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Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.

实验结果还表明,在TBHP或O_2/TEMPO存在下,各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮,其中,配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛,而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差;在TBHP存在下,配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮,但对各类其它伯醇选择氧化的性能相对较差。

推荐网络例句

On closer examination, though, this is not a vote for multilateralism but just the opposite.

仔细审视后我们发现,这并非是对多边主义投出的赞成票,而是恰好相反。

Uncovering their weak spots, so I can defeat them.

揭露出他们的弱点,这样我就可以打败他们了。

Methyl bromides, in C_(3v) symmetry, have been extensively studied at their first absorption A-band because the behavior of these molecules can be used as a prototype for depicting numerous types of photodissociations in a variety of polyatomic molecules.

例如,有很多研究报道了C_(3v)对称的溴甲烷等分子在第一吸收带的光解,这是因为其光解行为可以作为理解其它多原子分光解的原型。