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Secondly, according to the construction and characteristic of the N-isopropylacrylamide and the temperature-sensitivity of PNIPA hydrogel, Pdualistic hydrogel was synthesized by microwave low temperature plasma. The effects of the factors on the swelling characteristic of P dualistic hydrogel, such as treatment time and power of plasma, concentrations of crosslinking agent and total monomers, proportion of AMPS, polymerizing temperature etc, was discussed in detail. The three dimensions structure , thermostability , reversional volume , swelling/deswelling kinetics, temperature-sensitivity and pH-sensitivity of the hydrogel were also investigated. The optimal synthesizing technics of P dualistic hydrogel initiated by microwave low temperature plasma was confirmed.

在此基础上,结合NIPA的结构特征和PNIPA的温敏性,用微波低温等离子体引发聚合了P二元智能凝胶,详细探讨了微波低温等离子体处理功率、处理时间、总单体浓度、AMPS单体浓度、交联剂浓度及聚合反应溫度等因素对P二元凝胶溶胀性能的影响;并对其三维交联结构、热稳定性、失水-吸水动力学、温度敏感性、pH敏感性、体积复原性等进行了研究;确定了适合微波低温等离子体引发聚合P二元智能凝胶的最佳工艺。

Much coagulation coul d be found to be adhered to the wall of reaction vessel and mixer when this cros slinker was used for conventional emulsion polymerization whereas coagulation co uld be greatly reduced and no obvious bulking of particle size of the product wo uld occur when this crosslinker was used for microemulsion polymerization and do sage and proportion of emulsifier wer.

将此交联剂用于乳液聚合中,若采用常规乳液聚合方法,反应器壁及搅拌上会粘附有大量凝胶;采用微乳聚合的方法并调整乳化剂用量及比例,可大大减少凝胶量,同时使产品粒径无明显粗大化现象。

Moreover, nano-scale SiO〓 particle is as seed, styrene-acrylate-acrylic acid emulsion polymerization and soapless acrylic emulsion are studied from varying the level of SiO〓 particle and reaction temperature, particle size of these emulsions are determined and SiO〓 content of participating polymerization is also determined. Kinetic study is carried out in the presence of nano-scale SiO〓 particle.

此外用原位聚合法制备了纳米SiO〓/苯乙烯-丙烯酸酯复合乳液和无皂丙烯酸乳液,研究了不同SiO〓含量、反应温度等对聚合反应稳定性的影响,测定了所得乳胶粒的粒径,分析了在乳液中SiO〓含量,并进行了在SiO〓存在下乳液聚合反应的动力学研究。

NodD binds to and bends target promoters through anchoring two tandem and individual specific DNA sites. NodD functions as a tetramer, which has a V-shaped main body. Tetrameric NodD is to change its own conformation rather than its oligomeric forms in response to small signal molecules. The specific interaction between each NodD DNA-binding domain and each specific DNA site does not alter itself in spite of naringenin induction, and the induced conformational change is transferred from protein to DNA. Only the DNA conformation incited by induced NodD is competent for RNA polymerase to form the transcriptional open complex. It cannot be excluded that NodD may have protein-to-protein contacts with RNA polymerase, and that the NodD conformational change may also directly contribute to the transcriptional open complex formation. However, the NodD conformational change itself cannot serve as the determinant of the transcriptional molecular switch.

通过研究,我们提出了初步的NodD操纵子激活模型:第一,四聚体是NodD蛋白的功能单位,它通过铆钉两个串联的相对独立的DNA靶位点结合被诱导的启动子;第二,小分子配基的结合是改变NodD四聚体的构象而不是引发不同形式的寡聚体,在我们的模型中,NodD四聚体缩小其V形主体的弯折角,进而缩短其DNA结合功能域的间距;第三,小分子信号的诱导并没有改变NodD的DNA结合域和其DNA靶位点的相互作用,NodD的构象改变由蛋白质经其双铆钉位点传递给DNA;第四,只有诱导状态的NodD激发的DNA构象才能有效地使RNA聚合酶形成转录开放复合物;第五,不排除NodD与RNA聚合酶可能有直接的相互接触位点,不排除NodD构象的改变可能直接有利于RNA聚合酶形成转录开放复合物,但是我们认为NodD构象改变本身不是充当转录激活开关的决定因素。

The recombinant MA can undergo trimerization and the NC contains an I domain that can promoter Gag-Gag interaction. Previous studies have shown that the assembly function of NC in Gag can be replaced by sequences that dimerize or multimerize.

MA有聚合的能力,而NC上的I domain也能促进Gag-Gag之间的聚合作用,研究证实,以一种能促使蛋白间产生聚合作用的序列可取代NC 在Gag组装过程中的角色。

Reversible Addition-Fragmentation Transfer polymerization; Living Free Radical Polymerization; Photoinitiate polymerization; Trithiocarbonate

工程科技I,化学,高分子化学可逆加成-断裂链转移自由基聚合;活性聚合;紫外光聚合;苯乙烯St

1MM GTP was mixed with tubulin (2mg/ml) and varying concentrations of sodium selenite. The mixture was incubated at 37℃ for 1hr. MTs were separated from unassembled tubulin by centrifugation. Both supernatants and pellets were subjected to SDS-PAGE.

其中一组实验是在相同的微管蛋白体系中加入不同浓度的亚硒酸钠,然后加入GTP,37℃聚合,离心,沉淀为聚合的微管,而上清液为未聚合的微管蛋白。

Concentrated emulsion polymerization of styrene in the presence of two polymerizable surfactants, sodium undecylenic acid and newly synthesized CS-1 was carried out.

在苯乙烯的浓乳液聚合体系中,考察了两种可聚合的表面活性剂十一烯酸钠和新近合成的阴离子型羧酸盐类的表面活性剂CS-1的聚合行为。

The temperature of volume phase transition for polymerized gels is about 110 ~ 120 ℃ higher than that of the unirradiated gels.

聚合凝胶只有体积相变而无凝胶-溶胶相转变,且聚合凝胶的体积相变温度要比光聚合前的凝胶-溶胶相转变温度高出约为110 ~ 120 ℃。

The relationship of the amounts of emulsifier, organosilicon monomer (D4) and initiator with the ratio of fluorescence intensity between first vibronic peak of pyrene (λ= 373 nm) and third vibronic peak of pyrene (λ=384nm)Ⅰ1/Ⅰ3 were discussed during the emulsion polymerization process, in which pyrene was used as fluorescence probe. The polymerization behavior of the organosilicon-acrylate latex with core-shell structure was investigated in line with the relationship of monomer conversion and development of morphology in latex particles with the value of Ⅰ1/Ⅰ3 for probe pyrene during the polymerization process.

以芘为荧光探针,探讨了有机硅-丙烯酸酯核壳乳液聚合过程中,芘的第一振动峰(373nm处)与第三振动峰(384nm处)荧光强度的比值Ⅰ1/Ⅰ3与乳化剂、有机硅单体(D4)和引发剂用量之间的关系,并结合聚合过程中探针芘的Ⅰ1/Ⅰ3 峰值与单体转化率及乳胶粒形态演变之间的关系,研究了核壳结构有机硅-丙烯酸酯乳液的聚合行为。

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