查询词典 sapo

The results showed that the TEAOH possessed stronger framework-directing function during the synthesis process of SAPO-34 molecular sieve, and took up more electronegative framework positions while the morpholine mainly filled the micropore system of SAPO-34 molecular sieve.

结果表明，TEAOH在导向生成SAPO-34分子筛骨架过程中表现活跃，占据了较多的平衡骨架负电荷的位置，而吗啉主要起到填充分子筛孔道的作用。

The invention relates to a molecular sieve, in particular to an aluminum phosphosilicate SAPO-34 type molecular sieve and the preparation thereof, wherein the SAPO-34 type molecular sieve contains zirconium ion as a modified metallic element.

本发明涉及一种分子筛，具体涉及磷硅铝酸盐SAPO-34型分子筛及其制备方法，在SAPO-34型分子筛中含有作为改性金属元素的锆离子。

The lattice of SAPO molecular sieves is not rigid after template removal and are very sensitive to adsorbates even at room temperature.

小晶粒的SAPO-34分子筛和金属修饰的SAPO-34分子筛的稳定性降低，MTH反应加剧了分子筛脱硅。

The invention relates to a synthesis method for an SAPO molecular sieve, which mainly solves the problems of low crystallinity and poorer performance of the SAPO molecular sieve in the prior art.

本发明涉及一种SAPO分子筛的合成方法，主要解决现有技术中SAPO分子筛结晶度低、性能较差的问题。

The structures of various SAPO and their suitable catalytic reaction systems were described in this paper.The application possibilities of SAPO as catalysts in the conversion of methanol to light olefins or supports of catalysts for the automotive exhaust control were also prospected.

在此论述了SAPO的结构类型及适用的催化反应体系，并对它作为甲醇转化制低碳烯烃过程催化剂和汽车尾气净化催化剂载体的应用前景作了展望。

29Si NMR spectra indicate that SAPO-11 sample with an Si/Al of 0.33 significantly enhances the neighboring region between SAPO region and Si region, and NH_3-TPD results also show it has higher strong acid/weak acid ratio.

33的SAPO-11的SAPO区与Si区的交界区明显扩大，与之对应的NH_3-TPD也表明有较高的中强酸/弱酸比例。

The results show that the SAPO–5 has a pillar-like morphology with the size of about 20 μm×5 μm×5 μm.The ratio of P:Al:Si is 1:1.19:0.67 in its crystal structure, the content of Si is high. The total acidimety fo the SAPO–5 is 578.0 μmol/g , hihger than that of prepared by one step crystalline hydrothermal method.And its initial catalysis character performance on normal butane isomerization reaction reach 24.8 %, higher than that of prepared by one step crystalline hydrothermal method.

实验结果表明：产物为柱状的磷酸硅铝分子筛，其晶粒尺寸大约为20 μm×5 μm×5 μm，其晶体结构中P：Al：Si＝1：1.19：0.67，硅含量较高；采用分段晶化方式制备的SAPO-5分子筛的总酸量为578.0 μmol/g高于一段晶化方式制备的SAPO-5分子筛的总酸量；采用分段晶化生成的SAPO-5分子筛的催化正丁烷异构化反应初始活性可达到24.8 %，远高于一段晶化制备的SAPO-5分子筛的初始活性14.1 %。

The method adopts the following steps: after mixed, phosphorus source, silicon source, aluminum source, an organic template agent, water and a precursor of the SAPO molecular sieve are hydrothermally crystallized for at least 0.1 hour at the temperature ranging from 110 to 260 DEG C to obtain the SAPO molecular sieve; wherein, the preparation method for the precursor of the SAPO molecular sieve has the following steps:, the molar ratio is 0.03 to 0.6 R:(Si0.01 to 0.98: Al 0.01 to 0.6: P0.01 to 0.6): 2 to 500 H2O; wherein, R stands for mixture solution of raw materials which is blended by the phosphorus source, the silicon source, the aluminum source, the an organic template agent and water of the template agent;, the mixture solution of raw materials prepared in step reacts at the temperature which is at least 50 DEG C lower than the crystallization temperature for at least 0.1 hour.

本发明通过采用包括以下步骤：将磷源、硅源、铝源、有机模板剂、水和SAPO分子筛前驱体混合后在110～260℃的温度下水热晶化至少0.1小时获得SAPO分子筛；其中SAPO分子筛的前驱体的制备包括以下步骤：将摩尔配比为0.03～0.6R∶(Si0.01～0.98∶Al0.01～0.6∶P0.01～0.6)∶2～500H 2 O，式中R代表模板剂的磷源、硅源、铝源、有机模板剂和水混合成原料混合液；将步骤制备的原料混合液在低于晶化温度至少50℃的温度下反应至少0.1小时的技术方案较好地解决了该问题，可应用于含氧化合物制烯烃催化剂的制备过程。

Large single crystals of many AlPO〓 or SAPO molecular sieves such as AlPO〓-41, AlPO〓-11, AlPO〓-CJ2, AlPO〓-5, SAPO-47, SAPO-11, and SAPO-31 was easily synthesized using normal synthesis method.

如AlPO〓-41、AlPO〓-11、AlPO〓-5、SAPO-47、SAPO-11、SAPO-31、AlPO〓-15、AlPO〓-CJ2、NKX-19、NKX-20。其中NKX-19、NKX-20为新合成化合物，AlPO〓-41分子筛单晶属于首次合成，AlPO〓-CJ2、AlPO〓-15是在不加任何有机模板剂的情况下合成的。

The invention provides a preparation method of small crystal SAPO-43 molecular sieve, which is characterized in that: the stepwise procedures are adopted to synthetize SAPO-43 molecular sieve, temperature-rising rate in different temperature phase during crystallization is controlled, so that the synthetized SAPO-43 molecular sieve has small particles, even crystal particles, short crystallization time, and reduce the amount of templates greatly, thereby reducing environmental pollution.

本发明的目的是提供一种小晶粒SAPO-43分子筛的制备方法。本发明的特点在于它是采用分阶段程序升温来快速合成小晶粒SAPO-43分子筛。通过对晶化过程中不同温度段内升温速率的控制，从而实现了合成的SAPO-43分子筛晶粒小，晶粒尺寸分布均匀，晶化时间短，且大大的降低了模板剂的用量，从而减少了对环境的污染。

Methods: Five patients with parkinsonism or dystonia were assigned to general anesthesia using an modified endotracheal tube.

本实验依照人体实验之相关规定进行，五位患有帕金森氏症或肌张力异常的病人接受神经立体定位手术。

If you can benefit from this book, it is our honour.

如果您能从本书获益，这将是我们的荣幸。