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This thesis consists of three main parts of the research work on the syntheses, structures and reactivities of the olefin-coordinated transition metal carbene and carbyne complexes. In chapter 1, on the basis of our previous research works on the reacitivites of the cationic carbyne complexes of transition metals with metalcarbonyl anions, we explored the reactions of the cationic carbyne complexes of manganese (1) and rhenium (2) with polymetalcarbonyl anions, and developed a new method for the preparations of heternuclear trimetal bridging carbyne complexes.

本论文对烯烃配位的过渡金属卡宾和卡拜络合物的合成、结构和反应性能进行了研究,主要进行了如下三方面的工作:第一章在本小组过去的研究基础上,进一步考察锰和铼的阳离子卡拜络合物1和2与羰基金属阴离子化合物的反应,用来合成异核多金属桥卡拜络合物,发展合成多金属桥卡拜络合物的新方法和新路线。

Semanotus bifasciatus is most sensitive to Terpinolene, following are pinene and Rohan Chamigrene. The potential reactivities of Semanotus bifasciatus by different compounds are positive correlation in the decimus concentration.

利用触角电位仪测定的试验结果表明:双条杉天牛对Terpinene的触角电位反应最大,其次是Pinene和Thujopsene。

The addition of NaOH greatly enhanced the sorbent reactivities toward SO2 because NaOH is deliquescent and its presence increased the amount of water collected by the sorbent.

由于氢氧化钠的潮解性质,使较多的水分能吸附在吸收剂表面,提高了吸收剂与二氧化硫的反应性。

These dendritic NOBIN derived Schiff base ligands have been applied to titanium catalyzed hetero-Diels-Alder reaction of Danishefshy's diene and aldehydes, affording the corresponding 2-substituted 2, 3-dihydro-4H-pyran-4-one in quantitative yields and excellent enantioselectivities (up to 97. 2%ee). Comparing the reactivities and enantioselectivities of reaction catalyzed by the titanium complexes of these Schiff base ligands, it was found that a series of ligands L〓 were superior to the other three series of ligands L〓, L〓 and L〓, a significant positive NLE and a dendrimer effect existed in the L〓 dendritic catalyst system. The disposition of the dendritic wedges and the dendron size in the ligands were observed to have a significant impact on the enantioselectivity of the reaction.

NOBIN衍生的树枝状大分子希夫碱手性配体与钛形成的配合物在催化不对称杂Diels-Alder反应中的应用将得到的四个系列NOBIN衍生的树枝状希夫碱三齿手性配体与四异丙氧基钛形成的配合物用于催化Danishefsky's diene与醛的不对称杂Diels-Alder反应,通过反应条件的优化,获得了定量的收率和最高达97.2%ee值的对映选择性;考察了这四个系列NOBIN衍生的树枝状希夫碱钛配合物的催化活性和对映选择性,结果发现它们的活性次序依次为L〓≈L〓>L〓>L〓,对映选择性次序依次为L〓>L〓>L〓>L〓。

This review deals with the active site structure, reactivities and chemical mimics of the binuclear copper enzymes, particularly hemocyanin and tyrosinase .

本文综述了双核铜酶,特别是酪氨酸酶、血蓝蛋白的结构,键合氧、活化氧的性能及有关仿酶模型的研究进展。

The use of lanthanides in organic chemistry and in organic synthesis has attracted broad interest recently because of the unique reactivities and selectivities exhibited by compounds of these rare earth elements.

标题: Lanthanides:化学和在有机的综合过程中使用化学と有機的な総合的な過程の中に使用します在有机化学方面的使用lanthanides,因为独特的reactivities,在有机的综合过程中最近已经吸引宽的兴趣,选择性被这些稀土元素的化合物展览。

During the operation of nuclear reactor, it is important to monitor the reactivities at real-time for the safety of reactor.

在反应堆运行过程中,实时监测堆内反应性的大小,对于保证反应堆的安全具有十分重要的意义。

The reactivities of phosphate rock in China are low and its impurity,especially the Mg is high.

鉴于我国不少磷矿的反应活性偏低和杂质对高浓度磷复肥的生产不利,指出:磷肥工业的发展应结合因矿制肥的原则,对低品质的磷矿应着重提高磷肥产品有效养份和产品质量。

The types of atmospherically relevant investigations described include the measurement of reactivities, the measurement of radicals, the measurement of photolysis frequencies and products, kinetic and product studies on the oxidation of different types of hydrocarbons by important oxidant species (OH, N03, 03), formation of secondary organic aerosol from hydrocarbon oxidation etc. A special section includes contributions from eastern European countries which highlight some of the environmental research being performed in these countries.

大气的类型描述的相关的调查包括reactivities的测量,激进主义者的测量, photolysis 频率和产品的测量,动力和产品在烃以重要氧化剂种类的不同类型的氧化上研究(噢, N03,03),由烃氧化形成第二有机的烟等等特别部分从东欧国家那里包括贡献哪最精彩场面一些环境研究。

Knowledge of synthesis methods, reactivities, reagents, protective groups and much more is best acquired - and retained - by way of detailed analysis and processing of complex synthesis paths.

合成法的知识, reactivities,试剂,保护组和更多被最好获得-并且保留-作为详细分析并且复杂综合道路的处理。

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What are your goals and strategies for growth?

你的成长目标和策略是什么?

And unto the angel of the church in Sardis write; These things saith he that hath the seven irits of God, and the seven star I know thy works, that thou hast a name that thou livest, and art dead.

3:1 你要写信给撒狄教会的使者,说,那有神的七灵和七星的,说,我知道你的行为,按名你是活的,其实是死的。

"It is a testament to making sure unemployment compensation is available, making sure we are looking out for people who have lost their jobs," she said.

"这是个实证,证明我们必须确保人们都可以得到失业补偿,确保那些失去工作的人们得到照顾。"