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三乙酰胺

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Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料,在氢化钠存在下反应,合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应,用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2,4-咪唑啉-二酮、1,2,4-三嗪-3-酮、喹喔啉等含氮杂环化合物。

Study on an efficient process for the preparation of trifloxystrobin starting from 2-methylacetophenone bypartial oxidation,esterification,reaction with methoxyamine,bromization and condensation with 3'- acetophenone oxime.

以邻甲基苯乙酮为原料,经过高锰酸钾的碱性氧化,甲醇酯化,再与甲氧基胺盐酸盐肟化后,用N-溴丁二酰亚胺溴化,最后和间三氟甲基苯乙酮肟缩合得到目标产物肟菌酯。

In this thesis,three copolymerization systems have been investigated in detail.They are α-ethylacrylic acid/maleimide,α- acrylic acid/maleimide and monomethyl itaconate/maleimide,respectively.

本文对α-乙基丙烯酸/马来酰亚胺、α-正丙基丙烯酸/马来酰亚胺和衣康酸单甲酯/马来酰亚胺三种新的共聚体系进行了详细地研究,并对合成共聚物的生理活性进行了初步探讨,实现了α-正丙基丙烯酸乙酯/马来酰亚胺体系的可控共聚反应。

Two oligosaccharides, a hexasaccharide fragment of group E Streptococcus polysaccharide and a tetrasaccharide repeating unit of E. coli O7: K98: H6, consisting of α-(1→2)-and α-(1→3)-linked rhamnose backbones were synthesized in a regio-and-stereoselective manner.

以三氯乙酰亚胺酯为供体,不保护或部分保护的糖为受体,成功地合成了以α-(1→2)-和-α(1→3)-交替连接的鼠李糖为主链的GroupE Streptococcus六糖和E.coli O7:K98:H6四糖。

All of the tripodal schiff base ligands and their complexes were characterized.

以三乙醇胺、巯基苯胺、巯基乙胺为初始原料,设计合成了六个三脚架结构的化合物,其合成路线如下:三乙醇胺与氯化亚砜反应得到三(2-氯乙基)胺(1),然后与巯基苯胺或巯基乙胺在碱性条件下反应生成三脚架结构的三{[2-(2-氨基苯基)硫代]乙基}胺(2)或三{[2-(2-氨基乙基)硫代]乙基}胺(3),然后再与水杨醛、2-甲酰基-8-羟基喹啉(8)、2-甲酰基-8-苄氧基喹啉(7)反应得到六种新型的含硫西佛碱化合

In this thesis, the design, synthesis and application of substituted 1,8-naphthalimides and napthopyrones conjugated with uridine, substituted 1,3,5-triazine, 1,2-dibromoethane, ethyl bromoacetate have been studied.

本论文研究了取代l,8-萘酰亚胺和萘并吡喃酮与尿苷、取代均三嗪、二溴乙烷、溴乙酸乙酯偶合和双l,8-萘酰亚胺之间偶合的设计、合成及应用。

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