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The infection of the reaction rate of the virous monomers was reviewed respectively by the different THF dosage, TMEDA dosage, t-BuOK dosage, t-AmOK dosage and different temperature. The monomers apparent reaction rate constant was obtained.And the polymer composition at different conversion was reviewed, too.The effect of modifier and temperature on heat effect was also studied. In addition, the sequence structure and microstructure of the terpolymer was reviewed at different modifier dosage, and the structure was characterized by the ~1H—NMR.

分别考察了不同THF、TMEDA、t-BuOK、t-AmOK加入量以及聚合温度对各单体及总的反应速率的影响规律,得到了各单体及总的表观反应速率常数,求得了不同转化率下各单体在共聚物中的分布情况,同时考察了调节剂加入量对聚合温升热效应的影响规律;研究了在三种聚合体系下,通过~1H—NMR对共聚物的结构进行了表征,分别考察了不同调节剂加入量对共聚物的序列结构及微观结构的影响规律。

Probably the octamer changes position without ever completely losing contact with the DNA

聚合酶前进时,它会在前方产生阳性的超螺旋结构,这将会取代与DNA和聚合酶保持联系,并在RNA聚合酶后嵌入八聚体。

n thes paper, the oligomers with different molecular weight of monohydroxylpolyethersulfones were synthesized in solution and the optimum condition ofpolymerization was obtained; With phase transfer catalyst method,the oligomerswas obtained and transformed to monovinylpolyethersulfones macromer. Its structure was characterized with IR and 1H-NMR.

本文采用溶液法以单酚(4-氯-4'-羟基二苯砜)为原料合成了不同聚合度的单酚低聚体,得到了控制聚合度的最佳聚合条件;用相转移催化剂法成功地将单酚转化为单烯大分子单体,并用IR、1H—NMR对其结构进行了表征;测定了双键官能度均在1.90以上。

Factors exerting influence are discussed, such as amounts of initiator and crosslinker, pH value of water phase, polymerizing temperature, as well as inductive time.

研究引发剂用量、交联剂用量、水相pH值、聚合温度和诱导时间等因素的影响,得出的最佳聚合条件为:引发剂用量为共聚单体质量的0.18%,交联剂用量为共聚单体质量的0.27%,pH值6.5,聚合温度65~75℃,诱导期40~60min。

In order to study the mechanism of macromolecule deterring propellant on changing burning law,the polymerizing conditions,mechanical and thermal decomposition performance of coating-layer is studied.

通过改变聚合方式、温度、时间、引发剂、聚合界面的方法,探讨了涂覆层的聚合工艺;通过材料试验机试验和热分解试验,研究了聚二甲基丙烯酸乙二醇酯涂覆层在不同温度下的力学性能及其热分解规律。

As far as the Fe catalytic system, the higher the Al/Fe molar ratios, the stronger Lewis acidities and the higher reactivates of carbon-aluminum bond in the cocatalysts resulted in the higher polymerization activities.

以铁配合物为主催化剂时,各种助催化剂催化乙烯聚合活性随Al/Fe比的增加而升高;助催化剂的Lewis酸性越强,其分子内碳—铝键的反应活性越高,聚合体系的聚合活性则越高。

In the past there has been a lot of emphasis on chromatin modifications and physical access to genes, but Scp1 regulates the activity of the enzyme that transcribes genes directly, he adds.

激酶可以为RNA聚合酶 II加上一个小的磷酸盐基团,使RNA聚合酶 II继续转录基因,而Scp1则会移除小的磷酸盐基团,使RNA聚合酶 II停工。

Polyaspartic acid was synthesized with maleic anhydride and salvolatile as raw material by the method of thin layer polymerization.

以马来酸酐和碳酸铵为原料,通过薄层聚合制备了聚天冬氨酸,研究了反应物配比、聚合时间及反应温度等因素对聚合物产率、相对分子质量的影响;考察了聚合物用量及相对分子质量对阻垢性能的影响。

In this paper,the aqueous solution polymerization of acrylamide by using copper chloride/ethylene diamide/α chloroethyl benzene as an initiator was studied. Molecular weigh has a correlation of a straight line with the time.

原子转移自由基聚合是一种自由基&活性&聚合,自发现[1 ] 以来已应用该技术合成了一系列结构不同、性能各异的聚合物材料[2~ 3] ,并发展了多种ATRP引发体系,是活性聚合发展史上最简便的一种技术。

Herein the latest developments of olefin aqueous polymerization which are mainly promoted by late- transition metal catalysts are reviewed including ethylene,α-olefins, cyclo-olefins and dienes polymerization, along with ROMP of cyclo-olefins and CO/olefins copolymerization.

本文综述了后过渡金属催化剂水相催化烯烃配位聚合的一些新进展,内容包括烯、α-烯烃、环烯烃、二烯烃的聚合反应和环烯烃的开环聚合反应以及CO/烯烃的共聚反应等方面。

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