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催化剂

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While the adsorptions of l-propanol and 1-Br-propane at 100 癈 give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 癈 shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150 癈, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO2 catalyst.

原位IR光谱实验结果表明:200℃时丙烷/O_2混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似,均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰;溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基,异丙氧基主要转化为丙烯和丙酮,丙烯进一步转化为丙烯醛;溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基,正丙氧基主要转化为丙醛;丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基,升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。

Therefrom; heating said waste edible oil from which solid materials have been removed to a predetermined temperature, thereby removing moisture and materials of odor contained in the waste edible oil therefrom by evaporation; dissolving in alcohol a catalyst containing at least one type or more types of alkaline material selected from a group comprised of at least potassium hydroxide, potassium carbonate and potassium alcoholate, thereby preparing an alcoholic solution containing the catalyst; mixing said waste edible oil from which said solid materials, moisture and materials of odor have been removed with said alcoholic solution containing the catalyst and stirring the waste edible oil and alcoholic solution, thereby accelerating a catalytic reaction between the waste edible oil and the alcohol and obtaining a reaction product between the waste edible oil and the alcohol; separating said reaction product into a light solution and a heavy solution; mixing the light solution obtained in the separation step with a solid absorbent, thereby impurities such as residual catalyst, odor material, moisture contained in the light solution being absorbed by the solid absorbent; and separating and removing said solid absorbent from a mixture of the solid absorbent having absorbed the impurities and the light solution.

完成前述对象,根据这项发明的特点是获得的柴油燃油从废油脂透过几个步骤:去除固体材料包含在一个废油脂倾倒,从餐厅,食品厂,民政等因此;暖气说,废油脂从哪个固体材料已被调离到一个预定的温度,从而消除了水分和材料的气味,载于废油脂因此由蒸发;溶解在酒精的催化剂至少含有一种或更多类型的碱性材料选定由一组组成的至少氢氧化钾,碳酸钾和钾,醇,从而准备一醇溶液中含有催化剂;混合说,废油脂从哪个说,固体材料,含水率和材料的气味已被剔除与说,酒精性解决方案载有催化剂和搅拌废物食用油及含酒精的解决办法,从而加速催化反应之间的废油脂及酒精和获得反应产物之间的废油脂及酒精;分开说,反应产物成为一个轻型的解决方案和沉重的解决方案;混合轻解决方案,获得了在分离一步一个坚实的吸水性,从而杂质,如残留的催化剂,气味的物质,水分,载于轻解决方案,被吸收的固体吸收剂;分离和消除说,固体吸附剂从混合物对固体吸收剂吸收了杂质和轻便的解决办法。

To study the performance of inorganic composite catalyst for the SPC oxidation of p-methyl anisole, Cu2-Co2-KBr is used as catalyst of sodium percarbonate oxidation for p-methyl anisole synthesized by paracresol methylating. Effect of reaction conditions, such as the factors of catalyst composition, catalyst quantity, solvent, reaction temperature and time on oxidation of p-methyl anisole, is investigated.

研究了无机复合催化剂催化SPC氧化对甲基苯甲醚的反应性能:以Cu2-Co2-KBr为催化剂,利用过碳酸钠氧化对甲酚甲基化产物对甲基苯甲醚,系统研究了催化剂组成比例、催化剂用量、溶剂、反应温度、反应时间等因素对反应的影响。

Thus, the synthesis of anisole by O-methylation of phenol with DMC had been extensively investigated using phase transfer catalysts, organic alkaline catalysts or zeolites catalysts.

相转移催化剂,有机碱类催化剂以及分子筛催化剂是DMC甲基化苯酚合成苯甲醚这一反应的高效催化剂,研究的比较广泛和深入。

The effects of catalyst, catalyst promoter, ratio and amount of catalyst and catalyst promoter, temperature, reaction time and pressure on the selectivity and yield of benzaldehyde have been investigated.

重点考察了催化剂种类、助催化剂种类、催化剂和助催化剂的配比和用量、反应温度、反应时间和反应压强等因素对苯甲醛的选择性和收率的影响。

Vapor makes the activity and selectivity of the catalyst decrease a great deal yet this disvalue is reversible; When the elemental sulfur and vapor exist simultaneity in the system, it might generate H〓S and S on 〓 catalyst since the anti-Claus reaction, but this phenomena is not observed on CoS〓-TiO〓 catalyst showing that sulfides could check the anti-Claus reaction.

对硫化物催化剂CoS〓-TiO〓来说,助剂La和Ce的引入对CoS〓-TiO〓催化剂的氧化还原性能有一定影响,硫化物催化剂平均粒径要小,但助剂并未改变催化剂的电子结构,对于氨分解克劳斯反应的活性改变不大明显。

Advances in the catalysts for synthesis of ethylene glycol ethers via etherification were reviewed, and some suggestion were made for development of new catalysts.

介绍了醚化反应法合成乙二醇醚催化剂的研究进展,并对催化剂的开发提出了建议。在进行环氧乙烷与醇的醚化反应时,使用传统的碱性催化剂,反应容易形成多醚;使用传统的酸性催化剂,反应容易形成有毒物质二烷。

The effect of different reaction conditions,such as catalyst concentration,molar ratio of reactants,reaction temperature,reaction time,on the coupling reaction of trioxane and methyl formate synthesizing methyl glycolate and methyl methoxy acetate using sulfuric acid as catalyst has been studied.Through the analysis for the yield of products and system pressure,and comparison with other different acidity catalysts,we considered that the activation of formaldehyde was the control step of reaction rate to the...

以硫酸为催化剂,研究了三聚甲醛与甲酸甲酯偶联合成乙醇酸甲酯和甲氧基乙酸甲酯的反应中,催化剂浓度、原料配比、反应温度、反应时间等条件对反应过程的影响,通过对产物收率和系统压力变化的分析,并结合与其它不同酸强度催化剂的对比,得到甲醛的活化是偶联反应的速率控制步骤,催化剂的酸强度决定其对甲醛的活化能力,是影响偶联反应的主要因素。

On the NiO/SiO〓 catalyst prepared by IM, the main hydrogenation product of MA was SA, the activity and selectivity were almost no relation with the nickel content and nickel species 3. Summarizing the characterization and activity evaluation of the catalysts, we concluded: On nickel based catalyst, when NiO was crystallite, and the Ni〓 that was prepared by reducing, hydrogenation of the MA could lead to SA but not to γ-BL; when NiO was cluster and had a properly interaction with the support, the Ni〓 prepared by reducing, could hydrogenate MA to SA then to γ-BL. When NiO cluster and crystallite were both existed on the catalyst, the hydrogenation products were mixture of SA and γ-BL, and the amounts of SA and γ-BL were related with the ratio of cluster and crystallite.

综合催化剂的表征和活性评价得出:当镍基催化剂上氧化镍以结晶态存在,经氢还原后的零价镍可使顺丁烯二酸酐加氢得到丁二酸酐,丁二酸酐难以进一步加氢为γ-丁内酯;当镍基催化剂上氧化镍以簇团形式存在,与载体之间有适当的相互作用时,经氢还原后的零价镍可使顺丁烯二酸酐加氢得到的丁二酸酐进一步加氢为γ-丁内酯;若催化剂上氧化镍既有结晶态又有簇团形式时,随二者含量比例不同而得到丁二酸酐和γ-丁内酯的混合物。

Multi-hydrogen-groups on the catalyst make deep hydrogenation or hydrogenolysis take place. Adding promoters in the copper-substrate and zinc-substrate catalysts helps to formatting the multi-hydrogen-groups on the surface of them.

通过助催化剂的添加,在Cu基催化剂和Zn基催化剂上产生多氢吸附集团,可以改善催化剂深度加氢或氢解反应的性能,以有效地调控深度加氢反应。

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