of DPC and anisole from 373 K to 473 K was calculated by using Material Studio and ChemCAD software as well as Benson and Joback group contribution methods.

DMC与苯酚酯交换合成DPC反应热力学方面的研究报道很少,散见于一些工艺设计专利中,且都未对数据来源做详细介绍,很难对数据的可靠性进行验证。

1000 Ljubljana, Slovenia bQueensland University of Technology, School of Advertising, Marketing and Public Relations, G.P.O.

5,1000 Ljubljana,斯洛文尼亚技术的 bQueensland 大学,广告,行销和公共关系的学校,G.P.O。

The crystal belongs to triclinic, space group P-1 with α=0.775 1(2) nm, b=0.837 7(2) nm, c=1.003 7(2) nm,α=75.57(3),β=83.05(3),γ=86.08(3), D=1.296 g/cm^3, Z=2, F(000)=256,μ=0.095 mm^(-1), and the final deviation factor R=0.0545 and wR=0.146 0. X-ray analysis reveals that molecules are linked by intermolecular O-H…O hydrogen bonds formed between the adjacent molecules.

具体测定结果如下:该晶体属于三料晶系,P-1空间群,α=0.7751 (2) nm, b=0.8377 (2) nm, c=1.0037 (2) nm,α=75.57 (3),β=83.05 (3),γ=86.08 (3), D=1.296 g/立方公分,Z=2, F(000)=256,μ=0.095 mm^(-1),最终偏差因子分别为R=0.0545,wR=0.1460.X-射线衍射分析表明,分子之间通过相邻分子间形成的O-H…O氢键相连。

Rhodamine B, Malachite green, Auramine O, Bismark Brown,Methyl Violet 5BN, Basic Magenta, Acid Orange II, Chrysophenine GX, Direct Fast Black G, Indigo, Sulphur Black, Solvent Red 24, Solvent Red 49, Solvent Brown 41, Solvent Orange 3,Pigment Yellow 154,155, Pigment Red 188,208, Meta-Diethyiaminophenol, M-Amino acetanilide , P-Amino acetanilide, etc.

主要产品:碱性玫瑰精,碱性品绿,碱性嫩黄O,碱性品红,碱性紫5BN,碱性红6DDN,酸性橙II,靛蓝,硫化黑,直接冻黄,直接黑G,溶剂红24,溶剂红49,溶剂棕41,溶剂橙3,溶剂橙62,颜料黄154,155,颜料红188,208,间羟基-N,N-二乙基苯胺,间氨基乙酰苯胺,对氨基乙酰苯胺。

Results 30~80μg/ml 23-hydroxyl betulinic acid in vitro and 300mg/kg~600mg/kg P.O.in vitro markedly inhibited the growth of B16 cells at a dose-dependent manner with a great number of apoptotic cells seen.

结果 23-羟基桦木酸体外30~80μg/ml处理,体内300mg/kg~600mg/kg灌胃时,对B16细胞有显著的生长抑制作用,有一定的剂量依赖关系并出现大量的凋亡细胞,同时体内肿瘤细胞被阻滞在G0~G1期,DNA合成受阻,肿瘤体积缩小。

In o rder to explore the relationship bet ween HSP70and P-g p,the human hepatocarc inoma line HepG2cells was induced by heat shock in vitro,and the inhibiting effect of quercetin on them was obs erved at the same time to seek the method incre asing the effectiveness of hyperthermal therapy on hepatocarcinoma.

本研究拟通过热休克诱导人肝癌HepG2细胞表达HSP70和P-gp,并观察槲皮素(quercetin,Qu)对二者表达的抑制效应。

Based on relative literatures,this part has included five resesearch aspects as below.1 Fifteen compounds were isolated and purified by extraction,column chromatography,and their structures were determined on the basis of spectral analysis: acteoside(Ⅰ-1),isoacteoside(Ⅰ-2),crenatoside(Ⅰ-3),cistanoside F(Ⅰ-4),sinapoyl-4-O-β-D-glucoside(Ⅰ-5),adenosine(Ⅰ-6),β-siterol(Ⅰ-7),oleanic acid(Ⅰ-8), succinic acid(Ⅰ-9),caffeic acid(Ⅰ-10),protocatechuic aldehyde(Ⅰ-11),p-hydro xybenzyl alcohol(Ⅰ-12),β-daucosterol(Ⅰ-13),D-galacitol(Ⅰ-14),D-mannitol(Ⅰ-15).Ⅰ-4~15 were obtained from this plant for the first time,andⅠ-6,7,9,and 13 were isolated from Orobanche genus for the first time.2 The scavenging test of DPPH showed that most compounds have comparative antioxidant activity as L-ascorbic acid and part of them show better activity such as the O.coerulescens extract and phenylethanoid glycosides.Acteoside showed potent free radical scavenging effects with a median inhibition concentration of 25.6μg/ml.3 The anti-HBV activities of acteoside,isoacteoside and crenatoside were measured,and all of them showed suppressive activity on the expression of HBsAg and HBeAg in the HepG2.2.15 cell line.

本论文在文献调研基础上对紫花列当化学成分及生物活性进行了研究,并从免疫抗病毒角度探讨紫花列当中特征性成分类叶升麻苷的肝保护作用及其机制。1采用大孔树脂、硅胶和Sephadex LH-20等色谱技术对紫花列当进行系统的植物化学研究,从中分离得到19个化合物,利用UV和NMR等波谱手段及理化性质鉴定了其中的15个化合物,分别为类叶升麻苷(Ⅰ-1)、异类叶升麻苷(Ⅰ-2)、crenatoside(Ⅰ-3)、cistanoside F(Ⅰ-4)、sinapoyl-4-O-β-D-glucoside(Ⅰ-5)、腺苷(Ⅰ-6)、β-谷甾醇(Ⅰ-7)、齐墩果酸(Ⅰ-8)、琥珀酸(Ⅰ-9)、咖啡酸(Ⅰ-10)、原儿茶醛(Ⅰ-11)、对羟甲基苯甲酸(Ⅰ-12)、β-胡萝卜苷(Ⅰ-13)、D-半乳糖醇(Ⅰ-14)和甘露醇(Ⅰ-15除化合物Ⅰ-1、Ⅰ-2和Ⅰ-3外,其余化合物均为首次从该植物中分离得到。2)通过大孔树脂富集该药材有效部位苯乙醇总苷,并采用HPLC测得其所含特征性成分类叶升麻苷的含量可达80%以上。3DPPH自由基清除试验显示紫花列当提取物及其所含的苯乙醇苷类化合物均具有较好的抗氧化能力,其清除DPPH自由基能力接近于抗坏血酸。4采用卡介苗整体致敏、脂多糖离体攻击构建大鼠原代肝细胞免疫性损伤模型,在体外观察类叶升麻苷的保肝作用。

They have husbanded their farms very well.; q! p+ a/ b U5 o# w9 n1 C Students in Hong Kong can view a collection of more than 1oo rare species of goldfish in the Ocean park.

9 ~! Z9 ~8 |( G$ A1 h; O; m 读者们不难从上面的例子看出,用名词作动词可以带来一种新鲜感,能唤起人们的注意并给人们留下一个逼真生动的画面。7 L6 p* L, e)}% Q%- P1 j: y% a3 o2 H

Results: fops had inhibitory effect on o 2 production in vitro, having a 50% of inhibitory concentration (ic50) of 3.866×10-6 g/ml, and a weak inhibitory effect on h2o2 production with a ic50 of l.668×10-3 g/ml but showed a potent inhibitory effect on the various free radicals produced by "respiratory burst" of human leukocyte. fops (20, 40, 80 mg/kg) increased the sod activity in myocardial tissue, liver and kidney of mice and decreased the mda content of myocardial tissue, liver, kidney and spleen of mice.

结果:在体外阿里红多糖可有效的清除o 2,其ic50为3.866×10-6;对h2o2的清除作用很弱,但能抑制人血嗜中性粒细胞&呼吸爆发&产生的多种自由基,ic50为1.668×10-3;阿里多红糖(20、40、80 mg/kg)可明显增加小鼠心脏和肝脏中sod的活性,其中剂量为40、80 mg/kg的阿里红多糖可明显增加肝脏中sod的活性,同时各给药组均可明显减少小鼠心脏、肝脏、肾脏和脾中mda的含量,与对照组相比较差异有统计学意义(p.05)。

But in December, The Wall Street Journal's editorial page denounced any such means-testing, because "middle- and upper-middle-class (i.e., G.O.P.) voters would get less than they were promised in return for a lifetime of payroll taxes."

但华尔街日报在12月的社论版谴责这项测试,「中产与中上阶层选民缴一辈子的工资税,最终所能拿到的钱却比先前保证的还少。

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Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克,果实色泽鲜艳,汁多味浓,甜酸适口,离核仁甜,清末时就驰名陕、甘两省,清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异:红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感,ED90值分别为47.65、71.67和29.17g/hm2;春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感,ED90值分别为96.91、114.20g/hm2;而番茄不敏感。

However, I have an idea.

不过,我有个主意。