相异的

Linear solvation energy relation was firstly introduced in the paper, and the method and step of gaining the special parameters of solvent and solute were introduced in detail, and these special parameters were used to selection and optimization of extractive agent in extractive distillation. The model of predicting activity coefficient at infinite dilution was established by linear solvation energy relation. By the above theory, several candidate solvents were selected to separate C5 fraction, and by experiment of vapor-liquid phase equilibrium at atmosphere pressure, the mixture of N-methyl-pyrrolidone including 4% water was used extractive agent of separating C5 fraction. Then binary vapor-liquid phase equilibrium of the some compound in C5 fraction and N-methyl-pyrolidone were determined at atmosphere pressure and correlated by NRTL equation. Isoprene being objective compound, experiments were operated in the laboratory-scale column; the processes were simulated by RadFrac model in ASPEN PLUS. And by the combination of experiment and simulation, the new process of separation of C5 was established.

本文首先对线性溶剂化能关系进行了分析介绍，也介绍了采用溶剂化能关系得到溶质溶剂特性参数的方法步骤，并将这些参数用于萃取精馏萃取剂的选择与优化；也通过线性溶剂化能关系式建立无限稀释活度系数预测模型，取得了一定的预测精度；将通过上述方法初选的溶剂进行了常压汽液平衡的测定研究，通过实验研究选定含水4%的N-甲基吡咯烷酮溶液做为C5分离的萃取剂，测定了大量N-甲基吡咯烷酮与C5组分的二元平衡数据，并进行关联计算；以异戊二烯为目标产物在实验室规模的精馏塔内进行了C5分离的实验研究，取得大量塔内数据；通过选用合适的热力学模型，采用ASPEN中RadFrac模块对分离过程进行模拟研究，通过实验与模拟相结合，建立了C5分离的新工艺，为将来的工业化打下了坚实的基础。

The conclusion of the dissertation points out that between different cultural systems,city heterotopia only has two basic faces:first,the culture of this city is very different from the writer\'s culture;second,the culture of this city culture mingles with the writer\'s culture,sharing many similarities.

论文结语指出，在不同的文化体系之间，城市异托邦的具体形象可能千变万化，但最基本的面孔却只有两副：其一，该城市的文化与叙述者所属城市的文化以相异性为主；其二，该城市的文化杂糅了叙述者所属城市的文化，体现出较多的相似性。

All these many properties exist in a simple Here, where they interpenetrate each other. None of these has a different Here from the others; each is everywhere in the same Here where the others are. And at the same time, without being divided by different Heres, they do not affect each other in their interpenetration; its being white does not affect or alter the cubical shape it has, and neither affects its tart taste, and so on: on the contrary, since each is simple relation to self, it leaves the others alone and is related to these merely by being also along with them, a relation of mere indifference.

所有这些众多的特质都存在于这一个简单的这里，它们并且在这里互相贯穿起来；没有一种特质具有异于另一种特质的另一个这里，而每一种特质随便在何处都同别的特质一样存在于同一这里之中；并且同时它们并没有由于不同的这里把它们分离开，在这种贯穿在一起的情况下，它们又彼此互不相影响；盐的白色不影响或改变盐的方形，盐的白色和立方形两者又不影响或改变盐的咸味，既然由于每一特质本身都是简单的自我关联，它们互不干扰对方，它们彼此间只是通过那漫无差别的又联系起来。

Several transient compounds were synthesized by the homo- and heterogeneous reactions of reactive halogen compounds, In-situ ultraviolet photoelectron spectroscopy and photoionization mass spectroscopy as well as theoretical calculations were used to study their molecular structures, stability and molecular orbital properties, their electronic structures and geometric structures were obtained for the first time; Simultaneously, the electronic structure and thermal dissociation of acetyl peroxynitrate and trifluoroacetyl peroxynitrate which have great importance in the atmospheric chemistry were studied; The substituent effects of series of halopyridines and halothiophenes were studied by the ultraviolet photoelectron spectroscopy method for the first time. The atmospheric chemical reaction between peroxyacetyl radicals with IO radicals as well as the dissociation of the most stable isomer of CH3COIO3 were calculated by density functional theory, it was found that the CH3COOIO2 isomer may be act as a new reservoir of inorganic iodine in the stratosphere.

通过活性卤素的系列均相与非均相化学反应合成了几种瞬态物种，采用原位紫外光电子能谱和光电离质谱结合量子化学理论计算对化合物的分子结构、稳定性以及分子轨道特性进行了研究，首次获得了这些物种的电子结构和几何结构的信息；同时研究了大气中有重要作用的乙酰过氧硝酸酯和三氟乙酰过氧硝酸酯的电子结构性质及热解过程；采用紫外光电子能谱手段首次研究了系列卤代吡啶和噻吩的取代基效应；通过量子化学理论计算研究了乙酰基过氧自由基与IO自由基的大气化学反应及其最稳定异构体CH3COOIO2的解离，发现该物种可能是无机碘化合物在平流层中的储库物种。

Based on the fact that the stable tautomer of NTBC by calculation is different from that from X-ray experiment, the quantitative structure-activity relationship (Comparative Molecular Field Analysis, CoMFA and Comparative Molecular Similarity Index, CoMSIA) were studied on the five possible active tautomers in order to conjecture the structure of NTBC binding with HPPD.

基于理论计算得到的NTBC的稳定异构体结构与实验观测结构不一致的事实，利用比较分子力场和比较分子相似性指数的分析方法对NTBC可能存在的五种活性结构分别进行了三维构效分析，最终由CoMFA分析得到的最佳模型所对应的NTBC的活性结构与动力学实验推测的结合模式相吻合。

Focusing on the PGE enrichment mechanism in the basic-ultrabasic intrusions in the Panxi rift, firstly, through the interpretation of TM photograph, data processing of regional geochemical exploration and geophysical prospecting results of gravity, magnetic force and seism, we analyzed the controlling effect of structure and magmatic movement on the PGE mineralization; Secondly, through the study of volcanic apparatus, petrography, measurement of comprehensive geochemical section, isotope tracing and dating of typical PGE-rich melanocratic rock series, we discussed the sources of the PGE-bearing mafic-ultramafic intrusions and basalts, their timing, evolvement sequences, the geochemical processes of magma crystallization and fractionation, and the relationship between magma evolution and structural development; Finally, through the analysis of PGE and chalcophile elements concentrations in the melanocratic rock series and the contrastive study with the Noril''sk magmatic Ni-Cu-PGE sulfide deposit, its related continental flood basalts and Siberia Traps, we discussed PGE mineralization characteristics and its enrichment mechanisms in the melanocratic rock series in the Panxi rift.

本项目首先围绕川西地区主要的PGE矿床及伴生矿的地质环境和有关的地质构造背景，通过TM卫片解译、区域化探和重、磁及地震物探资料分析，总体把握构造及岩浆活动对PGE成矿的控制作用；然后通过对典型富PGE暗色岩套的火山机构地质构造、岩石岩相学、地球化学、同位素定年和示踪等方面的工作，分析本区基性－超基性含矿岩体与喷出岩之间的成岩物质来源、侵入时代及演化序列，研究该区同一岩浆房分异结晶的地球化学过程及其随构造发展的耦合关系；最后通过对暗色岩套PGE地球化学剖面分析以及与俄罗斯诺里尔斯克陆内裂谷溢流型玄武岩中PGE矿化的岩石－构造环境对比研究，探讨该区暗色岩套中的矿化特点和富集部位及其PGE富集机制。

By the field survey which lasting a period of 3 grown seasons and by the means of remote sense and geographic information system, we ascertain the present vegetation pattern of Hunshan-Dake sand land, find out vegetation distribution principles on the different scales in the same time . From west to east, with the increasing of dry degree, the type of plant community changed form the xeric to the mesic. The vegetation of Sand land shows the characteristic of the zonal vegetation, but dont consistent with the traditional diversification principle. The vegetation of the middle part displays a high differential characteristic, which compresses the longitudinal zonation at a certain extent. So we can say that sand land vegetation is semi-zonal.

通过对浑善达克沙地历时三个生长季的地面考察并应用遥感及地理信息系统等手段，确定了浑善达克沙地植被分布现状及浑善达克沙地植被在不同尺度下的分异规律：由西向东，沙地植被随着干燥度的降低，由旱生群落为主的区段递变为以中生群落为主的区段，表现出具有一定的地带性植被特征，但与传统的地带性植被的递变规律不相一致，沙地中段的植被表现出了高度的特异性，在一定程度上压缩了植被的经向地带性，表现出沙地特有的地带性分布规律，所以认为沙地植被是一种半地带性植被。

The Division of Neurology is primarily dedicated to teaching and research in neurology including molecular aspects of xenobiotic enzymes, epilepsy, percutaneous carotid and vertebral artery angioplasty, In vitro and in vivo experimental studies on neuroprotective effects of neuropeptides during focal cerebral ischaemia, cardiovascular and autonomic complications during the acute stage of stroke.

神经学分部主要致力于神经学的教学与研究，其研究领域包括异生化合酶类的分子相，癫痫，颈动脉和脊椎动脉血管成形术，脑局部缺血中神经肽的体内和体外神经保护，急性中风时的心脏血管和自发的并发症等。

Determination of Tyrosine in Urine Spectrophotometric Method;2. For chemical pre-extraction, MSTFA/TMSL derivatization reaction, GC/MS analysis, it is confirmed that two main metabolites (19-no-randrosterone and 19-noretiocholanolone) were found in nandrolone urine.

本文对合成的19-去甲雄烷醇酮的四个差向异构体混合物进行气相色谱分离，对诺龙和炔诺酮用药后，留取的人尿样通过化学预处理，MSTFA/TMSI衍生化反应，GC/MS分析，确证了尿样中诺龙的两个主要代谢产物为19-去甲雄酮和19-去甲原胆烷醇酮，炔诺酮的两个主要代谢物是四氢炔诺酮的两个形式，可能是3α-OH-5α-THINE和3α-OH-5β-THINE，在炔诺酮代谢前期，还发现有诺龙的上述两个代谢物存在。

Methyl isobutyl ketone is a good origanic slovent and the advanced process for producing MIBK is one-step synthesis by gas-phase condensation and hydrogenation of acetone. In this process, the key technology is to develop the multi-fuctional catalyst, which has both the ability of hydrogenateon and condensation, as well as suitable acid-base sites.

甲基异丁基酮是一种优良的有机溶剂，先进的生产方法是丙酮气相缩合加氢一步法，该工艺关键的技术是开发高效的双功能催化剂，即催化剂同时具有缩合、加氢以及适宜的酸、碱性质。

Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克，果实色泽鲜艳，汁多味浓，甜酸适口，离核仁甜，清末时就驰名陕、甘两省，清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异：红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感，ED90值分别为47.65、71.67和29.17g/hm2；春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感，ED90值分别为96.91、114.20g/hm2；而番茄不敏感。