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吸收光谱

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Raman spectrum, UV-Vis spectra, IR, NIR and XPS spectra were used to characterize the material. The result indicates that there is a conjugative effect between MWNT and bromine, which induces the change of electron distribution on the MWNT surface. It increased the car- rier density and the electrical conductivity of MWNT became higher.

通过拉曼光谱,紫外可见光谱,红外吸收光谱,近红外吸收光谱和X光电子能谱等方法研究,结果表明:溴与多壁碳纳米管之间存在共轭作用,使多壁碳纳米管表面的电子云分布发生了变化,导致空穴载流子的产生,增加了载流子浓度,提高了多壁碳纳米管的导电性能。

The UV absorption of α hydroxy α,α dimethyl acetophenone,α hydroxy α,α dimethyl acetophenone and α,α dimethoxy α phenyl acetophenone in different media was investigated.

利用紫外吸收光谱对不同环境中的光引发剂进行考察,但由于其吸收光谱没有明显的变化,因而未能获得较确切的结论[1,2]。

Experimental results showed that the CuL complex had five-membered and six-membered rings containing two M—O,and one M—N bonds and that the ligand was of a multidentate one.

对其结构进行元素分析、摩尔电导率、紫外吸收光谱、红外吸收光谱、荧光光谱及电化学表征,结果表明,配合物同时含有2个M─O和1个M─N键形成的五元环和六元环,HL为多齿配体。

In the second part of this work, a computor program is developed to calcalate〓L〓energy levels, reduced matrix elements, crystal field energy levels, oscillator strengths of f-f transition and theoretical f-f absorption spectra of f-ions. The calculation results of the f-f absorption spectra of Nd in water coordination sphere and H di (2-ethylhexyl phosphinic acid coordination sphere with different symmetric structure are shown and compared with observed spectra.

在第二部分中,编制了计算f离子的〓L,能级、约化矩阵元、晶体场中Stark能级分裂、f-f跃迁振子强度及f-f理论吸收光谱的计算机程序,以此程序分别计算了Nd在不同结构对称的水配位层及烷基磷酸配位层中的f-f吸收光谱,通过与实验谱比较,识别了可能的配位层结构,并讨论了f-f跃迁的强度机理。

Comparisons between the experimental and computational IR spectra clarify the difference of the open- and closed-ring isomers, which indicate that it is possible to identify the tautomeric form of this diarylethene derivative using a highly selective infrared absorption band and the strong absorption at 1 705 cm-1 of the ring-closed isomer can be used in non-destructive readout by IR light.

通过红外吸收光谱表征了该光致变色二芳基乙烯衍生物在溶液中开、关环前后结构的变化,并采用理论化学计算方法研究了该化合物开、关环异构体的红外吸收振动特性。光致变色异构化过程可以通过红外吸收光谱的变化而识别。关环异构体在1 705 cm

The method to record the position and intensity of absorption lines with the Fourier\|transform Intra\|cavity Laser Absorption Spectrometer is discussed.

介绍了使用连续扫描方式工作的傅里叶变换光谱仪来探测激光腔内吸收光谱的原理,并探讨了傅里叶变换激光腔内吸收光谱方法测量光谱谱线和强度的工作方式。

The fluorescence spectra of Eu~(3+) may be used to study the structure ofcompounds.The band shift of Nd~(3+) in its absorption spectra,the red-to-orangeintensity ratio of the Eu~(3+) emission(~5D_0→~7F_2)/(~5D_0→~7F_1)and the yellow-to-blue intensity ratio of the Dy~(3+) emission~4F_(9/2→~6H_(13/2)/~4F(9/2→~6H(15/2)intheir fluorescence spectra may be used to study the degree of covalency of theLn-O bond and its relation with the electronegativity of M in Ln-O-M.

本文介绍了利用 Eu~(3+)的荧光光谱研究化合物的结构;利用 Nd~(3+)的吸收光谱的谱带位移和 Eu~(3+)的荧光光谱的红橙发射强度比(~5D_0→~7F_2)/(~5D_0→~7F_1)和 Dy~(3+)的黄兰比~4F_(9/2→~6H_(13/2)/~4F_(9/2→~6H_(15/2),了解Ln—O—M中 Ln—O 化学键的共价程度以及 M 的电负性对共价程度的关系;利用吸收光谱、荧光光谱和磁化率研究稀土的价态以及利用磁化率研究化合物的组成。

Based on the changes in the spectrum characters of guest molecules producedthrough inclusion complex formation with cyclodextrins, we have carried out two aspects of investigation:First, the mechanisms for the host-guest recognition reactions have been studied, such as the interactions between 3-CD and curcumin, the main constituent of the rhizomes of the plant Curcuma longa, the recognition of p-CD towards rubidate, the effective component of the Chinese traditional medicine madder, and the reactions of p-CD towards the antileprotic drug dapsone and the antiinflammatory drug nabumetone: The formation of supramolecular complex between P-CD and guest molecule has been discussed and verified in virtue of multitudinous means such asultraviolet-visible absorption, fluorescence emission, infrared spectrogram and so on. The influence of addition of linear alcohols on the supramolecular system has been studied and the reason why the noncovalent interactions in the three-component system could result in a decrease in the apparent association constant of the inclusion complex has been revealed.

本论文基于环糊精对被包结客体光谱性质的改变,开展了两大方面的研究:β-环糊精对姜黄属植物根茎主要成分—姜黄素、中药茜草有效成分—茜草双酯、抗麻风药物氨苯砜及抗炎药物萘丁美酮的主-客体识别反应机制研究:借助超分子包合物的紫外吸收光谱、荧光光谱或红外吸收光谱等手段,通过多种方法探讨并验证了超分子包合物的形成;研究了直链醇的加入对超分子体系的影响,揭示了三元体系中非共价相互作用导致超分子包合物表观结合常数降低的原因:对超分子包结反应进行了热动力学研究,探讨了各热动力学参数的变化趋势并从熵焓互补的角度考察了超分子包结过程;通过荧光猝灭实验进一步揭示了水相中β-环糊精增敏客体荧光的本质原因,从而为超分子化学提供新的理论和研究方法。

Nanocrystalline silion have many difference from bulk silicon, such as structure, the capability of optics and photoelectricity. It shows high potential on light-emitting devices, photodetector, optoelectronic devices and sensor. Si-rich silica was deposited by RF magnetron sputtering and the film dopped with aluminium is deposited too.

本文采用射频磁控溅射方法制备富硅二氧化硅薄膜,并在此基础上掺入单质铝,经高温退火,自组装生长纳米硅颗粒,并对薄膜进行了拉曼散射、X射线衍射、扫描电镜、傅立叶红外吸收光谱和光电子能谱的测定,对吸收光谱也进行分析。

Thermal analysis showed that all of the four polymers have high thermal stability with T_g higher than 200 °C. The absorption spectra of PDOPPF and PDAOPF-PPF showed fine peaks resulting from pyrenes at C9 of the fluorene moiety and PDOFP and PDAOPF-P showed red-shift compared to polyflurenes.

同聚(9,9-二辛基芴)的光谱的相比,聚合物PDOPPF和PDAOPF-PPF的吸收光谱显示出一些精细吸收峰,聚合物PDOFP和PDAOPF-P的吸收光谱有较大红移,因而前两者的固态光谱发射蓝光,而后两者的则为蓝绿光,四个聚合物的薄膜即使经过在氮气气氛中150℃退火24h后光谱也没有明显的变化。

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On closer examination, though, this is not a vote for multilateralism but just the opposite.

仔细审视后我们发现,这并非是对多边主义投出的赞成票,而是恰好相反。

Uncovering their weak spots, so I can defeat them.

揭露出他们的弱点,这样我就可以打败他们了。

Methyl bromides, in C_(3v) symmetry, have been extensively studied at their first absorption A-band because the behavior of these molecules can be used as a prototype for depicting numerous types of photodissociations in a variety of polyatomic molecules.

例如,有很多研究报道了C_(3v)对称的溴甲烷等分子在第一吸收带的光解,这是因为其光解行为可以作为理解其它多原子分光解的原型。