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In this study, the CPE processes of four different kinds of polyaromatic hydrocarbons, acenaphthene, anthracene, phenanthrene a...

今利用两种聚醚型有机硅表面活性剂DC-193和DC-190,对蒽、菲、芘和苊四种多环芳烃进行浊点萃取研究,分别使用加热、加盐、离心和搅拌等辅助方法改变相分离过程的速度。

Effects of three feeding methods on siloxane modified acrylate emulsion polymerization stability and properties of emulsion were studied.

研究了3种单体投入方式对有机硅改性丙烯酸酯乳液聚合稳定性及性能的影响。

The effect of the substrate on the surface properties of organosilicon polymer and acrylate polymer blend films was investigated.

研究了成膜基材对有机硅聚合物-聚甲基丙烯酸甲酯溶液共混物薄膜表面性能的影响。

So modified by polysilicone , acrylate resins properties can be improved.

因此利用有机硅改性,可大大改善丙烯酸树脂的性能。

AEI, a leading supplier of broadband communication, broadband networking and broadband application products that are cutting edge, innovative and affordable, is located in Sunnyvale, California,...

其主要业务是研发生产销售有机硅、聚合物、精细化学品、多晶硅和超纯硅片。瓦克在欧洲、美洲和亚洲拥有20多个制造工厂以及全球100余个销售办事处,雇佣了大约近20000名员工。亚洲的制。。。

Transmission Electron Microscope and other properties testing results show that the complex emulsifier system is the crucial influence factor of the polymerization process and the properties of products. It may influence the coagulum content and reaction rate of the polymerization process, the performance, particle diameter,viscosity, electrolyte stability and storage stability of the emulsion products and the contact angle of the film.The initiator mainly influences the coagulum content and reaction rate.The acrylic monomers mainly influence the solid content, Minimum Film Formation Temperature of the emulsion and the Glass Transition Temperature of the film.The organic silicone monomer mainly influences the water absorption of the film.The reaction temperature mainly influences the reaction rate and conversion.The stirring intensity mainly influences the coagulum content of the polymerization process.

透射电镜等性能测试结果显示:复合乳化剂体系是硅丙共聚乳液的聚合过程及产品性能的主要影响因素,它可以对聚合过程的凝胶率、反应速率以及乳液的外观、粒径、粘度、耐电解质稳定性及贮存稳定性,还有乳液涂膜的接触角等造成不同程度的影响;引发剂主要影响反应速率和凝胶率;丙烯酸酯单体主要影响到乳液的固含量、最低成膜温度以及涂膜的玻璃化转变温度,有机硅单体主要影响涂膜的吸水率等;聚合反应温度主要影响乳液的反应速率和转化率等;搅拌强度主要是影响到聚合过程的凝胶率。

Calcium carbonate and soluble glass and so on were confected as alkaline antifouling agent. The Infrared Spectrometry results showed that 2275-2250 cm~(-1) diagnostic absorb wave crest in part A and 3390-3200 cm~(-1) in part B and 1730 cm~(-1) in coating film strongly proved polymers reacted just as the reacting mechanism, that means polysiloxane which offer low-surface-energy property linked Polyurethane system by —OH groups reacting with —NCO groups. Relative molar mass of part A and part B was determined by Gel Permeation Chromatography and the results were appropriate. Surface-energy was determined and results were between 33.6-47.17 mN/m and it increased when alkaline antifouling agent was put into the coating. Alkaline antifouling agent was releasing steadily when the coating film was dipped in seawater. As time gone, the pH value of seawater was increasing. Solubility parameter and results showed that there was no corrasive phenomenon between the polyethylene strand and the coating.

红外光谱分析结果表明,出现在A组分中的2275~2250cm~(-1)处的异氰酸酯特征吸收峰、B组分中的3390~3200cm~(-1)处硅羟基的特征吸收峰及出现在固化后涂膜中的1730cm~(-1)处氨基甲酸酯基团的特征吸收峰证明了涂料成膜物质交联固化符合本文的设计要求,即赋予涂膜低表面能特性的有机硅组分通过—OH基团与—NCO基团的反应已经链接到聚氨酯体系中;凝胶渗透色谱结果表明,成膜物质的A、B组分均为低分子量,符合预聚物的要求;涂膜表面能的测算结果表明,涂膜的表面能在33.6~47.17mN/m之间;加入碱式防污剂后涂膜的表面能略有升高;碱式防污剂的释放平稳,随着涂膜在海水中浸泡时间的增长,pH值有增加的趋势;用溶解度参数原则来评价涂料与网绳的涂装,结果表明,本试验研制的防污涂料对聚乙烯网绳无溶蚀作用。

The preferred organometallic compounds of the present invention are of the formula (R1)m M(PR23)x, where M is a metal selected from the group consisting of manganese, technetium, rhenium, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium iridium and platinum wherein m is 0, 1, 2, 3 or 4; x is 2, 3, 4 or 5 and m+x are 2, 3, 4, 5, 6, 7 or 8, m and x selected according to each metals appropriate valence; each R1 is independently selected from the group consisting of hydrogen, deuterium, N2, H2, D2 and a variety of substituted alkyl groups; each R2 is independently selected from the group consisting of lower alkyl, aryl, arylalkyl, and alkyl-Z, aryl-Z and arylalkyl-Z where Z is selected from the group consisting of oxy, silyl, siloxy, oxysilyl, siloxy, oxysiloxy, silyalkyl, oxysilylalkyl, siloxyalkyl, oxysiloxyalkyl, silylalkoxy, silylalkoxy, siloxyalkoxy and oxysiloxyalkoxy; and wherein when M is cobalt and one group R1 is selected to be N2, then m is 2 and the second group R1 is hydrogen or deuterium.

有机化合物的首选本发明的配方是米(R1代)米×(pr23)、那里是一米的金属挑选出来,第一组由锰、锝、铼、铁、钴、镍、钌、铑、钯、锇、铱铂其中M是0、1、2、3或4; X是2,3, 4或5米×+有2,3,4,5,6,7或8 米和X挑选合适的价按每个金属; R1的是每一组由独立选自氢、氘、氮、氢气、 D2和各种烷基取代群体; R2中的每个组由独立选自烷基低、芳、芳基烷基、烷基的Z、芳基、芳基烷基的Z-那里的ZZ是选自组风、含硅、氧、oxysilyl、硅、oxysiloxy,silyalkyl, oxysilylalkyl,siloxyalkyl,oxysiloxyalkyl,silylalkoxy,silylalkoxy,siloxyalkoxy和oxysiloxyalkoxy;其中,M是当钴一派R1的选择是氮气、然后是2米,第二组R1的氘是氢或者。

In addition to complex anion crowd carried by organic functional group, there were many kinds of mass point like aluminum, silicon, zinc and rare earth elements et al in composite elastic material, and there were replaceable cation as well as anion; besides, all cation kept rather distant each other. It was not easy to crystalize in composite elastomer because of the block of organic molecule.

在复合弹性体材料中,除了存在有机官能团所带有的络阴离子群之外,还同时存在铝、硅、锌和稀土元素等多种质点;存在可以置换的阳离子和阴离子,并且各种阳离子都保持相当远距离;由于有机分子的阻挡,复合弹性体内不易析晶。

This paper with 29 references reviewed the design, synthesis and applications of organosilyl linkers in solid phase synthesis within 26 years.

本文从直接法和间接法两方面综述了26年来具有代表性的多种有机硅连接体的设计、制备及其在固相有机合成中的应用。

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