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This dissertation involves the study of the growth dynamics of colloidal particles under unequilibrium and irreversibility condition. Firstly, it is of interest to investigate whether the ideal diffusion or reaction-limited aggregation universal behavior can be observed for the initially polydisperse practical system of basic yttrium carbonate as well. The fractal structure of basic yttrium carbonate aggregate cluster was observed using transmission eletron microscopy. The aggregation kinetics of basic yttrium carbonate colloids was studed using dynamic 1ight-scattering techniques. At 1.00mol/l NaCl solution the fast diffusion-limited aggregation behavior was observed with an increase in the aggregate size over time described by a power law. The aggregates are characterized by a fractal dimension D=1.82. The disordered and ramified cluster is consisted of primary colloidal particles and tenuous and more open. These are in good agreement with those observed for other colloidal system such as colloidal gold (1.86), silica (1.85) and polystyrene latex (1.82) in diffusion-limited aggregation from the static and dynamic light scattering by Lin. Therefore ideal diffusion-limited aggregation behavior can be observed in practical polydisperse system as well. Smoluchwski and fractal theories were used to obtain the aggregation rate constant for initially polydisperse system for the first time.

本论文研究胶粒的非平衡不可逆聚集动态学,分为两个部分,第一部分是通过实验研究一个新的初始多分散的碱式碳酸钇胶粒实际体系中,聚集标度性质的普适性,即使用透射电子显微技术观测聚集粒子簇的分形结构,使用动态激光光散射研究碱式碳酸钇胶粒的聚集动力学,胶粒带电而产生静电排斥作用使得碱式碳酸钇胶粒处于稳定状态,当加入电解质NaCl溶液时,碱式碳酸钇胶粒间的Debye-Hückel屏蔽距离缩短,从而降低静电排斥能垒,引起胶粒发生不可逆聚集,加入电解质NaCl的浓度为1.00mol/l时,碱式碳酸钇胶粒进行快速聚集,经历扩散控制聚集机理,形成结构疏松、更为开放的分形聚集粒子簇,其分形维数为1.82,碱式碳酸钇胶粒聚集增长动力学遵循幂函数增长规律,与Lin等使用静态激光光散射和动态激光光散射测量硅胶(1.85)、金胶(1.86)和聚苯乙烯胶乳(1.82)在扩散控制聚集状态形成聚集粒子簇的分形维数值以及粒子簇聚集增长的动力学规律相一致,表明胶粒聚集标度性质的普适性质在初始多分散的实际体系中也是存在的,首次由动态激光光散射的实验数据得到初始多分散胶粒分形粒子簇的聚集速率常数,并且其值与Smoluchowski聚集速率理论预期相符。

In this paper, the progress in the synthetic and typical structural chemistry of borates, germanates and boro germanates , has been reviewed in detail.

本文从结构化学的角度,分别讨论了硼酸盐、锗酸盐及硼锗酸盐研究体系,并对其中的典型结构进行了描述、归类与总结;针对硼、锗易成簇聚集的特点,探讨了硼-锗骨架无机微孔化合物研究的发展趋势。

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Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克,果实色泽鲜艳,汁多味浓,甜酸适口,离核仁甜,清末时就驰名陕、甘两省,清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异:红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感,ED90值分别为47.65、71.67和29.17g/hm2;春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感,ED90值分别为96.91、114.20g/hm2;而番茄不敏感。

However, I have an idea.

不过,我有个主意。