超精细的

With the increase of temperature, the relative intensity of each Doppler-free hyperfine spectroscopy has a trend of increase at the beginning, then decrease as the result of the influence of the effective atomic number density, Doppler-broadening and the susceptibility.

由于有效原子数密度、多普勒加宽、电极化率受温度变化的影响，每一条超精细谱线的相对强度随着温度的升高都会出现先增大后减小的变化趋势，相对强度最高时的温度称为最佳温度。

We think that the influence of substitutional atoms on theproperties of materials can be divided into volume effect and chemical bonding effect.

发现它们的量级是相同的，但Co和Ni的这两种效应对超精细场和同质异能移影响的正负是不同的。

The result show that the N elements curbed the transition from anatase phase to rutile phase , Doped-N was in the structure of the TiO2 as the form of Ti-O-N and formed a new bond energy level;N-doped changed the paramagnetic of the characteristics. The paramagnetic resonance spectrum of TiO2 showed anisotropic and showed hyperfine splitting, The Lande factor of Ti3 + combined with the N is 1.956. UV-Vis absorption spectra showed that the photocatalytic ability of photocatalyst TiO2-xNx to expand to the visible region, the sample (3.84wt %) has the highest photo catalytic activity, the adsorption edge extend to 520nm and degradation is 55.54% under the visible light for 1.5h.

研究结果显示，N元素抑制了锐钛矿相向金红石相的转变，阻止了晶粒的长大，掺杂的N元素以O-Ti-N的形式存在于光催化剂结构中，形成了新的能级结构；N掺杂改变了催化剂的顺磁特征，使TiO2的顺磁共振谱线呈现各向异性，发生了超精细分裂，其中g2=1.956，是与N结合的Ti3+的朗德因子；紫外可见光吸收谱表明，催化剂TiO2-xNx的光响应能力拓展到可见光区，光吸收带发生红移；光催化测试结果显示，掺杂量为3.84的TiO2-xNx在可见光区的响应能力最高，吸收波长延伸至520nm，其光催化活性最大，1.5h降解率达到55.54%。

In the first part of the thesis, we built up a highly sensitive and highresolution laser photoacoustic spectrometer, which can be used in the measurement of themolecular spectra of highly excited vibrational states. The high resolution near infraredspectrum of CrS and the hyperfine structure of 〓 molecule was also studied in thispart, spectroscopic constants were obtained by fitting the experimental data.

在本论文的第一部分，我们建立了一套高灵敏度和高分辨率的用于测量分子高振动态振转光谱的光声光谱仪，还使用激光诱导荧光方法研究了CrS分子近红外波段的高分辨光谱和〓分子的超精细结构，拟合得到了它们的光谱常数。

The diode laser at 657 nm has the characteristics of lower cost and higher power than that at 633 nm. Therefore, we use the 657 nm ECDL to investigate the saturation spectrum of the hyperfine structure components of P(84) 5-5 transition of 127I2 at 657.483 nm for frequency stabilization of our ECDL laser.

nm 波段的二极体雷射比起633 nm 波段的二极体雷射拥有较低的费用和较高的功率，因此，我们使用657 nm 波段的外腔二极体雷射来研究657.483 nm 波段之碘分子跃迁P(84 5-5 transition of 127I2，并将我们的外腔二极体雷射稳频在此跃迁的超精细结构成分上。

With decreasing concentration of PAn, the ESRspectrum of PAn/NMP solution gradually exhibits a hyperfine structure composed of threepeaks indicating the interaction between the spin electron and 〓.

PAn具有顺磁性，固态的ESR谱是一线宽较宽的单峰，而其浓溶液的ESR是一线宽较窄的单峰，随浓度的降低，逐渐出现三重峰的超精细分裂结构。

On the basis of the perturbation formulae of the g-factors (fourth-order) and the hyperfine structure constants (third-order) for a 3d9 ion in tetragonal symmetry, the spin Hamiltonian parameters for the Cu2+-doped LaSrAlO4 crystal are theoretically investigated.

根据晶体场理论，利用3d9离子在四角对称中自旋哈密顿参量g因子的四阶微扰公式以及超精细结构常数A因子的三阶微扰公式，对掺Cu2+的LaSrAlO4晶体的自旋哈密顿参量作出了理论分析。

Since the contribution of the spin-orbital coupling interaction of the ligand to optical and electron paramagnetic resonance spectra can not be neglected, the optical and EPR spectra g factors g‖、g⊥ and hyperfine structure constant A‖、A⊥ of LiHSO4:VO2+ crystal are calculated from the high-order perturbation formulas on the basis of double-spin-orbital coupling model and crystal-field theory for 3d1 ion in tetragonal symmetry.

考虑到配体离子的自旋－轨道耦合作用对光谱和电子顺磁共振谱的贡献不可忽略，采用3d1离子在四角对称下基于双自旋－轨道耦合模型的高阶微扰公式和晶场理论公式，理论计算了LiHSO4：VO2+晶体的光谱和电子顺磁共振参量g因子g‖、g⊥和超精细结构常数A‖、A⊥。

In addition,most of theprevious studies are focused on a very narrowly-separated doublets(e.g.,hyperfinestructure,Stark or Zeeman splittings)in a closed system.In fact,the atomic ormolecular system,especially the excited one,is an open system,but there are only afew studies for it.

另外，以往研究的多能级系统中相邻两能级的间距都很小(通常为原子的超精细结构、斯塔克分裂或塞曼分裂)，且大多数理论研究基本上都集中于封闭系统；然而，实际原子或分子特别是激发态的原子或分子体系通常为一开放系统，对于这方面的研究也很少。

In the present work, usingFCPC method, we have performed systematically the theoretical investigationsfor the electronic charge density, high-order Zeeman effect and hyperfinestructure.

本文通过研究这些物理量的收敛性质发现，波函数第二项对这些物理量的合理描述起着重要的作用，特别是对高阶Zeeman效应和超精细结构参数的影响。

If you are unfortunate enough to the lovelorn, please tell me, I will help you out, really, please contact me!

如果你不幸失恋了，请告诉我，我会帮助你摆脱困境，真的，请联系我啦！

China's plan to cut energy intensity by 20 percent and pollutant discharges by 10 percent between 2006 and 2010 is a case in point.

中国计划在2006年到2010间降低20%的能源强度和减少10%的主要污染物排放，就是一个这样的例子。