查询词典 transition complex

A simple estimation method for molar Gibbs free energy and enthalpy of formation for complex oxysalt minerals is proposed. Complex oxysalt minerals are divided into complex oxysalt minerals with water and complex oxysalt minerals without water. Complex oxysalt minerals without water can be considered as the composite of acidic oxides and alkaline oxides, so their molar Gibbs free energy or molar enthalpy of formation can be calculated by the summation of molar Gibbs free energy or molar enthalpy of formation of the acidic oxides and alkaline oxides which are combined into the complex compounds.

提出了一种复杂含氧盐矿物的摩尔生成Gibbs自由能和摩尔生成焓的简单估算方法，并把复杂含氧盐矿物分为不含水复杂含氧盐矿物和含水复杂含氧盐矿物，不含水复杂含氧盐矿物可以看作是酸性氧化物和碱性氧化物组成的物质，其摩尔生成Gibbs自由能或摩尔生成焓都可以看作是酸性氧化物和碱性氧化物复合成的化合物摩尔生成Gibbs自由能或摩尔生成焓之和。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

1While launching machine Dai soon suddenly accelerate, if the transition spray bore to stop, especially the vacuum type carburetor appear a transition badly, hybrid once annoy sparse but clean a carburetor transition after turning off by oneself the bore then can smoothly start to launch machine behind, after start in response to steady mildly accelerate, as far as possible avoid nasty acceleration, the factitiousness result in transition bad.

当发动机怠速时突然加速，若过渡喷孔堵塞，特别是真空式化油器出现过渡性不良，混合气过稀而自行熄火后，清洗化油器过渡孔后便可顺利启动发动机，启动后应平稳柔和地加速，尽量避免急加速，人为造成过渡性不良。

The four fluorescence peaks are generated separately by the combined actions of the methyl parathion and the acetone. In methyl parathion molecule, there are the transition of n electrons in nitryl, the transition of π electronic structure formed by the oxygen atom and the benzene ring and the transition of n electrons in P=O group. In acetone molecule, there is the transition of n electrons in C=O group.

分析得到，四处荧光峰分别是溶剂丙酮分子中C=O上的n电子跃迁、硝基上的n电子跃迁、甲基对硫磷分子中氧原子与苯环形成的大共轭π电子结构跃迁以及P=S上的n电子跃迁共同作用产生。

There are some main conclusions of the article. 1.Enterprise inclines to decision-making according to its profit, so constituting and anglicizing green institutions from the view of enterprise will advantage their microcosmic base, then can improve their adaptive abilities and green effects. 2.Government has powers and some potential advantages, but it inheres of some defects, so it should not become the principle parter but the urger, waiter and superintendent of the green transition process. 3.According to social cost and the situation of the social environment, we should adopt a gradual transition stratagem on the whole in the process. 4.We can classify the enterprise green transition into three kinds by the dominant factor in the push-drag-model, push-dominant mode, drag-dominant mode and friction-tight state. Different green policies should giveto different transition mode in odor to getting a good green effect. 5.The costs of enterprise have three levels by the point of view of sustainable development, apparent cost in generation, dormant cost in generation and intergenerational cost. The priority of green system should adjust to the level to which the benefits of the enterprise amount.

本文得出的主要结论有：1、企业具有相机决策的倾向，从企业的角度分析和制定绿色制度可以使政策具有较强的微观基础，进而可以提高它的适应性和绿色效果。2、政府具有暴力潜能，也具有固有的不足，在绿色制度变迁的过程中应该且只能是倡导者、服务者、监督与维护者，而不是主体参与者。3、综合考虑社会成本与社会环境，渐进式的总体推进模式是我国目前较为现实的选择。4、本文建立了企业绿色变迁推拉模型，并根据促使企业绿色转变的主导因素的不同，将企业绿色变迁的模式分为拉力主导型、推力主导型与摩擦状态三种类型，不同的类型应采取不同的绿色政策才能收到良好的绿色效果。5、从可持续发展的角度可以将企业的生产成本分为代内隐性成本、代内显性成本和代际成本三个层次，对于收益处于不同层次的企业，绿色制度的侧重点应有所不同。6、根据企业与政府在绿色制度变迁过程中所起的作用的不同可以将绿色制度变迁分为强制供给型、政府导向型、需求诱导型三种模式。

It was found from structure-electrochemical studies of hemoglobin that (1) electroreduction induces the T→R transition with chirality transition and umbrella conversed effect;(2) electric field induces the secondary structural transition between two α helices, which is smilar to the denaturalization of the protein;(3) The electrochemical reaction mechanism of EC including T→R transition and parameters have also been obtained.

在血红蛋白的结构-电化学研究中发现：（1）电化学还原诱导血红蛋白的T→R构型转化，手性转化的伞翻转效应；（2）电场诱导血红蛋白的两种α螺旋二级结构间的转化，属于电场诱导血红蛋白的部分变性；（3）获得血红蛋白电化学还原的包括R→T转换的EC机理和参数

The average percent value of G C (49.3%) was less than that of A T (50.7%), there was a bias of the content of G, T in the third codon; The number of transition G-A and T-C were 22, 15 respectively, which were higher than that of transition A-G and C-T, the number of tranversion C-A, T-G is 2 respectively, and other tranversion patterns didnt occur; the probability of transition was higher than that of tranversion , Ts/Tv = 9.5-19, there was the highest number of transition in the third codon. The gamma parameter a of the lst,nd and 3rd codon positions were 0.00572,0.01237 and 1.05239 respectively, they showed that there was adifferent substitution rate at different codon position. Frequences of synonymous codon usage were relatively biased. The average rates of synonymous and nonsynonymous substitution were 0.0787, 0.0011 respectively, there was a significant difference between dS and dN (Z = 4.713, p.01), and the low ratio( CD = 0.0284 .3) of dN/dS ratio impled that there were selective constraints against the nonsynonymous sites in cyt-b gene, The distribution of nonsynonymous codon substitution pattern related to Grantharm distance indicated that the purified selection at 2nd codon positions was more intensive than that at 1st codon positions. The phylogenetic trees supported the view of the double origin of Chinese goose, which means that domestic Chinese goose was derived from Anser cygnoides and domestic European goose, and Yili was derived from Anser anser.

碱基含量分析可知，序列的G C含量(49.3％)＜A T含量(50.7％)，密码子第三位点的G、T含量都有较强的偏倚性；序列间G→A和T→C的转换数(22次和15次)高于A→G和C→T的转换数(10次和9次)，C→A、T→G颠换数均为2次，其余颠换模式均未发生；转换数明显高于颠换数，Ts／Tv=9.5～19，密码子第三位点的转换数最高，呈现了相当强烈的转换偏倚性；密码子第一、二和三位点的gamma分布参数α值分别为0.00572、0.01237和1.05239，表明密码子第一位点的替换速率变异最大，第二位点次之，第三位点的替换速率变异相对较小；编码同一氨基酸的同义密码子并非随机使用，表现出一定程度的使用偏倚性；同义替换速率和非同义替换速率分别为0.0787和0.0011，dS与dN值间的差异极显著(Z=4.713，p＜0.01)，而ω=0.0284，明显小于0.3，表明雁属鹅细胞色素b基因序列经历了中度净化选择作用；单步非同义替换(Sing-step nonsymonymous codon substitution，SSNCS)分布模式与Grantharm距离之间的关系说明密码子的三个位点所受的净化选择强度不同；构建的最大简约树与邻接树拓扑结构一致，支持中国家鹅的双起源学说，即除伊犁鹅外的其它中国鹅品种起源于鸿雁，伊犁鹅和欧洲的郎德鹅、莱茵鹅起源于灰雁。

This paper establishes cubic spline function, analyzes subsection curve function and curve slope and curvature, at last decides to place the curve especial points which can be obtain easement curve length and other line parameters, such as the ZH point (end of line and beginning of transition curve), the HY point (end of transition curve and beginning of circular curve), the QZ point, the YH point (end of circular curve and beginning of transition curve), the HZ point (end of transition curve and beginning of line).

针对公路平面线形的8种组合类型，其线形元素特征则由最基本的直线、圆曲线、缓和曲线组成的特点，解析三次样条函数模型，得分段曲线函数、曲线斜率、曲率，从而确定曲线特征点（直缓ZH点、缓圆HY点、曲中QZ点、圆缓YH点、缓直HZ点）位置，进而得到曲线缓和曲线长度及其他线形参数。

The catalyst is composed of at least one transition metal or transition metal alloy supported on the rare-earth metal oxide, the content of each component: transition metal or transition metal alloy 0.1-99%, and rare-earth metal oxide

催化剂由至少一种过渡金属或过渡金属合金担载在稀土金属氧化物上组成，各组分含量为过渡金属或过渡金属合金0.1～90.0％，稀土金属氧化物10.0～99.9％。

Molecular Distillation is a kind of high vacuum distillation method, which is suitable for the separation of high boiling, heat sensitivity and viscidity products.

分子蒸馏技术是一种在高真空条件下进行的连续蒸馏过程，适合于分离高沸点、热敏性及具有生物活性的混合物。

They are to the Noughties what yuppies were to the Eighties .

那在六十年代是时髦的，但在八十年代肯定是过时了