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The influences of the amount of 1,2-diaminoethane, temperature, molar ratio of epichlorohydrin and dimethylamine, and time on the viscosity and cationic degree of polyamine flocculants were investigated.

以环氧氯丙烷和二甲胺为原料,乙二胺为交联剂,制备有机阳离子聚合物,研究乙二胺加入量、反应温度、环氧氯丙烷和二甲胺的摩尔比、聚合时间等对聚合物粘度和阳离子度的影响。

The solvolysis activity can be inhibited remarkably if a small amount of base was added in the medium. And the activity can be enhanced if acid was added.

原料中加入碱性物质可以显著抑制TS-1催化环氧丙烷溶剂解反应的活性;原料中添加酸性物质可以增强TS-1催化环氧丙烷溶剂解反应的活性。

The preparation of esterified derivant : it is prepared by the esterifying reacting of above (3) product and 4g dodecylbenzene sulphonic acid heated in water bath at 40℃ within 30min.

聚环氧氯丙烷乙二醇哌啶接支酯化衍生物的制备:4g十二烷基苯磺酸于40℃水浴条件下聚环氧氯丙烷乙二醇哌啶接支衍生物进行酯化反应。

Epichiorohydrin was synthesized from alkali and glycerol dichlorohydrin which was synthesized from glycerol and industrial hydrochloric acid in the presence of catalyst and additive.

介绍了环氧氯丙烷合成新工艺:在催化剂和添加剂存在下,甘油与工业盐酸反应制得二氯丙醇,然后二氯丙醇与碱反应制得环氧氯丙烷产品。

Epichlorohydrin was synthesized from alkali and glycerol dichlorohydrin which was synthesized from glycerol and industrial hydrochloric acid in the presence of catalyst and additive.

摘 要:介绍了环氧氯丙烷合成新工艺:在催化剂和添加剂存在下,甘油与工业盐酸反应制得二氯丙醇,然后二氯丙醇与碱反应制得环氧氯丙烷产品。

Influences of reaction temperature, catalyst concentration, molar ratio of methanol to propylene oxide and reaction time on conversion of propylene oxide, yield and selectivity of propylene glycol monomethyl ether were studied.

在反应温度为120~130℃、催化剂用量为0.20%~0.30%、甲醇与环氧丙烷摩尔比为3/1~5/1的反应条件下,环氧丙烷的转化率在98%以上,丙二醇甲醚的选择性达95%,收率达93%,产品中伯醚的选择性为92%~93%。

First, 4-(2, 3-epoxypropoxyl) benzaldehyde was obtained by reaction of 4-hydroxy benzaldehyde and epichlorohydrin. Then, the Wittig reaction was carried out to convert EBD to styryl glycidyl ether.

首先用对羟基苯甲醛和环氧氯丙烷反应制备4-(2, 3-环氧丙氧基)苯甲醛,然后通过Wittig反应将醛基转化为乙烯基得到含环氧基团的功能性单体苯乙烯基环氧丙基醚,最后用ATRP方法聚合单体SGE得到含环氧侧基的聚苯乙烯。

Chiral SalanCrX complexesa saturated version of SalenCr(ⅢX are designed,and in conjunction with an ionic quaternary ammonium salt or organic strong base can efficiently catalyze the asymmetric,regio-and stereoselective alternating copolymerization of CO_2 with rac-PO at mild conditions to afford isotactic-enriched polycarbonates with~95%head-to-tail linkages and moderate enantioselectivity.

本论文在Salen构型配体的基础上,设计合成了一系列手性Salan型铬配合物,并将其与季铵盐/有机强碱组成亲电-亲核双组分催化体系,在室温下可以有效的催化CO_2和环氧丙烷的不对称交替共聚反应,实现了CO_2和环氧丙烷的不对称交替共聚反应的区域和立体化学控制,得到95%的头尾连接单元和中等光学纯度(对映体过量值ee%≈70%)的全同结构的聚碳酸酯。

The distance difference between 6/8/6/4 taxoids and 5/7/6/4 taxoids indicates that the role of oxetane is to form a suitable bow-shaped skeleton with 6/8/6 tricycle.

环氧丙烷结构类型化合物弓形口间距值明显区别于其它三类化合物;5/7/6/4与6/8/6/4类型化合物弓形口距离不同,说明紫杉烷二萜化合物的环氧丙烷结构对活性的作用是和6/8/6三环骨架共同支撑一个合适大小的弓形架。

Under distillation conditions, including a bottoms temperature of greater than about 55 DEG C and less than about 75 DEG C, an overhead or side-cut distillate stream containing a purified propylene oxide is obtained with low yield loss of propylene oxide to propylene glycols and other glycol heavies.

在包括大于大约55℃且小于大约75℃底部温度的蒸馏条件下,得到含有纯环氧丙烷的塔顶馏分流或侧馏分流且具有低的从环氧丙烷转化到丙二醇和其他二醇重质的产率损失。

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