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The α-helical structure of the globulin is an important factor to forming and stabilizing the protein emulsion. The particle size distribution of legumin and vicilin hydrolysates were measured by dynamic light scattering, the particle size of legumin hydrolysates was decreased at first then increased during the papain hydrolysis, but the vicilin hydrolysates decreased continuously, it demonstrated that the legumin hydrolysates might have a re-aggregation in the solution which the vicilin hydrolysates did not have.

采用动态激光光散射分析了水解产物的粒径分布,结果表明:随着水解的进行,11S球蛋白水解物在溶液中的粒径出现先减小后增加的趋势,而7S球蛋白水解物的粒径呈递减趋势,说明11S水解产物分子间发生了新的选择性定向和聚合,而7S水解物分子间未发生二次聚合。

The distribution pattern also indicate radiolarian concentrations are strongly affected by the sediment type, radiolarian abundance and diversity is higher in the clay or mud than in fine sand, silt or coarse sand and decrease with the increase of terrigenous material. There is direct correlation between the radiolarian preservation and the amount of volcanic glass, the numerous volcanic ash shards have a significant influence on the radiolarian distribution pattern.

沉积物类型特别是其粒度和陆源物质的含量极大地影响着放射虫的分布,放射虫的丰度和分异度明显地随沉积物粒度的增大和陆源物质含量的增加而减小;同时,放射虫的分布也显示了与沉积物中火山玻璃含量的密切相关性。

The study of fluorescence spectrum proved that the excited phenylenerings of amorphous PES copolymer with high density phenylenerings in its main chain could form an excimer with the surrounding unexcited phenylenerings, and the emission peak intensity of excimer was strengthened with the increase of aging time.

荧光光谱的研究证明,非晶态聚醚砜共聚物由于主链苯环密度较高,苯环受激处于激发态时易与周围激态苯环相互作用形成激基缔合物,缔合物发射峰的强度随老化时间增加而增强。

The study of fluorescence spectrum proved that the excited phenylene-rings of amorphous PES copolymer with high density phenylene-rings in its main chain could form an excimer with the surrounding unexcited phenylene-rings, and the emission peak intensity of excimer was strengthened with the increase of aging time.

荧光光谱的研究证明,非晶态聚醚砜共聚物由于主链苯环密度较高,苯环受激处于激发态时易与周围激态苯环相互作用形成激基缔合物,缔合物发射峰的强度随老化时间增加而增强。

The silicone rubber based on PDM-MVS/PMMA blend had microphase-separated structure consisting of PMMA domains uniformly dispersed within a continuous PDM-MVS matrix.

结果表明,随着PDM-MVS中乙烯基质量分数的增加,共混物的黏度逐渐增大;由PDM-MVS/PMMA共混物制备硅橡胶的物理机械性能明显优于α,ω-羟基聚二甲基硅氧烷/PMMA共混物制备的硅橡胶;制得的硅橡胶具有微观相分离结构,PMMA分散相均匀地分布于PDM-MVS连续相中,两相的相容性良好。

The spectroscopic and electrochemical studies suggest the energy structure of this class complex can be easily controlled by modification. With the introduction of electron-donating arylamino groups, the obtained complexes show intense and continuous absorption bands in the region of 250-550nm with strong metal-to-ligand charge transfer dπ(Pt →π* transitions (ε~ 2×104 dm3 · mol-1 · cm-1). Complexes involving the construction of D-π-A type systems also display continuous absorption bands in the region of 400-750nm, rising from the overlapping effect of MLCT and LL'CT bands.

其中,芳胺及其二聚体类修饰基团的引入,使其配合物MLCT吸收谱带的摩尔吸光系数增加,并在250~550nm范围内形成了强的连续吸收;具有D-π-A结构的配合物,由于MLCT吸收谱带和LL'CT吸收谱带的协同效应,导致在400~750nm范围内形成连续吸收;得到了从绿光到深红光的磷光发射系列配合物,并采用真空蒸镀的方法获到了外量子效率分别为5.7%和5.0%的橙光和橙红光多层电致发光器件。

A novel method for determination of benzoyl peroxide with spectrophotometry was developed. Inclusion ratio of β cyclodextrin to dibenzoy peroxide and benzoic acid is obtained with spectrophotometry.The mechanism of the inclusion was studied,too. The results showed that β-CD react with dibenzoyl peroxide to form a 1:1 or 2:1 host-guest complex, with the apparent formation constants of 5.0× 10~2and 2.5× 10~4 , respectively.β-CD reacts with benzoic acid to form a 1:1 host-guest complex with the apparent formation constant of 6.9 × 10~2 after the dibenzoyl peroxide was reduced by hydroxyl ammonium chloride.

建立了用β环糊精测定过氧化苯甲酰的分光光度法,并测定了β环糊精与过氧化苯甲酰和苯甲酸的包结比,随着β-CD浓度的增大,可与BPO分别形成1:1或2:1的包容络合物,包结常数分别为5.0×10~2和2.5×10~4,与苯甲酸形成1:1的包容络合物,包结常数为6.9×10~2;由于包结物的吸光度值比过氧化苯甲酰的吸光度值大大增加,建立了一种当β-CD存在下,在水溶液中测定过氧化苯甲酰的方法。

In results, with the growing of L.kaempferi, the total carbohydrate decreases, water extractives including cold water extractives and hot water extractives increase, and 1%NaOH extractives also increase; glucosan and xylan decrease, however, galactosan increases.

结果表明:随着树龄的增大,原料中碳水化合物含量逐渐降低;冷水抽出物、热水抽出物和1%NaOH抽出物含量增加。

Bio-Ba/Ti, bio-Ba /Al were chosen as the sensitive markers to show the variation of the biogenic/terrigenous suspended particles in MNLS through the correlation analysis of 12 major elements of the suspended particles. Comparing with the overlain waters, the content of terrigenous particles in the BNL was increased significantly, but was lower than that in the surface sediment.

与上覆水体相比,近底雾状层内陆源组分显著增加,但较底质沉积物为低;生源组分则明显降低,但比底质沉积物为高,这一规律说明底质沉积物再悬浮对近底雾状层有显著的影响,表明Ba_/Ti和Ba_/Al值可以作为近底雾状层颗粒物的高精度示踪指标,其中Ba_/Al值尤为敏感。

While the tissue spaces surrounding a few blood vessels wasAl and Fg positive,no Al or Fg positive cells were observed.In antemortem injurygroup,diffuse subarachnoid hemorrhage,cerebral edema,swelling or pyknotic neu-rons could be observed.The axons showed irregular swelling and disconnection at1~3h,marked swelling and disconnection at 6h,and retraction ball at 15h whichwas more remarkable at 24h after injury.The space between myelin sheaths andaxons was increased at 3~6h after injury.Tortuous and wavelike myelin sheathswhich adhered on axons incompletely,or even peeled off could be found from 15hto 24h after injury.Perinuclear lysis of Nissl bodies began at 24h after injury.Thenumber of GFAP positive cells in cerebrum and brain-stem increased significantlyfollowed by decrease,and then increased again,but the time courses of the changesin different areas of brain were not same.Al and Fg positive neural cells,mainlysurrounded blood vessels,with diffuse or peripherally distributed positive matter incytoplasm could be observed at 0.5h after injury.The number of Al or Fg positivecells and the intensity of immunoreaction increased with the time of injury.The areaof SYN positivity in medulla oblongata and pons decreased notably 3~6h afterinjury,then return to normal levels and continued to 24h after injury.

生前损伤组,可见广泛蛛网膜下腔出血,脑组织水肿,神经细胞肿胀,晚期神经元固缩;伤后1~3h见部分神经轴突不规则增粗、断裂,伤后6h断端膨大,伤后15h可见收缩球,至伤后24h更为明显;伤后3~6h可见部分神经髓鞘与轴突之间的间隙增宽,伤后15h髓鞘明显曲折,不完全附着在轴突两侧,甚至剥脱,持续到伤后24h;核周尼氏体减少在伤后24h才开始出现;同一部位的GFAP阳性细胞数目随损伤时间发生改变,先增多(最早在伤后0.5h),达到高峰后减少,其后又有增多趋势,但不同部位的GFAP阳性细胞数目增减的时间过程不尽相同,同时,大脑中的GFAP阳性细胞数目也有改变;伤后0.5h,可在脑干组织中见到Al和Fg阳性神经细胞,主要位于血管周围,阳性物在胞浆中呈弥散性分布,但部分细胞的阳性物仅分布于靠近胞膜的胞浆中而呈环状,随损伤时间延长,阳性细胞数目增多,反应强度增加;伤后3~6h,延髓及桥脑中的SYN阳性物面积减少,其后恢复到正常水平,并持续到伤后24h。

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