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The optimum reaction conditions are as follows: diphenylmethanethiol : methyl chloroacetate is 1:1.5, and the reaction carried out at 100℃ for 4 h, 2- acetamide can be carried out in the room temperature for 20 h, the yield of 2- acetamide was 76%, hydrogen dioxide: 2- acetamide is 1:1, and the reaction carried out at 60℃ for 3 h, the yield of modafinil was 79%, the total yield of reaction can be reached 48%.

研究表明,采用氯乙酸甲酯作为醚化试剂,反应时间4h,反应温度100℃,二苯甲硫醇:氯乙酸甲酯=1:1.5,室温下氨解反应20h,二苯甲硫乙酰胺收率76%;采用过氧化氢作为氧化试剂,反应时间3h,反应温度60℃,过氧化氢:二苯甲硫乙酰胺=1:l,莫达非尼收率79%,反应总收率可达48%。

This paper mainly introduces experimental methods and basic principle about gelled acid reaction kinetics. Through the reaction kinetics experiment of straight acid and gelled acid, the reaction parameters of acid - rock reaction and kinetic equation in different conditions were achieved.

介绍了胶凝酸反应动力学的试验方法及基本原理,进行了普通酸和胶凝酸与灰岩的反应动力学试验,得到不同条件下的酸岩反应动力学参数及反应动力学方程,对优化碳酸盐岩油藏酸压设计有一定的指导作用。

Acieration Mu hydrogenation the main body of a book has been inspected mainly takes off the nitrogen function, the acieration Mu deoxidation acieration temperature and , deoxidation acieration reaction airspeed, the reaction pressure escaping from nitrogen reaction affects hydrogenation as well as the reaction airspeed azine hydrogenation to acieration Mu catalysator takes off the nitrogen function's.

本文主要考察了碳化钼的加氢脱氮性能,以及碳化钼还原碳化温度,还原碳化反应空速,加氢脱氮反应的反应压力以及反应空速对碳化钼催化剂的吡啶加氢脱氮性能的影响。

In the part of producing TONALIDE, through single-factor-experiments , the highest yield of reaction condition was confirmed as: reaction time about 4 hours; reaction temperature about 20 ; the quantity of chlori-acytyl about 10g; the quantity of aluminum chloride 13-15g and the yield of reaction was as high as 90%.

在TONALIDE的合成部分,通过单因素试验,找到了反应收率最高的反应条件为:反应时间4小时左右;反应温度20℃左右;乙酰氯的用量10g左右;反应中的三氯化铝的用量13~15g,此时反应收率可达90%。

The researching content was as follows: 1. When AlClx/HY zeolite be used as catalyst, the effects of the ratio of 2-methylnaphthalene to tetramethyl benzene, catalyst concentration, reaction temperature and reaction time on the conversion (based on 2-methylnaphthalene), yield and selectivity (both based on 2,6-DMN) were discussed. In addition, by orthogonal experiment, the optimum reaction conditions were determined at the same time. The optimum reaction conditions : the molar ratio of 2-methylnaphthalene and tetramethyl benzene =1:1, reaction temperature was 400℃.

具体研究如下: 1、以AlClx/HY型分子筛为催化剂,研究原料配比(2-甲基萘与均四甲苯的摩尔比)、反应温度和反应时间对2-甲基萘的转化率、目的产物2,6-DMN的收率和选择性的影响,并通过正交实验确定了该催化剂体系下的最佳反应条件为:原料的摩尔比为(2-甲基萘:均四甲苯)=1:1,反应质量空速为6h-1,反应温度为400℃。

Our product is a titanium , sparse noble metal material such as nickel, Mu , tantalum , zirconium processes; The tube , stick , silk , belt , board , foil , net , cake are encircled by reaching alloy products; Reaction equipment (500 L reaction boilers , titanium steel compound reaction boilers , titanium outside plate manage the warmup reaction boiler , the nickel steel compound reaction boiler); Heat exchanger (the titanium enumerates a pipe heat exchanger , titanium plate-type heat exchanger , the nickel heat exchanger , titanium helix plate-type heat exchanger); Compound board (titanium steel compound board , titanium copper compound board , titanium aluminium compound board finished product); The accessory and the heater titanium net are blue , the titanium flange , titanium nut titanium filter , titanium pump , titanium plate manage , the positive electrode , titanium centrifugal machine , titanium heater , various mistake are labeled with equipment and the accessory.

我们的产品是钛、镍、钼、钽、锆等稀贵金属材料加工;管、棒、丝、带、板、箔、网、饼环及合金制品;反应设备(500L反应釜、钛钢复合反应釜、钛外盘管加热反应釜、镍钢复合反应锅);换热器(钛列管式换热器、钛板式换热器、镍换热器、钛螺旋板式换热器);复合板(钛钢复合板、钛铜复合板、钛铝复合板成品);配件及加热器(钛网蓝、钛法兰、钛螺母钛过滤器、钛泵、钛盘管、阳极、钛离心机、钛加热器、各种非标设备及配件。

The phase equilibrium data of SBO-FAME-Methanol, SBO-FAEE-Ethanol and Glycerol-FAEE-Ethanol systems were measured. The results indicated that it involved two different stages: liquid-liquid-solid reaction stage and liquid-solid reaction stage. When the molar ratio of methanol to oil is 12:1 at 65℃, the turning point is at a 55% biodiesel yield. The liquid-liquid-solid reaction model was proposed based on the double-membranes theory. It indicated that the process is reaction and mass transfer controlled together at the first stage, and the second stage is reaction controlled. The predictions of the model are matched with the experimental results.In the end, the acid was extracted using methanol and ethanol from jatropha curcas l oil.

测定了生物柴油制备过程中的SBO-FAME-Methanol、SBO-FAEE-Ethanol、Glycerol-FAEE-Ethanol三组分相平衡数据,表明固体碱催化过程分为液-液-固和液-固两个反应阶段,在醇油摩尔比为12:1、65℃的初始反应条件下,转化率达到55%时,为第一阶段向第二阶段的转折点;基于双膜理论建立了固体碱催化制备生物柴油的非均相液-液-固反应模型,表明两个反应阶段分别为传质、反应共同控制和反应控制,模型计算值与实验值吻合较好。

The progress levels of symptoms after pathogen infection showed that interaction of gray leaf spot pathogen and host has differentiation or polymorphism. The progress levels of symptoms is different.The aggressively has polymorphism. The pathogenicity of different isolates in same cultivar has polymorphism, or the host reaction type of same isolate in different cultivars has polymorphism.The host reaction type has differentiation. There are seven types of host reaction in cultivar and inbred after infected by GLS pathogen:Rectangular lesion without chlorotic halo, Rectangular lesion with chlorotic halo,Irregular lesion without chlorotic halo,Irregular lesion with chlorotic halo, Spot lesion with chlorotic halo,Rectangular and irregular lesionand Rectangular and spot lesion. The host reaction type is coalesced lesion when disease severely. Frequency of each reaction types is different.

通过对玉米灰斑病菌侵染后的显症过程的系统观察,可在组织水平上说明该病菌与寄主互作反应存在分化或多样性:玉米灰斑病菌不同菌株侵染后显症过程表现出明显的差异;玉米灰斑病菌在侵袭力上存在多样性,菌株间对同一种品种的致病性表现多样化,或者同一菌株对不同品种侵染引起的寄主反应表现为多样性;病斑反应型的分化,玉米灰斑病菌侵染玉米品种或自交系后,主要有7种病斑反应类型,即RH型、RN型、IRH型(不规则形具褪绿晕圈病斑)、IRN型(不规则形无褪绿晕圈病斑)、SH型、RI型(长矩形与不规则形混合病斑)和RS型(长矩形与斑点形混合病斑),若发病严重,病斑连成片,而且这些反应类型出现的频率也不同。

Effects of microwave power, reaction time, reaction temperature, solvent etc. on reaction were studied by a single factor tests. The results show that maleic acid is more active than fumaric acid; the introduction of methyl group on the double bond can weak the reactivity of the Michael addition reaction; the ester base is more propitious to complete the Michael addition reaction than the nitrile base.

为研究微波下迈克尔反应的规律,本文采用单模聚焦微波有机合成仪,通过对顺丁烯二酸、反丁烯二酸和氨水合成DL-天冬氨酸、顺式3-甲基丁烯二酸和氨水合成3-甲基天冬氨酸、丙烯酸甲酯和氨水合成β-丙氨酸、丙烯腈和氨水合成β-氨基丙腈等五个反应对迈克尔加成反应进行了研究。

Melting point 3410 ℃, boiling point 560 ℃, relative density of 1935, F the external electronic structure of 5d46s2, in the chemical reaction time is very easy to lose 1-6 electronic, but also can get 1-2 electronic, so oxidation number of 0,± 1,± 2, 3, 4 , 5 and 6, with 6 price of the most stable compounds, such as WO3 does not dissolve in water, the air will form in the tungsten trioxide thin protective layer of tungsten, tungsten with fluorine at room temperature, chemical combination, red hot when there is no moisture and Bromine iodide together, red hot when you can and water reaction WO3, at room temperature reaction of tungsten with aqua regia, but the hot concentrated hydrochloric acid and sulfuric acid can only be played with its weak response, but molten nitrate, nitrite, too Hydrogen peroxide, sulfur steam, steam and other phosphorus can play intense reaction, high temperature can not be carbon, boron and silicon reaction of binary compounds, widely used in industrial tungsten steel and tungsten carbide, pure tungsten filament is used to the system, and X-ray tube Tube heating components, semiconductor components can be prepared tungsten silicide, tungsten industrial production is white or black tungsten ore tungsten ore refining.

熔点3410℃,沸点560℃,相对密度1935,F外围电子结构为5d46s2,在化学反应时很容易丢掉1—6个电子,也能得到1—2个电子,所以氧化数为0、±1、±2、+3、+4、+5和+6,以+6价化合物最稳定,如WO3不溶于水,空气中的钨会形成薄层三氧化钨保护层,钨能与氟在室温下化合,红热并无潮气时能与溴、碘化合,红热时还能和水反应生成WO3,室温下钨可与王水反应,但热的浓盐酸和硫酸只能与其起微弱反应,但对熔融的硝酸盐、亚硝酸盐、过氧化氢、硫蒸汽、磷蒸汽等能起激烈反应,高温下不能与碳、硼和硅反应生成二元化合物,工业上广泛使用钨钢和碳化钨,纯钨用来制灯丝、电子管和X射线管的发热元件,硅化钨可制半导体元件,钨工业生产是将白钨矿石或黑钨矿石精炼。

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