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The present production situation and market prospects of the main epichlorohydrin downstream products,such as epoxy resin,synthetic glycerol, chlorohydrin rubber ,and so on,are described.

论述了环氧氯丙烷的主要下游产品环氧树脂、合成甘油、氯醇橡胶等的生产现状、市场前景等,指出:我国氯碱行业应该重视这些环氧氯丙烷下游精细化工产品的开发,以促进我国环氧氯丙烷的发展。

PECH based PUs showed higher phase separation than that of PPG base PUs owing to that the -Cl groups in PECH reduced the flexibility of molecule chain and hindered the formation of hydrogen bonds between ether groups in soft segments and -NH groups in hard segments. As a result, PECH based PUs have lower free volume content, diffusion coefficient and equilibrium adsorption of CO〓, benzene and ethanol through them than through PPG based PUs.

聚环氧氯丙烷醚聚氨酯的氯基降低了链段柔性,妨碍了软段中醚基与硬段中氨基的氢键作用,导致其相分离程度较聚环氧丙烷醚聚氨酯大,并使CO〓、苯和乙醇蒸汽在聚环氧氯丙烷醚聚氨酯中的渗透系数和扩散系数较聚环氧丙烷醚聚氨酯小,而偏离费克扩散的程度大。

The optimum conditions were reaction temperature 120°C, reaction time 20h, mole ratio of 5-chloromethyl-2-oxazolidinone and sodium phenolate 1:1. 3,5-Dimethylphenol and epichlorohydrin in sodium hydroxide were condensated to give l,2-epoxy-3-phenoxy propane, then the reation of l,2-epoxy-3-phenoxypropane and the carbamate afforded oxazolidinone in the yields of 69.0%~76.0%. The side reaction had been avoided effectively by the uses of the excessive epichlorohydrin and mixed catalysts.

用3,5-二甲基苯酚和环氧氯丙烷在氢氧化钠存在下缩合生成苯氧基环氧丙烷,然后和氨基甲酸酯反应生成噁唑烷酮,采用过量环氧氯丙烷和使用混合催化剂,有效的避免了副反应的发生,提高了噁唑烷酮的产率,产率69.0%~76.0%。

It deliberated that magnesium sulphate and epichlorohydrin affecting on synthetization of starch xanthate, mass ratio of synthetic starch xanthate and Magnesium sulphate was...

研究了MgSO_4和环氧氯丙烷对DX合成的影响,得出淀粉和MgSO_4的重量比为8:1,淀粉和环氧氯丙烷的重量比为10:1,MgSO_4和环氧氯丙烷对黄原酸化程度没有影响,但能增强交联程度和不溶性。

Respectively, glutamic acid derivatized β-CD has been synthesized with epoxy chloropropane as the intermediate, a water-insoluble yellow liquid was got after the acetylating of the by using acetic anhydride, which was used as a novel gas chromatographic CSP; A water-soluble β-CD polymer cross-linked with epoxy chloropropane has been synthesized, and the derivatives of β-CD polymer were synthesized by its alkylating and acetylating. The different β-CD derivatives were coated on silica capillary columns by dynamic method, the chromatographic properties and retention behaviors of the fused silica capillary columns were studied, the results showed that the β-CD derivatives had good stereoselectivity and separation results to some compounds, especially to various positional isomers and enantiomers.

本文还分别以环氧氯丙烷为中间体,合成了七{2,6-二-O-[3-(1,3-二羟基丙氨酸)]}-β-环糊精,再用醋酸酐将其乙酰化,得到了一种淡黄色粘稠液体,合成了一种新型的环糊精衍生物;以环氧氯丙烷作交联剂合成了一种水溶性的β-环糊精聚合物,再将其烷基化和酰基化,合成了β-环糊精聚合物的不同衍生物,用动态法将不同类型的β-环糊精衍生物涂渍在石英毛细管柱上,通过对所制备柱柱性能的测试和对一系列化合物的分离和保留行为的研究,结果表明所合成的β-环糊精衍生物对各类化合物,特别是对位置异构体和对映异构体具有较好的分离效果,显示了很强的立体选择性。

Its high-capacity and strong-acid-resistance were proved. In the acid condition, the adsorption efficiency to acide green 6B and direct fast yellow RL reached above 90%. Through the adsorption rate curve on adsorption behavior of the three dyes, they were all according with pseudo-secondary adsorption rate curve. The rate constant of adsorption increased with increasing temperature. Through the adsorption isotherm of the three dyes, acide green 6B and direct fast yellow RL were according with Langmuir equation, while disperse blue 56 was according with Freundlich equation. The adsorption behavior was an endothermic process. Entropy was increasing during the adsorption. So raising temperature was in favor of adsorption.

结果表明,甲醛环氧氯丙烷交联壳聚糖对染料具有较强的吸附性能和耐酸性能,在酸性条件下,对酸性绿6B和直接耐晒黄RL的吸附效率达90%以上;拟合甲醛环氧氯丙烷交联壳聚糖对三种染料的吸附速率曲线,发现该吸附行为符合拟二级吸附速率曲线,其吸附速率常数随温度的升高而增大;通过测定不同温度下甲醛环氧氯丙烷交联壳聚糖吸附三种染料的吸附等温线表明,甲醛环氧氯丙烷交联壳聚糖对酸性绿6B和直接耐晒黄RL的吸附符合Langmuir方程,而对分散蓝56的吸附符合Freundlich方程,甲醛环氧氯丙烷交联壳聚糖对染料的吸附是一个吸热过程,吸附后体系熵增加,升温有利于吸附。

It is advisable to avoid the use of Aramine with cyclo-propane or halothane anesthesia

如果不是临床需要,建议本品不要与环丙烷或氟溴氯乙烷麻醉剂合用。

By synthesizing the hapten LBc starting from the metabolite of bifenthrin (2-methyl-3-phenylbenzyl alcohol), LBs (2-methyl[1,1-biphenyl]-3-ylmethyl 3-carboxyl-2,2-dimethylcyclopropane carboxylate and Lby (2-methyl[1,1-biphenyl]-3-ylcarboxylic acid , Three haptens were praparaed which were used in next step.

利用联苯菊酯的代谢物联苯醇合成了联苯菊酯的半抗原LBc(2-甲基-3-苯基苄基氧基羰基丙酸)、LBs(2-甲基-3-苯基苄基-3-羧基一2,2-二甲基环丙烷羧酸)和LBy(2-甲基-3-苯基苯甲酸)。

The chiral ligands la-lf were used in the copper catalyzed asymmetric addition of diethylzinc to imines.

第二部分探索了一个新的含氮杂环丙烷的手性膦配体2的合成方法。

This thesis focuses on the transformation of amines and imines under the condition of Barbier-type reactions,and also the synthesis of aziridines catalyzed by the PhI_2/I_2 system.

本论文主要对锌试剂Barbier型条件下胺、亚胺的转化和PhI_2/I_2体系下氮杂环丙烷的合成做了一些研究。

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