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Notably, compounds 12–14 can be described as a 3D open–framework with nano–channels, compound 15 can be described as a 3D open–framework with double helical channels, while compound 16 can be described as a 3D heterochiral coordination polymer with double helical channels, which can be obtained by spontaneous resolution from the racemic phosphonic acid.X–ray powder diffraction analysis shows that compound 16 is a pure phase. Surface photovoltage spectroscopy of compound 16 indicates that it possesses positive SPV response in the range of 300–600 nm and shows p–type semiconductor characteristic.

值得注意的是,化合物12-14为具有一维纳米孔道结构的三维开放骨架结构,化合物15是具有双螺旋孔道的三维开放骨架结构,而化合物16是外消旋的有机膦酸配体通过自发拆分而形成的具有双螺旋孔道的多手性三维开放骨架结构。X-射线粉末衍射分析表明化合物16为纯相;化合物16的表面光电压光谱分析中,在300-600nm范围内有3个正的光(来源:ABC论文12网www.abclunwen.com)伏响应带,表明它具有p型半导体的特征;化合物16的诱导表面光电压谱进一步确定它的p型半导体的特征;磁性研究表明,化合物16中两Mn原子之间存在弱的反铁磁相互作用。

This paper analyses the different concentrations of Pb, Zn ion hybrid seedlings on the soil culture camphor several physiological indicators of the impact of the results show that the experimental results show that, POD, SOD, CAT, such as the biological oxidation resistance of the show is basically change the trend promoting high-low suppression trend, proline, MDA membranaceous permeability, as well as the content, with the concentration of heavy metals increases, reflecting the biofilm was heavy metal ions damage situation.

求高手翻译一段话,好的话多给100分!本文分析了不同浓度的Pb、Zn混合离子对土培香樟幼苗的几种生理指标的影响,结果表明,实验的结果表明,POD,SOD,CAT等抗氧化性的生物酶的改变趋势基本上呈现低促高抑的趋势,而脯氨酸,丙二醛以及膜质透性的含量是随着重金属浓度的增大而增大,体现出了生物膜被重金属离子的破坏的情况。

TyPe II collagen induced arthritisln the rat ank1e joint andoVathumin as antigen induced arthritis WA in the rabbit knee joint wereestab1ish2 Qualitative evaluation of me in skin, muscle, synovium, cedilagearound joint and blood was performed by OMA3 The CIA rats were treated on day 7 after hind paw swelling and erythemaAnimals were injected intravenously with ase at a dose of 10mg/kg,tWenty minuots 1ater, one ankle of the rats random1y assigned was exPosedlaser irradiation at l00J/cm fOr l000 seconds, and another ankle wasM grouP wihout laser The other two groups is unmanipulatedcontrol group and untreated CIA group Bimaleolar ankle widthmeasuremellts were taken in all animals every tWo days using amicrometer The histopathology of the ank1e Joint was assessed at day 21after disease onset4 The pro1iferating cell nuclear antigen WCNA of CIA treated by PDT andthe HMME group without laser was doterdrined by immunohistochemiStry5 The AfA rabbits were treated on day 7 after knee swelling and erythemaThe theraPy invo1ved lntravenous injection of l0mg/kg HMME, fOl1owedby 20 minues period in dim light, and transdermal light treatment with\l00 J/cm2 fOr l000 seconds The inner sides of the treated Anees wereirradiated at first, and then the outer side did 24 hours later, the synovialtissue of the Anees joint were removed and in situ cel1 aPoptosis wasdetCCted With tednal deoxync1eotidyl transferase-mediated dUTP nickend labelingR6suIt8:l The pathologic changes of CIA and AIA include subsynovial inflammation,opovial hyPerplasia, pannus formation, cartilage and bone destructionresemble RA.2 The studies demonstrated that there are different uptake of HMME withinskin, muscle, synovium, cartilage and b1ood, and the synovium cou1draPidly uPtake more ase than skin and cartilage at the firSt 30 minuesaller intravenous injection of HMME3 The bimaleolar anke width had no different among PDT treated group,H group withollt 1aser and untreated CIA group But hlstologicalevaluation showed statiStical1y significallt reductions in synovialhyperplasia, pannus formation and cart1lage reosion, bone destruction andtotal score in PDT treated group4 Image analysis showed that the ratlo bforeen the areas of the coufltedobect to that of the entire area in PDTtreated grOup is lower than that in conirol group, but the integrated oPticaldensity had no different between the two groups5 Imape analysis showed that the ratio between the area of the countedobject to that of the e

治疗组在大鼠出现踝关节红肿后1周,炎症达到高峰时进行PDT治疗。随机治疗大鼠一侧的踝关节,另。2。一一侧作单纯HMME 对照。治疗方法是大鼠麻醉后尾静脉注入 HMME10ngkg,20分钟后踝关节照光,激光波长627.sum,功率密度 100mwcm',照射时间1000秒,能量密度100)/。治疗后避光喂养72 小时。隔日一次测量大鼠的踝关节左右横径,治疗后两周取关节进行病理d 观察。 4。大鼠CIA模型用上述方法进行PDT治疗后,治疗组和单纯HMME 组用兔疫组化SP法检测石蜡切片的核增殖抗原。 5。兔AIA模型在关节炎出现第七天进行PDT治疗,随机治疗一侧膝关节,另一侧作自身对照。兔耳静脉注入I'arrainrelomg/Kg,20分钟后,膝关节用金蒸气激光照射,激光能量密度100)儿旷。24 /J'时后取膝关节滑膜作病理检查,并用脱氧核昔酸末端转移酶介导的缺口末端标记法原位检测凋亡细胞。结果: 1。模型观察:CIA大鼠炎症高峰期滑膜下炎细胞浸润明显,滑膜细胞明显增殖,炎症达到高峰后二周,血管缀形成,并侵蚀和破坏软骨和骨, CIA模型病理改变与人类RA相似。兔AIA模型膝关节滑膜病理可见滑膜细胞增生,滑膜下炎细胞浸润,也与人类RA滑膜改变相似。 2。关节周围组织中光敏剂含量的测定结果表明,各组织对HMME 的吸收速度和吸收量不同,荧光值一时间曲线不同,滑膜组织比皮肤和软骨对 HMME的吸收多,在 2 0分钟时即有明显差异。 3.PDT对CIA模型的治疗结果表明:PDT治疗后关节炎组、单纯 HMME组和治疗组踝关节左右横径统计学检验差异没有显著性,但病理评分PDT治疗组滑膜增生、血管资形成及软骨破坏、骨破坏和总分比关节炎对照组和HMME对照组好,统计学检验差异有显著性。。3_军医进修学院硕士学位论文中文摘要 4.PDT治疗组PCNA阳性细胞较对照组少,图像分析结果表明面密度(阳性染色的面积总和与统计视野面积的比值)治疗组小于对照组,统计学检验差异有显著性。。 5.PDT治疗组凋亡阳性细胞较对照组明显增多,图像分析结果单位视野内阳性细胞数和面密度PDT治疗组高于对照组,统计学检验差异有显著性。凋亡细胞核直径PDT治疗组较小,与对照组相比,统计学检验差异有显著性。结论:二。CIA、AIA的病理改变类似人类RA,可作为研究RA病因、发病机制、检查及治疗方法的模型。 2。各组织对HMME的吸收速度和吸收量不同,滑膜组织比皮。

Thus we conclude that JA might be one of the potent factors, other than auxin, involving in the regulation of LR formation.3. Relationship between JA and SA on LR formation in rice seedlingMouse monoclonal antibodies against salicylic acid was produced and characterized for the first time. The McAb S2-8F, were derived from an immunogen in which 5-aminosalicylic acid (5-ASA) was conjugated to KLH (hemocyanin from keyhole limpets) through its-NH2 group.

实验结果还表明IBA对水稻幼苗侧根发生的促进作用可能并非是通过转化为吲哚乙酸(indole-3-acetic acid,IAA)而实现,因为外源IAA不能促进水稻幼苗侧根的发生,荣莉酸对水稻幼苗侧根发生的诱导效应及其与生长素和水杨酸的关系却和 IBA一样可以抑制种于根伸长及促进侧根伸长,只是IAA具有这种效应需要的浓度是IBA的20多倍。3。

The humidity resistance and the sensitivity to chemical warfare agents simulants of the tuned films were also investigated.Self-assembled LBL polyaniline films were prepared from aniline monomers by in situ polymerization and the mechanism of film formation was discussed. It was proposed that the self-assembly of polyaniline occurred through the quick absorption of aniline monomer cations or aniline monomer cation radicals on the glass surfaces by electrostatic attractions to form homogeneous polymerization centers, then increased gradually by the way of upright to the glass supports for extensity, leading to the polyaniline chain growth. The polyaniline was doped under acidic condition to absorb anionic polyelectrolyte, such as sodium polystyrene sulfonate based on the electrostatic force, or to adsorb polymer based on hydrogen-bonding interactions, for example Polyvinyl Alcohol, and then recycled to fabricate_n or_n self-assembled multilayer films.

跟踪了原位聚合的具有纳米结构的聚苯胺多层自组装膜的成膜过程,提出了该自组装膜的成膜机理:聚合反应初始阶段的苯胺阳离子或苯胺阳离子自由基通过静电作用快速吸附到带负电荷的基片表面,形成均匀的聚合中心,然后以垂直于基片的方式进行链增长生成PANI;PANI在酸性条件下经现场掺杂后带正电荷,再通过静电作用吸附带负电荷的聚电解质如聚苯乙烯磺酸钠,或通过氢键作用吸附聚合物如聚乙烯醇,这样循环LBL-SA即得到_n或_n等原位聚合聚苯胺自组装膜。

Single component and multi\|component of iron system colloidal catalyst \Ali\|Bu\-3CH\-2CHCH\-2Cl\ were mixed by different ratios in hydrogenated gasoline medium at 25℃.This paper studied the relationship between the nonaqueous systematic electroconductivity and the concentration of catalyst components.In combination with Tyndall effect,polymerization experimental results,Ali\|Bu\-3 existed in associated state and dissociated into ionpair.The reaction between Ali\|Bu\-3 and Fenaph\-2 was the main reaction which formed colloidal core.Ali\|Bu\-3 reacted on CH\-2CHCH\-2Cl and Ali\|Bu\-2Cl was yielded which joined the formation of active center on the surface of colloidal core.The excessive Ali\|Bu\-3 was dissociated into ionpair which formed double electrode layer,and the double electrode layer kept the colloidal particles relatively stable.

研究了在25℃加氢汽油介质中,铁系胶体催化剂[Fenaph2Ali-Bu3―CH2==CHCH2Cl]单组分、多组分按不同配比混合,非水体系电导率与浓度的关系,结合Tyndall效应,聚合实验结果,得出Ali-Bu3以缔合状态存在并解离成离子对它同环烷酸亚铁的作用是形成胶核的主要反应,与氯丙烯反应生成的氯化异丁基铝,在胶核表面参与形成活性中心由过量Ali-Bu3解离的离子对形成的双电层结构,使胶粒保持相对稳定。

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Methods: Five patients with parkinsonism or dystonia were assigned to general anesthesia using an modified endotracheal tube.

本实验依照人体实验之相关规定进行,五位患有帕金森氏症或肌张力异常的病人接受神经立体定位手术。

If you can benefit from this book, it is our honour.

如果您能从本书获益,这将是我们的荣幸。

The report also shows that the proportion of unmarried men and women living together has doubled between 1986 and 2006, with 13 per cent of those aged 16 to 59 now cohabiting.

报告还指出,从1986年至2006年,英国未婚男女同居的比例增长了一倍,在16岁至59岁的人群中,有13%的人同居。