查询词典 tempo

A selective and mild PS-DIB/ionic-liquid immobilized TEMPO catalytic oxidation procedure of alcohols to the corresponding aldehydes and ketones in ionic liquid BF4 at room temperature was developed. The oxidant PS-DIB was prepared via Iodation and acetylation of polystyrene resin. For the preparation of the ionic-liquid immobilized TEMPO catalyst, 4-(2,2,6,6-Tetramethyl-1-oxyl-4-piperidoxyl)butyl bromide was first synthesized from 2,2,6,6-tetramethyl-piperidin-4-ol-N-oxyl and 1,4-dibromobutane.

将聚苯乙烯树脂先碘化再乙酰基化，制得了负载型二乙酰氧碘苯(diacetoxyiodo polystyrene，PS-DIB)作为氧化剂。2，2，6，6-四甲基-N-氧自由基哌啶醇(2，2，6，6-tetramethyl-piperidin-4-ol-N-oxyl，TEMPO)与1，4-二溴丁烷反应生成4-溴丁氧基-2，2，6，6-四甲基-哌啶-1-氧化物，再与N-甲基咪唑发生季铵化反应，生成的溴化季铵盐与四氟硼酸钠进行离子交换制得氟硼酸型2，2，6，6-四甲基-N-氧自由基哌啶负载离子液体TEMPO-IL。

Between 1984-1992 he worked with Tempo newsmagazine banned by the government in 1994

在1984年到1992年间，他曾为 Tempo 新闻杂志社工作（该社于1994年被政府查封）。

At the same time, the enthalpy change of 212 kJ/mol for Tempo trapping methyl radical, namely O-〓 bond dissociation energy has been also obtained. This value is close to that of nitrous acid ester and far less than that of nitric acid ester. It is probably due to the relatively strong electron withdrawing capability of nitryl group.

同时我们还测得了甲基自由基与Tempo的反应的焓变，即O—〓键离解能为212 kJ／mol，它接近于亚硝酸甲酯中C—O键的离解能，而小于硝酸甲酯中的键离解能，这可能和硝酸根的吸电子能力较大有关。

It replaced the Ford Sierra in Europe, and the Ford Telstar in Asia and other markets, while Contour and Mystique replaced the Ford Tempo and Mercury Topaz in North America.

蒙迪欧在欧洲代替了Sierra品牌，在亚洲以及其他市场代替了Ford Telstar 品牌，而Contour 和Mystique 在北美取代了福特Tempo 和 Mercury Topaz 。

Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.

实验结果还表明，在TBHP或O_2/TEMPO存在下，各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮，其中，配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛，而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差；在TBHP存在下，配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮，但对各类其它伯醇选择氧化的性能相对较差。

The amphiphilic block copolymers are synthesized using TEMPO controlled polymerization method with tertrabutylammonium styrenesulfonate and divinyl benzene as monomers for each block.

此双亲性共聚高分子乃利用TEMPO之方式进行活性聚合，将磺酸钠盐聚苯乙烯单体转换成疏水性单体，第二链段选择DVB作为具备交联之单体。

Many engineers set predelay values that are related to the tempo.

许多工程师把设置Predelay和Tempo关联起来。

Ford and Chrysler are not only replacing their long-in-the-tooth Tempo and Acclaims.

福特和克莱斯勒不仅是光替换他们牙老赤黄的 Tempo 和 Acclaims 两款车型。

In the concentration rage used the rete constant k is directly proportional to the concentration of TEMPO while is proportional to the concentration of NaBr in a relatively lower range and tends to level off at higher concentration.

在本研究所用的TEMPO浓度范围内，氧化反应这率与TEMPO的浓度成正比。在较低浓度时，氧化反应速率与NaBr用量也成正比，但浓度较大时，氧化反应这率基本不随NaBr浓度增大而增大。

In the concentration rage used the rete constant k is directly proportional to the concentration of TEMPO while is proportional to the concentration of NaBr in a relatively lower range and tends to level off at higher concentration.

在本研究所用的TEMPO浓度范围內，氧化反应这率与TEMPO的浓度成正比。在较低浓度时，氧化反应速率与NaBr用量也成正比，但浓度较大时，氧化反应这率基本不隨NaBr浓度增大而增大。

But in the course of internationalization, they meet with misunderstanding and puzzlement.

许多企业已经意识到了这一点，但在国际化的进程中，仍存在一些误区与困惑。

Inorder toaccomplish this goal as quickly as possible, we'll beteamingup with anexperienced group of modelers, skinners, and animatorswhosenames willbe announced in the coming weeks.

为了尽快实现这个目标，我们在未来数周内将公布与一些有经验的模型、皮肤、动画制作小组合作。