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Since there exists some disadvantages such as poor mechanic properties and much higher burning rate pressure exponents (?1) in the fundamental formulations, this work is devoted to the improvements of combustion characteristics and mechanic properties of LOVA propellants. The effects of the crystal shape, size and contents of nitroamine particles, the types of binder, plasticizer and surface-active agents and the contents of NC on combustion performance are studied by closed bomb tests. In the mechanic properties tests, the effects of the types of binders, plasticizers and solid fillers, the interaction between binders and solid fillers and technological procedures on propellant mechanic properties are researched.

针对基础配方具有燃速压力指数远大于1、力学性能差等特点,采用密闭爆发器等试验手段,研究了诸如硝胺粒径、硝胺晶体形状、硝胺含量、粘结剂、增塑剂、硝化棉含量及表面活性剂等因素对燃烧性能的影响;采用抗沖、抗压静态试验方法,对粘结剂、增塑剂、固体填料、粘结剂与固体填料之间的相互作用及工艺条件与力学性能之间的关系进行了研究,提出了改善低易损性发射药燃烧性能和力学性能的技术途径。

Subtitle D of the Act is dedicated to nonhazardous solid waste requirements, while Subtitle C focuses on hazardous solid waste.

法案附件 D 致力于无害固体垃圾要求,附件 C 集中于危害固体垃圾。

Performing the process in the presence of the organoboron or organoaluminum-treated solid surprisingly leads to an increased activity compared to polymerization processes performed without the treated solid.

与不使用处理过的固体进行的聚合方法相比,在有机硼或有机铝处理的固体存在下进行所述方法令人惊奇地使活性增加。

A computer-aided local transient flow property measuring system was developed using a high speed CCD camera coupled with optical fibers in order to study the Gas-liquid-solid three-phase jet loop reactors. SnO2 crystal films were orientally deposited on the alkoxysilane molecule-coated hydroxyl glass substrates so as to prepare surface-marked particles as the tracers. An image analysis system was established to identify different phases. Stroboscopic photography was utilized to extend the measure range. The developed measuring and analysis system was capable of determining accurately the local transient flow property in a G-L-S jet loop reactor. Based on the above system, local transient flow properties of gas, liquid, and solid phase were measured and studied the influences of fluid property, operation and configuration parameters on the reactor.

中文摘要:以气液固三相喷射环流反应器为研究对象,将高速CCD和光纤束耦合制成局部瞬态流动特性微机数据采集及图象处理系统,利用MPS硅烷分子在带有羟基的玻璃基底上的自组装引导SnO2晶态膜层在功能化表面上进行沉积,以获得表面标记的示踪粒子,解决图象处理技术与相的识别的问题,利用频闪技术拓展了测量上限,得到可以准确测定气液固三相喷射环流反应器中局部瞬态流动特性的测试系统;采用上述测试技术进行喷射环流反应器中局部气相、液相与固相瞬态流动特性的实验研究,并考察物性参数、操作参数与结构参数的影响规律。

We found out one kind of new orange-red long afterglow material La2O2S: Eu3+, Mg, Zr.2 In the phosphor Gd2O2S, Mg, Ti which was prepared by high-temperature solid-state method, the orange afterglow phenomenon can be seen after illuminated with UV light.3 Using the high-temperature solid-state method, Gadolinium oxysulfide phosphors doped with rare earth ions were synthesized. We can observe the red or orange phosphorescence in Gd2O2S doped with Eu3+, Sm3+, Tm3+, Yb3+, Dy3+, Er3+, Nd3+or Ho3+. This is a new result of the long afterglow phosphors research.4 Using the microwave radiation method, the new Sm3+ doped gadolinium oxysulfide phosphor, which has the orange-red long afterglow emission after illuminated with UV light or visible light, was synthesized for the first time.5 In fluorescent materials YOX doped with europium ions, the long afterglow phenomenon wasnt observed but the blue luminescence of Eu2+ and red luminescence of Eu3+ are simultaneously examined. This is a new result of the valence stability and change of Eu2+ in yttrium oxyhalide .We systematically studied the effects of the host, addition agents and reaction atmosphere on the valence change and fluorescence property of europium ions.

经过系统的研究总结得到以下的结论与成果: 1采用高温固相反应法合成了一系列稀土离子掺杂的硫氧化镧发光粉,发现了该体系中Eu~(3+)的长余辉发光,从而得到一种迄今未见文献报道的红色长余辉发光材料:La_2O_2S:Eu~(3+),Mg,Zr; 2在Gd_2O_2S,Mg,Ti磷光粉中观察到橙色的长余辉发光现象; 3采用高温固相反应法合成了一系列稀土离子掺杂的硫氧化钆磷光粉,在掺杂Eu~(3+)、Sm~(3+)、Tm~(3+)、Yb~(3+)、Dy~(3+)、Er~(3+)、Nd~(3+)、Ho~(3+)的Gd_2O_2S中观察到红色和橙色长余辉发光; 4首次采用微波法合成了Gd_2O_2S:Sm~(3+),Mg,Ti磷光粉,该磷光粉经紫外或可见光激发后呈现明显的橙红色长余辉发光; 5在YOX中同时观察到Eu~(2+)和Eu~(3+)的发射,系统研究了基质、添加剂及反应气氛对Eu价态和发光的影响。

Both of phase proportions and compositions of mineral solid solutions could be optionally approximated, based upon the principle of mineral crystal chemistry, the law of mineral paragenetic assemblage, and the priority of partitioning of minor components into the solid solution phases.

优化计算结果的理论依据主要有矿物晶体化学原理、矿物共生组合规律和次要组分分配的固溶体矿物相优先原则。

The electric conductivity of solid polyiodides increases largely as the aggrandizement of polyiodide anions"polymerization degree. The solid polyiodides have excellent sterilizing effects and the effect of tetra-n-butyl ammonium undecaiodide is the best of them, and the sterilizing effects increase as the aggrandizement of polyiodide anions" polymerization degree. The sterilizing effects of resinic polyiodides increase as the aggrandizement of polyiodide anions polymerization degree, the heptaiodide resinic polyiodide has better sterilizing effects than the triiodide and pentaiodide.

固体高聚碘系列化合物的电导率随着高聚碘阴离子聚合度的增加而增加,并且增幅较大;固体高聚碘对常见细菌均具有很好的杀灭作用,并且随着高聚碘阴离子聚合度的增加,杀菌能力也随着增强,其中正四丁基十一碘化铵杀菌剂的效果最佳;树脂高聚碘随着高聚碘阴离子聚合度的增加,杀菌能力增强,碘七树脂高聚碘的杀菌效果要明显好于碘三树脂和碘五树脂高聚碘。

In solid phase process, the polyiodides, which include triiodide, pentaiodide, heptaiodide, nonaiodide and undecaiodide tetra-n-butyl ammonium iodide, tetrabutyl ammonium bromide and tetramethyl ammonium iodide poly-compounds, were synthesized by the low-heat solid phase reaction between iodine and tetra-n-butyl ammonium iodide, tetrabutyl ammonium bromide or tetramethyl ammonium iodide; In complexation process, solution polyiodides were synthesized by complexing action of different agents; In resinifying process, triiodide, pentaiodide, heptaiodide resinic polyiodides were synthesized by ion-exchange when the strong basicity styrene anion exchange resin, potassium iodide and iodine were used as raw materials.

固相法是用正四丁基碘化铵、四丁基溴化铵或四甲基碘化铵分别与碘作用,通过低热固相反应,合成出碘三、碘五、碘七、碘九和碘十一形式的正四丁基碘化铵、四丁基溴化铵或四甲基碘化铵的系列高聚碘化合物;在络合法合成溶液高聚碘的实验中,选用几种络合剂通过络合作用首次合成了溶液高聚碘;树脂法合成高聚碘的实验是采用强碱性苯乙烯系阴离子交换树脂、碘化钾和碘为原料,通过离子交换,合成了碘三、碘五和碘七形式的树脂高聚碘。

Two solid complexes of terbium with phenylacetic acid(L1) and phenyl-hydroxylacetic acid(L2) were synthesized by solid state reaction at low temperature,and the complexes were characterized by chemical analysis.

以两种不同结构的羧酸苯乙酸和苯基羟基乙酸与氯化铽为原料,采用低温固相反应合成了两种羧酸铽配合物。

Four series and sixteen solid complexes of rare earth chloride with 1-naphthoic acid (L_1),benzoic acid (L_2),phenylacetic acid (L_3) and Mandelic acid (L_4) have been synthesized by method of solid state reaction at low temperature,and then these complexes were characterized by chemical analysis methods.

本文采用低温固相合成法,以稀土氯化物、1—萘甲酸(HL_1)、苯甲酸(HL_2)、苯乙酸(HL_3)、苯羟乙酸(HL_4)为原料,以六次甲基四胺为质子受体,合成并表征了四个系列十六种固态配合物。

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